Primary and secondary reaction pathways in ruthenium-catalyzed hydrocarbon synthesis

Residence time studies show that n-paraffins, {alpha}-olefins, and cis-2-olefins are primary products during hydrocarbon synthesis on Ru catalysts. Their formation, as well as that of branched isomers, is consistent with previously proposed surface reactions of alkyl groups on metal surfaces. Second...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1991-10, Vol.95 (20), p.7795-7804
Hauptverfasser:	Madon, Rostam J, Reyes, Sebastian C, Iglesia, Enrique
Format:	Artikel
Sprache:	eng
Schlagworte:	10 SYNTHETIC FUELS 100200 - Synthetic Fuels- Production- (1990-) ALKANES ALKENES CATALYSIS CATALYSTS CATALYTIC EFFECTS Catalytic reactions CHEMICAL REACTION YIELD CHEMICAL REACTIONS Chemistry DATA DEHYDROGENATION ELEMENTS Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry HETEROGENEOUS CATALYSIS HYDROCARBONS HYDROGENATION INFORMATION ISOMERIZATION MATHEMATICAL MODELS METALS NUMERICAL DATA ORGANIC COMPOUNDS PLATINUM METALS RUTHENIUM SYNTHESIS Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry TRANSITION ELEMENTS YIELDS
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