Decompositions of multiply charged oligonucleotide anions

Multiply charged single-strand deoxyoligonucleotide anions fragment first by loss of a nucleobase followed by cleavage at the 3' C-O bond of the sugar from which the base is lost. Both steps are proposed to proceed via 1,2-elimination involving hydrogens from the sugar and to yield a stable sub...

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Veröffentlicht in:Journal of the American Chemical Society 1993-12, Vol.115 (25), p.12085-12095
Hauptverfasser: McLuckey, Scott A, Habibi-Goudarzi, Sohrab
Format: Artikel
Sprache:eng
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