193-nm photodissociation of acryloyl chloride to probe the unimolecular dissociation of CH2CHCO radicals and CH2CCO

The work presented here uses photofragment translational spectroscopy to investigate the primary and secondary dissociation channels of acryloyl chloride (CH2==CHCOCl) excited at 193 nm. Three primary channels were observed. Two C-Cl fission channels occur, one producing fragments with high kinetic...

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Veröffentlicht in:	The Journal of chemical physics 2004-03, Vol.120 (9), p.4223-4230
Hauptverfasser:	Szpunar, D E, Miller, J L, Butler, L J, Qi, F
Format:	Artikel
Sprache:	eng
Schlagworte:	CHLORIDES DISSOCIATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY PROBES RADICALS
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