High-resolution pulsed field ionization photoelectron–photoion coincidence study of CH4: Accurate 0 K dissociation threshold for CH3
The formation of methyl cation (CH3+) from methane (CH4) has been investigated in high resolution using the newly perfected pulsed field ionization photoelectron–photoion coincidence (PFI-PEPICO) scheme. The PFI-PEPICO data reveal that fragmentation of CH4 in high-n Rydberg states occurs at energies...
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Veröffentlicht in: | The Journal of chemical physics 1999-11, Vol.111 (18), p.8267-8270 |
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Format: | Artikel |
Sprache: | eng |
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