Identification of an “End-on” Nickel−Superoxo Adduct, [Ni(tmc)(O2)]
An “end-on” Ni2+−superoxo adduct has been prepared via two independent synthetic routes and its structure ascertained by spectroscopic and computational methods. The new structure type in nickel coordination chemistry is supported by resonance Raman and EPR spectroscopic features, the former display...
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| Veröffentlicht in: | Journal of the American Chemical Society 2006-11, Vol.128 (44), p.14230-14231 |
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| container_issue | 44 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 128 |
| creator | Kieber-Emmons, Matthew T. Annaraj, Jamespandi Seo, Mi Sook Van Heuvelen, Katherine M. Tosha, Takehiko Kitagawa, Teizo Brunold, Thomas C. Nam, Wonwoo Riordan, Charles G. |
| description | An “end-on” Ni2+−superoxo adduct has been prepared via two independent synthetic routes and its structure ascertained by spectroscopic and computational methods. The new structure type in nickel coordination chemistry is supported by resonance Raman and EPR spectroscopic features, the former displaying a high frequency ν (O−O) mode (1131 cm-1) consistent with significant superoxo character. The Ni2+−superoxo adduct oxidizes PPh3 to OPPh3 in quantitative yield. |
| doi_str_mv | 10.1021/ja0644879 |
| format | Article |
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The new structure type in nickel coordination chemistry is supported by resonance Raman and EPR spectroscopic features, the former displaying a high frequency ν (O−O) mode (1131 cm-1) consistent with significant superoxo character. 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Am. Chem. Soc</addtitle><description>An “end-on” Ni2+−superoxo adduct has been prepared via two independent synthetic routes and its structure ascertained by spectroscopic and computational methods. The new structure type in nickel coordination chemistry is supported by resonance Raman and EPR spectroscopic features, the former displaying a high frequency ν (O−O) mode (1131 cm-1) consistent with significant superoxo character. The Ni2+−superoxo adduct oxidizes PPh3 to OPPh3 in quantitative yield.</description><subject>ADDUCTS</subject><subject>Chemistry</subject><subject>ELECTRON SPIN RESONANCE</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Heterocyclic Compounds - chemistry</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>Molecular Structure</subject><subject>MORPHOLOGY</subject><subject>Nickel - chemistry</subject><subject>NICKEL COMPLEXES</subject><subject>Organometallic Compounds - chemistry</subject><subject>OXIDIZERS</subject><subject>Oxygen - chemistry</subject><subject>RAMAN SPECTROSCOPY</subject><subject>Spectrum Analysis, Raman</subject><subject>Superoxides - chemistry</subject><subject>SYNTHESIS</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNpt0MtqFEEUBuBCDGZMXPgC0i6UDKS17pdlGBIdGBIhcSVSVFdXY016qsaqaoi7LF271pebJ7HDDJlNVofD-fg5_AC8RvADghh9XBrIKZVCPQMTxDCsGcL8OZhACHEtJCeH4GXOy3GlWKIX4BAJKDgVfALm89aF4jtvTfExVLGrTKg293_PQ1vHsLn_V116e-v6ze8_18PapXgXq7O2HWw5rb5d-pOystOTKzz9fgwOOtNn92o3j8DXi_Ob2ed6cfVpPjtb1IYKUuquw1QaypVsEKbMIEWFYLQhpKFNZxBiziJEmMK2RdYKLCxxrSQcS6aaRpEj8HabG3PxOltfnP1hYwjOFq0IRPjBvN-adYo_B5eLXvlsXd-b4OKQNVcQY0zYCKdbaFPMOblOr5NfmfRLI6gfutWP3Y72zS50aFau3ctdmSN4twMmW9N3yQTr895JzBiBcnT11vlc3N3j3aRbzQURTN98udazBaNSXVCN97nGZr2MQwpjv088-B-m0Jp-</recordid><startdate>20061108</startdate><enddate>20061108</enddate><creator>Kieber-Emmons, Matthew T.</creator><creator>Annaraj, Jamespandi</creator><creator>Seo, Mi Sook</creator><creator>Van Heuvelen, Katherine M.</creator><creator>Tosha, Takehiko</creator><creator>Kitagawa, Teizo</creator><creator>Brunold, Thomas C.</creator><creator>Nam, Wonwoo</creator><creator>Riordan, Charles G.</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>OTOTI</scope></search><sort><creationdate>20061108</creationdate><title>Identification of an “End-on” Nickel−Superoxo Adduct, [Ni(tmc)(O2)]</title><author>Kieber-Emmons, Matthew T. ; Annaraj, Jamespandi ; Seo, Mi Sook ; Van Heuvelen, Katherine M. ; Tosha, Takehiko ; Kitagawa, Teizo ; Brunold, Thomas C. ; Nam, Wonwoo ; Riordan, Charles G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a473t-ff248a4698b1245a1947754b33b4bfa115ec113592cd1cc727c3ed8362859bb93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>ADDUCTS</topic><topic>Chemistry</topic><topic>ELECTRON SPIN RESONANCE</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Heterocyclic Compounds - chemistry</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>Molecular Structure</topic><topic>MORPHOLOGY</topic><topic>Nickel - chemistry</topic><topic>NICKEL COMPLEXES</topic><topic>Organometallic Compounds - chemistry</topic><topic>OXIDIZERS</topic><topic>Oxygen - chemistry</topic><topic>RAMAN SPECTROSCOPY</topic><topic>Spectrum Analysis, Raman</topic><topic>Superoxides - chemistry</topic><topic>SYNTHESIS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kieber-Emmons, Matthew T.</creatorcontrib><creatorcontrib>Annaraj, Jamespandi</creatorcontrib><creatorcontrib>Seo, Mi Sook</creatorcontrib><creatorcontrib>Van Heuvelen, Katherine M.</creatorcontrib><creatorcontrib>Tosha, Takehiko</creatorcontrib><creatorcontrib>Kitagawa, Teizo</creatorcontrib><creatorcontrib>Brunold, Thomas C.</creatorcontrib><creatorcontrib>Nam, Wonwoo</creatorcontrib><creatorcontrib>Riordan, Charles G.</creatorcontrib><creatorcontrib>BROOKHAVEN NATIONAL LABORATORY (BNL), NATIONAL SYNCHROTRON LIGHT SOURCE (NSLS)</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>OSTI.GOV</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kieber-Emmons, Matthew T.</au><au>Annaraj, Jamespandi</au><au>Seo, Mi Sook</au><au>Van Heuvelen, Katherine M.</au><au>Tosha, Takehiko</au><au>Kitagawa, Teizo</au><au>Brunold, Thomas C.</au><au>Nam, Wonwoo</au><au>Riordan, Charles G.</au><aucorp>BROOKHAVEN NATIONAL LABORATORY (BNL), NATIONAL SYNCHROTRON LIGHT SOURCE (NSLS)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Identification of an “End-on” Nickel−Superoxo Adduct, [Ni(tmc)(O2)]</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2006-11-08</date><risdate>2006</risdate><volume>128</volume><issue>44</issue><spage>14230</spage><epage>14231</epage><pages>14230-14231</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>An “end-on” Ni2+−superoxo adduct has been prepared via two independent synthetic routes and its structure ascertained by spectroscopic and computational methods. The new structure type in nickel coordination chemistry is supported by resonance Raman and EPR spectroscopic features, the former displaying a high frequency ν (O−O) mode (1131 cm-1) consistent with significant superoxo character. The Ni2+−superoxo adduct oxidizes PPh3 to OPPh3 in quantitative yield.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>17076476</pmid><doi>10.1021/ja0644879</doi><tpages>2</tpages></addata></record> |
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| subjects | ADDUCTS Chemistry ELECTRON SPIN RESONANCE Exact sciences and technology General and physical chemistry Heterocyclic Compounds - chemistry INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Molecular Structure MORPHOLOGY Nickel - chemistry NICKEL COMPLEXES Organometallic Compounds - chemistry OXIDIZERS Oxygen - chemistry RAMAN SPECTROSCOPY Spectrum Analysis, Raman Superoxides - chemistry SYNTHESIS |
| title | Identification of an “End-on” Nickel−Superoxo Adduct, [Ni(tmc)(O2)] |
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