Formation and Characterization of Thorium Methylidene CH2ThHX Complexes

Laser-ablated thorium atoms react with methyl fluoride to give the CH2ThHF molecule as the major product observed and trapped in solid argon. Infrared spectroscopy, isotopic substitution, and density functional theoretical frequency calculations confirm the identification of this methylidene comple...

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Veröffentlicht in:	Inorganic chemistry 2005-11, Vol.44 (23), p.8610-8616
Hauptverfasser:	Lyon, Jonathan T, Andrews, Lester
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL PROPERTIES Environmental Molecular Sciences Laboratory RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY SYNTHESIS THORIUM COMPLEXES
Online-Zugang:	Volltext
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