Crystalline ice growth on Pt(111) : Observation of a hydrophobic water monolayer
The growth of crystalline water films on Pt(111) is investigated using rare gas physisorption. The water monolayer wets Pt(111) at all temperatures investigated (20-155 K). At low temperatures (T< or =120 K), additional water layers kinetically wet the monolayer surface. However, crystalline ice...
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| Veröffentlicht in: | Physical review letters 2005-10, Vol.95 (16), p.166102.1-166102.4, Article 166102 |
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| container_end_page | 166102.4 |
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| container_issue | 16 |
| container_start_page | 166102.1 |
| container_title | Physical review letters |
| container_volume | 95 |
| creator | KIMMEL, Greg A PETRIK, Nikolay G DOHNALEK, Zdenek KAY, Bruce D |
| description | The growth of crystalline water films on Pt(111) is investigated using rare gas physisorption. The water monolayer wets Pt(111) at all temperatures investigated (20-155 K). At low temperatures (T< or =120 K), additional water layers kinetically wet the monolayer surface. However, crystalline ice films grown at higher temperatures (T > 135 K) do not wet the water monolayer. These results are consistent with recent theory and experiments suggesting that the molecules in the water monolayer form a surface with no dangling OH bonds or lone pair electrons, giving rise to a hydrophobic water monolayer on Pt(111). |
| doi_str_mv | 10.1103/physrevlett.95.166102 |
| format | Article |
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The water monolayer wets Pt(111) at all temperatures investigated (20-155 K). At low temperatures (T< or =120 K), additional water layers kinetically wet the monolayer surface. However, crystalline ice films grown at higher temperatures (T > 135 K) do not wet the water monolayer. 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The water monolayer wets Pt(111) at all temperatures investigated (20-155 K). At low temperatures (T< or =120 K), additional water layers kinetically wet the monolayer surface. However, crystalline ice films grown at higher temperatures (T > 135 K) do not wet the water monolayer. 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The water monolayer wets Pt(111) at all temperatures investigated (20-155 K). At low temperatures (T< or =120 K), additional water layers kinetically wet the monolayer surface. However, crystalline ice films grown at higher temperatures (T > 135 K) do not wet the water monolayer. These results are consistent with recent theory and experiments suggesting that the molecules in the water monolayer form a surface with no dangling OH bonds or lone pair electrons, giving rise to a hydrophobic water monolayer on Pt(111).</abstract><cop>Ridge, NY</cop><pub>American Physical Society</pub><pmid>16241818</pmid><doi>10.1103/physrevlett.95.166102</doi><tpages>1</tpages></addata></record> |
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| source | American Physical Society Journals |
| subjects | Cross-disciplinary physics: materials science rheology CRYSTAL GROWTH Environmental Molecular Sciences Laboratory Exact sciences and technology ICE INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Materials science Methods of deposition of films and coatings film growth and epitaxy Physics PLATINUM SORPTION SURFACE PROPERTIES Theory and models of film growth WETTABILITY |
| title | Crystalline ice growth on Pt(111) : Observation of a hydrophobic water monolayer |
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