Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti
The new pseudo-binary intermetallic compound, Ti{sub 11}(Sb,Sn){sub 8}, has been synthesized by reacting Ti and Sb in a Sn flux at 1100 C and its structure determined from both single-crystal X-ray and neutron diffraction data (orthorhombic, Pnma, Z=4, X-ray diffraction at 90 K: a=14.6877(6) {angstr...
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| Veröffentlicht in: | Journal of solid state chemistry 2001-02, Vol.157 (1) |
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| container_title | Journal of solid state chemistry |
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| creator | Kim, Hyungrak Olmstead, Marilyn M. Chan, Julia Y. Canfield, Paul C. Fisher, Ian R. Henning, Robert W. Schultz, Arthur J. Kauzlarich, Susan M. |
| description | The new pseudo-binary intermetallic compound, Ti{sub 11}(Sb,Sn){sub 8}, has been synthesized by reacting Ti and Sb in a Sn flux at 1100 C and its structure determined from both single-crystal X-ray and neutron diffraction data (orthorhombic, Pnma, Z=4, X-ray diffraction at 90 K: a=14.6877(6) {angstrom}, b=5.5677(2) {angstrom}, c=17.7207(7) {angstrom}, V=1449.14(10) {angstrom}3, neutron diffraction at room temperature: a=14.677(6) {angstrom}, b=5.577(3) {angstrom}, c=17.716 (6) {angstrom}, V=1450(1) {angstrom}3). The structure contains two differently oriented repeating layers and interstitial atoms that are closely connected to make linear chains aligned along the crystal b axis. The compound exhibits mixed site occupancies of Sb and Sn on the anion sites. The phase width (Sb/Sn ratio=0.98-1.40) was determined by microprobe elemental analysis. The electrical resistivity of a single crystal as a function of temperature is anisotropic (b=1{approximately}2 x 10{sup {minus}1} m {center_dot}cm, b = 0.5 x 10{sup {minus}1} m {center_dot} cm) and confirms that this compound is metallic. Magnetic susceptibility measurements show Pauli paramagnetism. |
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| fullrecord | <record><control><sourceid>osti</sourceid><recordid>TN_cdi_osti_scitechconnect_783977</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>783977</sourcerecordid><originalsourceid>FETCH-osti_scitechconnect_7839773</originalsourceid><addsrcrecordid>eNqNzEsKwjAUQNEgCtbPHp4LKKT_dlwUnUjBDpyVmL7SSJuU5BVx9zpwAY7u5HAXzAt4kfhZmN6XzOM8DP04KdI12zj35DwIkjz2WH0jO0uaLYLQLVT92ykpBqismdCSQgemA-oRrviCyuHcGv-htLBvuGhCOyKJYVASSjNOZv4-arVjq04MDve_btnhdKzLs28cqcZJRSh7abRGSU2WR0WWRf-YD8CKQaE</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Kim, Hyungrak ; Olmstead, Marilyn M. ; Chan, Julia Y. ; Canfield, Paul C. ; Fisher, Ian R. ; Henning, Robert W. ; Schultz, Arthur J. ; Kauzlarich, Susan M.</creator><creatorcontrib>Kim, Hyungrak ; Olmstead, Marilyn M. ; Chan, Julia Y. ; Canfield, Paul C. ; Fisher, Ian R. ; Henning, Robert W. ; Schultz, Arthur J. ; Kauzlarich, Susan M. ; Department of Chemistry, University of California-Davis, CA (US) ; Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana (US) ; IPNS Division, Argonne National Laboratory, Argonne, Illinois (US) ; Department of Physics, Iowa State University, Ames, Iowa (US)</creatorcontrib><description>The new pseudo-binary intermetallic compound, Ti{sub 11}(Sb,Sn){sub 8}, has been synthesized by reacting Ti and Sb in a Sn flux at 1100 C and its structure determined from both single-crystal X-ray and neutron diffraction data (orthorhombic, Pnma, Z=4, X-ray diffraction at 90 K: a=14.6877(6) {angstrom}, b=5.5677(2) {angstrom}, c=17.7207(7) {angstrom}, V=1449.14(10) {angstrom}3, neutron diffraction at room temperature: a=14.677(6) {angstrom}, b=5.577(3) {angstrom}, c=17.716 (6) {angstrom}, V=1450(1) {angstrom}3). The structure contains two differently oriented repeating layers and interstitial atoms that are closely connected to make linear chains aligned along the crystal b axis. The compound exhibits mixed site occupancies of Sb and Sn on the anion sites. The phase width (Sb/Sn ratio=0.98-1.40) was determined by microprobe elemental analysis. The electrical resistivity of a single crystal as a function of temperature is anisotropic (b=1{approximately}2 x 10{sup {minus}1} m {center_dot}cm, b = 0.5 x 10{sup {minus}1} m {center_dot} cm) and confirms that this compound is metallic. Magnetic susceptibility measurements show Pauli paramagnetism.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><language>eng</language><publisher>United States</publisher><subject>ANIONS ; ANISOTROPY ; ANTIMONY COMPOUNDS ; ATOMS ; CHAINS ; CHEMICAL PREPARATION ; ELECTRIC CONDUCTIVITY ; ELECTRON MICROPROBE ANALYSIS ; EXPERIMENTAL DATA ; INTERMETALLIC COMPOUNDS ; INTERSTITIALS ; LATTICE PARAMETERS ; MAGNETIC SUSCEPTIBILITY ; MATERIALS SCIENCE ; MONOCRYSTALS ; NEUTRON DIFFRACTION ; ORTHORHOMBIC LATTICES ; PARAMAGNETISM ; PHYSICAL PROPERTIES ; SPACE GROUPS ; TEMPERATURE DEPENDENCE ; TIN COMPOUNDS ; TITANIUM COMPOUNDS ; X-RAY DIFFRACTION</subject><ispartof>Journal of solid state chemistry, 2001-02, Vol.157 (1)</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/783977$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Kim, Hyungrak</creatorcontrib><creatorcontrib>Olmstead, Marilyn M.</creatorcontrib><creatorcontrib>Chan, Julia Y.</creatorcontrib><creatorcontrib>Canfield, Paul C.</creatorcontrib><creatorcontrib>Fisher, Ian R.</creatorcontrib><creatorcontrib>Henning, Robert W.</creatorcontrib><creatorcontrib>Schultz, Arthur J.</creatorcontrib><creatorcontrib>Kauzlarich, Susan M.</creatorcontrib><creatorcontrib>Department of Chemistry, University of California-Davis, CA (US)</creatorcontrib><creatorcontrib>Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana (US)</creatorcontrib><creatorcontrib>IPNS Division, Argonne National Laboratory, Argonne, Illinois (US)</creatorcontrib><creatorcontrib>Department of Physics, Iowa State University, Ames, Iowa (US)</creatorcontrib><title>Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti</title><title>Journal of solid state chemistry</title><description>The new pseudo-binary intermetallic compound, Ti{sub 11}(Sb,Sn){sub 8}, has been synthesized by reacting Ti and Sb in a Sn flux at 1100 C and its structure determined from both single-crystal X-ray and neutron diffraction data (orthorhombic, Pnma, Z=4, X-ray diffraction at 90 K: a=14.6877(6) {angstrom}, b=5.5677(2) {angstrom}, c=17.7207(7) {angstrom}, V=1449.14(10) {angstrom}3, neutron diffraction at room temperature: a=14.677(6) {angstrom}, b=5.577(3) {angstrom}, c=17.716 (6) {angstrom}, V=1450(1) {angstrom}3). The structure contains two differently oriented repeating layers and interstitial atoms that are closely connected to make linear chains aligned along the crystal b axis. The compound exhibits mixed site occupancies of Sb and Sn on the anion sites. The phase width (Sb/Sn ratio=0.98-1.40) was determined by microprobe elemental analysis. The electrical resistivity of a single crystal as a function of temperature is anisotropic (b=1{approximately}2 x 10{sup {minus}1} m {center_dot}cm, b = 0.5 x 10{sup {minus}1} m {center_dot} cm) and confirms that this compound is metallic. Magnetic susceptibility measurements show Pauli paramagnetism.</description><subject>ANIONS</subject><subject>ANISOTROPY</subject><subject>ANTIMONY COMPOUNDS</subject><subject>ATOMS</subject><subject>CHAINS</subject><subject>CHEMICAL PREPARATION</subject><subject>ELECTRIC CONDUCTIVITY</subject><subject>ELECTRON MICROPROBE ANALYSIS</subject><subject>EXPERIMENTAL DATA</subject><subject>INTERMETALLIC COMPOUNDS</subject><subject>INTERSTITIALS</subject><subject>LATTICE PARAMETERS</subject><subject>MAGNETIC SUSCEPTIBILITY</subject><subject>MATERIALS SCIENCE</subject><subject>MONOCRYSTALS</subject><subject>NEUTRON DIFFRACTION</subject><subject>ORTHORHOMBIC LATTICES</subject><subject>PARAMAGNETISM</subject><subject>PHYSICAL PROPERTIES</subject><subject>SPACE GROUPS</subject><subject>TEMPERATURE DEPENDENCE</subject><subject>TIN COMPOUNDS</subject><subject>TITANIUM COMPOUNDS</subject><subject>X-RAY DIFFRACTION</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqNzEsKwjAUQNEgCtbPHp4LKKT_dlwUnUjBDpyVmL7SSJuU5BVx9zpwAY7u5HAXzAt4kfhZmN6XzOM8DP04KdI12zj35DwIkjz2WH0jO0uaLYLQLVT92ykpBqismdCSQgemA-oRrviCyuHcGv-htLBvuGhCOyKJYVASSjNOZv4-arVjq04MDve_btnhdKzLs28cqcZJRSh7abRGSU2WR0WWRf-YD8CKQaE</recordid><startdate>20010215</startdate><enddate>20010215</enddate><creator>Kim, Hyungrak</creator><creator>Olmstead, Marilyn M.</creator><creator>Chan, Julia Y.</creator><creator>Canfield, Paul C.</creator><creator>Fisher, Ian R.</creator><creator>Henning, Robert W.</creator><creator>Schultz, Arthur J.</creator><creator>Kauzlarich, Susan M.</creator><scope>OTOTI</scope></search><sort><creationdate>20010215</creationdate><title>Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti</title><author>Kim, Hyungrak ; Olmstead, Marilyn M. ; Chan, Julia Y. ; Canfield, Paul C. ; Fisher, Ian R. ; Henning, Robert W. ; Schultz, Arthur J. ; Kauzlarich, Susan M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_7839773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>ANIONS</topic><topic>ANISOTROPY</topic><topic>ANTIMONY COMPOUNDS</topic><topic>ATOMS</topic><topic>CHAINS</topic><topic>CHEMICAL PREPARATION</topic><topic>ELECTRIC CONDUCTIVITY</topic><topic>ELECTRON MICROPROBE ANALYSIS</topic><topic>EXPERIMENTAL DATA</topic><topic>INTERMETALLIC COMPOUNDS</topic><topic>INTERSTITIALS</topic><topic>LATTICE PARAMETERS</topic><topic>MAGNETIC SUSCEPTIBILITY</topic><topic>MATERIALS SCIENCE</topic><topic>MONOCRYSTALS</topic><topic>NEUTRON DIFFRACTION</topic><topic>ORTHORHOMBIC LATTICES</topic><topic>PARAMAGNETISM</topic><topic>PHYSICAL PROPERTIES</topic><topic>SPACE GROUPS</topic><topic>TEMPERATURE DEPENDENCE</topic><topic>TIN COMPOUNDS</topic><topic>TITANIUM COMPOUNDS</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Hyungrak</creatorcontrib><creatorcontrib>Olmstead, Marilyn M.</creatorcontrib><creatorcontrib>Chan, Julia Y.</creatorcontrib><creatorcontrib>Canfield, Paul C.</creatorcontrib><creatorcontrib>Fisher, Ian R.</creatorcontrib><creatorcontrib>Henning, Robert W.</creatorcontrib><creatorcontrib>Schultz, Arthur J.</creatorcontrib><creatorcontrib>Kauzlarich, Susan M.</creatorcontrib><creatorcontrib>Department of Chemistry, University of California-Davis, CA (US)</creatorcontrib><creatorcontrib>Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana (US)</creatorcontrib><creatorcontrib>IPNS Division, Argonne National Laboratory, Argonne, Illinois (US)</creatorcontrib><creatorcontrib>Department of Physics, Iowa State University, Ames, Iowa (US)</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Hyungrak</au><au>Olmstead, Marilyn M.</au><au>Chan, Julia Y.</au><au>Canfield, Paul C.</au><au>Fisher, Ian R.</au><au>Henning, Robert W.</au><au>Schultz, Arthur J.</au><au>Kauzlarich, Susan M.</au><aucorp>Department of Chemistry, University of California-Davis, CA (US)</aucorp><aucorp>Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana (US)</aucorp><aucorp>IPNS Division, Argonne National Laboratory, Argonne, Illinois (US)</aucorp><aucorp>Department of Physics, Iowa State University, Ames, Iowa (US)</aucorp><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2001-02-15</date><risdate>2001</risdate><volume>157</volume><issue>1</issue><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>The new pseudo-binary intermetallic compound, Ti{sub 11}(Sb,Sn){sub 8}, has been synthesized by reacting Ti and Sb in a Sn flux at 1100 C and its structure determined from both single-crystal X-ray and neutron diffraction data (orthorhombic, Pnma, Z=4, X-ray diffraction at 90 K: a=14.6877(6) {angstrom}, b=5.5677(2) {angstrom}, c=17.7207(7) {angstrom}, V=1449.14(10) {angstrom}3, neutron diffraction at room temperature: a=14.677(6) {angstrom}, b=5.577(3) {angstrom}, c=17.716 (6) {angstrom}, V=1450(1) {angstrom}3). The structure contains two differently oriented repeating layers and interstitial atoms that are closely connected to make linear chains aligned along the crystal b axis. The compound exhibits mixed site occupancies of Sb and Sn on the anion sites. The phase width (Sb/Sn ratio=0.98-1.40) was determined by microprobe elemental analysis. The electrical resistivity of a single crystal as a function of temperature is anisotropic (b=1{approximately}2 x 10{sup {minus}1} m {center_dot}cm, b = 0.5 x 10{sup {minus}1} m {center_dot} cm) and confirms that this compound is metallic. Magnetic susceptibility measurements show Pauli paramagnetism.</abstract><cop>United States</cop></addata></record> |
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| subjects | ANIONS ANISOTROPY ANTIMONY COMPOUNDS ATOMS CHAINS CHEMICAL PREPARATION ELECTRIC CONDUCTIVITY ELECTRON MICROPROBE ANALYSIS EXPERIMENTAL DATA INTERMETALLIC COMPOUNDS INTERSTITIALS LATTICE PARAMETERS MAGNETIC SUSCEPTIBILITY MATERIALS SCIENCE MONOCRYSTALS NEUTRON DIFFRACTION ORTHORHOMBIC LATTICES PARAMAGNETISM PHYSICAL PROPERTIES SPACE GROUPS TEMPERATURE DEPENDENCE TIN COMPOUNDS TITANIUM COMPOUNDS X-RAY DIFFRACTION |
| title | Structure and Physical Properties of the New Pseudo-binary Intermetallic Compound Ti |
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