Transition metal chemistry of main group hydrazides. 4. Phosphorus hydrazido ferrocences as novel synthons to new iron(II)-palladium(II) heterotrimetallic organometallic compounds. Synthesis and characterization of palladium(II) chloride complexes of ferrocene functionalized phosphorus hydrazides. Single-crystal x-ray structures of C[sub 2]H[sub 5]OP(S)(NCH[sub 3]NCHCp[prime]FeCp)[sub 2] and C[sub 2]H[sub 5]OP(S)(NCH[sub 3]NCHCp[prime]FeCp)[sub 2]-PdCl[sub 2] [Cp[prime] = C[sub 5]H[sub 4], Cp =

The reactions of aryl-, alkyl-, and alkoxy-substituted phosphorus hydrazides, RP(E)(NMeNH[sub 2])[sub 2] (R = Ph, E = S, I; R = OEt, E = S, 2; R = Ph, E = O, 3; R = Et, E = O, 4; R = Me, E = O, 5) with ferrocenecarboxaldehyde gave metallocene-functionalized phosphorus hydrazides in good yields (appr...

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