A cubic-to-monoclinic structural transformation in the sesquioxide Dy2O3 induced by ion irradiation

Polycrystalline pellets of the sesquioxide Dy2O3 were irradiated at cryogenic temperature with Kr++ ions to a fluence of 1 × 1020 Kr/m2. The crystal structure of the irradiated Dy2O3 was observed to change from a cubic, so-called C-type rare-earth sesquioxide structure to a monoclinic, B-type rare-e...

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Veröffentlicht in:Journal of nuclear materials 2004-06, Vol.328 (1), p.71-76
Hauptverfasser: TANG, M, VALDEZ, J. A, LU, P, GOSNELL, G. E, WETTELAND, C. J, SICKAFUS, K. E
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Sprache:eng
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Zusammenfassung:Polycrystalline pellets of the sesquioxide Dy2O3 were irradiated at cryogenic temperature with Kr++ ions to a fluence of 1 × 1020 Kr/m2. The crystal structure of the irradiated Dy2O3 was observed to change from a cubic, so-called C-type rare-earth sesquioxide structure to a monoclinic, B-type rare-earth sesquioxide structure upon ion irradiation. This transformation is accompanied by a decrease in molecular volume (or density increase) of approximately 9%.
ISSN:0022-3115
1873-4820
DOI:10.1016/j.jnucmat.2004.02.014