High-resolution pulsed field ionization photoelectron–photoion coincidence study of CH4: Accurate 0 K dissociation threshold for CH3

The formation of methyl cation (CH3+) from methane (CH4) has been investigated in high resolution using the newly perfected pulsed field ionization photoelectron–photoion coincidence (PFI-PEPICO) scheme. The PFI-PEPICO data reveal that fragmentation of CH4 in high-n Rydberg states occurs at energies...

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Veröffentlicht in:The Journal of chemical physics 1999-11, Vol.111 (18), p.8267-8270
Hauptverfasser: Weitzel, Karl-Michael, Malow, Marcus, Jarvis, G. K., Baer, Tomas, Song, Y., Ng, C. Y.
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Sprache:eng
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