Selenization of metallic Cu-In thin films for CuInSe sub 2 solar cells
A new approach for formation of photovoltaic CuInSe{sub 2} films by chalcogenization of Cu-In multilayers with a thin selenium layer and subsequent heat treatments is presented. Morphological, compositional, and structural properties of films along with aspects of various processing conditions are d...
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| Veröffentlicht in: | Journal of applied physics 1989-12, Vol.66:12 |
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| container_title | Journal of applied physics |
| container_volume | 66:12 |
| creator | Szot, J. Prinz, U. |
| description | A new approach for formation of photovoltaic CuInSe{sub 2} films by chalcogenization of Cu-In multilayers with a thin selenium layer and subsequent heat treatments is presented. Morphological, compositional, and structural properties of films along with aspects of various processing conditions are discussed. The possibility of obtaining perfectly homogeneous chalcopyrite ternary films was affected by composition deviations from stoichiometry, although films obtained in a modified two-stage heat treatment processing were of good structural and photovoltaic quality. Heterojunctions with (Zn, Cd)S as window material showed efficiencies better than 5%, mainly limited by low open-circuit voltage and poor fill factor. Short-circuit currents were comparable to CuInSe{sub 2}-based cells fabricated by multiple-source evaporation. |
| doi_str_mv | 10.1063/1.343588 |
| format | Article |
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Morphological, compositional, and structural properties of films along with aspects of various processing conditions are discussed. The possibility of obtaining perfectly homogeneous chalcopyrite ternary films was affected by composition deviations from stoichiometry, although films obtained in a modified two-stage heat treatment processing were of good structural and photovoltaic quality. Heterojunctions with (Zn, Cd)S as window material showed efficiencies better than 5%, mainly limited by low open-circuit voltage and poor fill factor. Short-circuit currents were comparable to CuInSe{sub 2}-based cells fabricated by multiple-source evaporation.</description><identifier>ISSN: 0021-8979</identifier><identifier>EISSN: 1089-7550</identifier><identifier>DOI: 10.1063/1.343588</identifier><language>eng</language><publisher>United States</publisher><subject>140501 - Solar Energy Conversion- Photovoltaic Conversion ; CHALCOGENIDES ; COHERENT SCATTERING ; COPPER ; COPPER COMPOUNDS ; COPPER SELENIDE SOLAR CELLS ; COPPER SELENIDES ; CRYSTAL DOPING ; DIFFRACTION ; DIRECT ENERGY CONVERTERS ; ELECTRON MICROSCOPY ; ELEMENTS ; FABRICATION ; HEAT TREATMENTS ; INDIUM ; INDIUM COMPOUNDS ; INDIUM SELENIDE SOLAR CELLS ; INDIUM SELENIDES ; METALS ; MICROSCOPY ; MORPHOLOGY ; PHOTOELECTRIC CELLS ; PHOTOELECTRIC EFFECT ; PHOTOELECTROMAGNETIC EFFECTS ; PHOTOVOLTAIC CELLS ; SCANNING ELECTRON MICROSCOPY ; SCATTERING ; SELENIDES ; SELENIUM ; SELENIUM COMPOUNDS ; SEMIMETALS ; SOLAR CELLS ; SOLAR ENERGY ; SOLAR EQUIPMENT ; STOICHIOMETRY ; SYNTHESIS ; THIN FILMS ; TRANSITION ELEMENT COMPOUNDS ; TRANSITION ELEMENTS ; X-RAY DIFFRACTION</subject><ispartof>Journal of applied physics, 1989-12, Vol.66:12</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/7271631$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Szot, J.</creatorcontrib><creatorcontrib>Prinz, U.</creatorcontrib><title>Selenization of metallic Cu-In thin films for CuInSe sub 2 solar cells</title><title>Journal of applied physics</title><description>A new approach for formation of photovoltaic CuInSe{sub 2} films by chalcogenization of Cu-In multilayers with a thin selenium layer and subsequent heat treatments is presented. Morphological, compositional, and structural properties of films along with aspects of various processing conditions are discussed. The possibility of obtaining perfectly homogeneous chalcopyrite ternary films was affected by composition deviations from stoichiometry, although films obtained in a modified two-stage heat treatment processing were of good structural and photovoltaic quality. Heterojunctions with (Zn, Cd)S as window material showed efficiencies better than 5%, mainly limited by low open-circuit voltage and poor fill factor. Short-circuit currents were comparable to CuInSe{sub 2}-based cells fabricated by multiple-source evaporation.</description><subject>140501 - Solar Energy Conversion- Photovoltaic Conversion</subject><subject>CHALCOGENIDES</subject><subject>COHERENT SCATTERING</subject><subject>COPPER</subject><subject>COPPER COMPOUNDS</subject><subject>COPPER SELENIDE SOLAR CELLS</subject><subject>COPPER SELENIDES</subject><subject>CRYSTAL DOPING</subject><subject>DIFFRACTION</subject><subject>DIRECT ENERGY CONVERTERS</subject><subject>ELECTRON MICROSCOPY</subject><subject>ELEMENTS</subject><subject>FABRICATION</subject><subject>HEAT TREATMENTS</subject><subject>INDIUM</subject><subject>INDIUM COMPOUNDS</subject><subject>INDIUM SELENIDE SOLAR CELLS</subject><subject>INDIUM SELENIDES</subject><subject>METALS</subject><subject>MICROSCOPY</subject><subject>MORPHOLOGY</subject><subject>PHOTOELECTRIC CELLS</subject><subject>PHOTOELECTRIC EFFECT</subject><subject>PHOTOELECTROMAGNETIC EFFECTS</subject><subject>PHOTOVOLTAIC CELLS</subject><subject>SCANNING ELECTRON MICROSCOPY</subject><subject>SCATTERING</subject><subject>SELENIDES</subject><subject>SELENIUM</subject><subject>SELENIUM COMPOUNDS</subject><subject>SEMIMETALS</subject><subject>SOLAR CELLS</subject><subject>SOLAR ENERGY</subject><subject>SOLAR EQUIPMENT</subject><subject>STOICHIOMETRY</subject><subject>SYNTHESIS</subject><subject>THIN FILMS</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>TRANSITION ELEMENTS</subject><subject>X-RAY DIFFRACTION</subject><issn>0021-8979</issn><issn>1089-7550</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNqNyk8LgjAYgPERBdkf6CO8dNf2utR5liTPdhcbExdzA9956dPXoQ_Q6YEfD2Mn5AnyXFwwEVeRSbliEXJZxkWW8TWLOE8xlmVRbtmO6MU5ohRlxOpWW-3Muw_GO_ADTDr01hoF1RI3DsJoHAzGTgSDn7_YuFYDLU9IgbztZ1DaWjqwzdBb0sdf9-xc3x7VPfYUTEfKBK1G5Z3TKnRFWmAuUPw1fQBsgz6V</recordid><startdate>19891215</startdate><enddate>19891215</enddate><creator>Szot, J.</creator><creator>Prinz, U.</creator><scope>OTOTI</scope></search><sort><creationdate>19891215</creationdate><title>Selenization of metallic Cu-In thin films for CuInSe sub 2 solar cells</title><author>Szot, J. ; Prinz, U.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_72716313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>140501 - Solar Energy Conversion- Photovoltaic Conversion</topic><topic>CHALCOGENIDES</topic><topic>COHERENT SCATTERING</topic><topic>COPPER</topic><topic>COPPER COMPOUNDS</topic><topic>COPPER SELENIDE SOLAR CELLS</topic><topic>COPPER SELENIDES</topic><topic>CRYSTAL DOPING</topic><topic>DIFFRACTION</topic><topic>DIRECT ENERGY CONVERTERS</topic><topic>ELECTRON MICROSCOPY</topic><topic>ELEMENTS</topic><topic>FABRICATION</topic><topic>HEAT TREATMENTS</topic><topic>INDIUM</topic><topic>INDIUM COMPOUNDS</topic><topic>INDIUM SELENIDE SOLAR CELLS</topic><topic>INDIUM SELENIDES</topic><topic>METALS</topic><topic>MICROSCOPY</topic><topic>MORPHOLOGY</topic><topic>PHOTOELECTRIC CELLS</topic><topic>PHOTOELECTRIC EFFECT</topic><topic>PHOTOELECTROMAGNETIC EFFECTS</topic><topic>PHOTOVOLTAIC CELLS</topic><topic>SCANNING ELECTRON MICROSCOPY</topic><topic>SCATTERING</topic><topic>SELENIDES</topic><topic>SELENIUM</topic><topic>SELENIUM COMPOUNDS</topic><topic>SEMIMETALS</topic><topic>SOLAR CELLS</topic><topic>SOLAR ENERGY</topic><topic>SOLAR EQUIPMENT</topic><topic>STOICHIOMETRY</topic><topic>SYNTHESIS</topic><topic>THIN FILMS</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>TRANSITION ELEMENTS</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Szot, J.</creatorcontrib><creatorcontrib>Prinz, U.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of applied physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Szot, J.</au><au>Prinz, U.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selenization of metallic Cu-In thin films for CuInSe sub 2 solar cells</atitle><jtitle>Journal of applied physics</jtitle><date>1989-12-15</date><risdate>1989</risdate><volume>66:12</volume><issn>0021-8979</issn><eissn>1089-7550</eissn><abstract>A new approach for formation of photovoltaic CuInSe{sub 2} films by chalcogenization of Cu-In multilayers with a thin selenium layer and subsequent heat treatments is presented. Morphological, compositional, and structural properties of films along with aspects of various processing conditions are discussed. The possibility of obtaining perfectly homogeneous chalcopyrite ternary films was affected by composition deviations from stoichiometry, although films obtained in a modified two-stage heat treatment processing were of good structural and photovoltaic quality. Heterojunctions with (Zn, Cd)S as window material showed efficiencies better than 5%, mainly limited by low open-circuit voltage and poor fill factor. Short-circuit currents were comparable to CuInSe{sub 2}-based cells fabricated by multiple-source evaporation.</abstract><cop>United States</cop><doi>10.1063/1.343588</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8979 |
| ispartof | Journal of applied physics, 1989-12, Vol.66:12 |
| issn | 0021-8979 1089-7550 |
| language | eng |
| recordid | cdi_osti_scitechconnect_7271631 |
| source | AIP Digital Archive |
| subjects | 140501 - Solar Energy Conversion- Photovoltaic Conversion CHALCOGENIDES COHERENT SCATTERING COPPER COPPER COMPOUNDS COPPER SELENIDE SOLAR CELLS COPPER SELENIDES CRYSTAL DOPING DIFFRACTION DIRECT ENERGY CONVERTERS ELECTRON MICROSCOPY ELEMENTS FABRICATION HEAT TREATMENTS INDIUM INDIUM COMPOUNDS INDIUM SELENIDE SOLAR CELLS INDIUM SELENIDES METALS MICROSCOPY MORPHOLOGY PHOTOELECTRIC CELLS PHOTOELECTRIC EFFECT PHOTOELECTROMAGNETIC EFFECTS PHOTOVOLTAIC CELLS SCANNING ELECTRON MICROSCOPY SCATTERING SELENIDES SELENIUM SELENIUM COMPOUNDS SEMIMETALS SOLAR CELLS SOLAR ENERGY SOLAR EQUIPMENT STOICHIOMETRY SYNTHESIS THIN FILMS TRANSITION ELEMENT COMPOUNDS TRANSITION ELEMENTS X-RAY DIFFRACTION |
| title | Selenization of metallic Cu-In thin films for CuInSe sub 2 solar cells |
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