Ceramic Thin-Film Formation on Functionalized Interfaces Through Biomimetic Processing
Processing routes have been developed for the production of thin ceramic films through precipitation from aqueous solutions. The techniques are based on crystal nucleation and growth onto functionalized interfaces. Surface functionalization routes have been developed by the mimicking of schemes used...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 1994-04, Vol.264 (5155), p.48-55 |
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| creator | Bunker, B. C. Rieke, P. C. Tarasevich, B. J. Campbell, A. A. Fryxell, G. E. Graff, G. L. Song, L. Liu, J. Virden, J. W. McVay, G. L. |
| description | Processing routes have been developed for the production of thin ceramic films through precipitation from aqueous solutions. The techniques are based on crystal nucleation and growth onto functionalized interfaces. Surface functionalization routes have been developed by the mimicking of schemes used by organisms to produce complex ceramic composites such as teeth, bones, and shells. High-quality, dense polycrystalline films of oxides, hydroxides, and sulfides have now been prepared from "biomimetic" synthesis techniques. Ceramic films can be synthesized on plastics and other materials at temperatures below 100°C. As a low-temperature process in which water rather than organic solvents is used, this synthesis is environmentally benign. Nanocrystalline ceramics can be produced, sometimes with preferred crystallite orientation. The direct deposition of high-resolution patterned films has also been demonstrated. The process is well suited to the production of organic-inorganic composites. |
| doi_str_mv | 10.1126/science.264.5155.48 |
| format | Article |
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C. ; Rieke, P. C. ; Tarasevich, B. J. ; Campbell, A. A. ; Fryxell, G. E. ; Graff, G. L. ; Song, L. ; Liu, J. ; Virden, J. W. ; McVay, G. L.</creator><creatorcontrib>Bunker, B. C. ; Rieke, P. C. ; Tarasevich, B. J. ; Campbell, A. A. ; Fryxell, G. E. ; Graff, G. L. ; Song, L. ; Liu, J. ; Virden, J. W. ; McVay, G. L.</creatorcontrib><description>Processing routes have been developed for the production of thin ceramic films through precipitation from aqueous solutions. The techniques are based on crystal nucleation and growth onto functionalized interfaces. Surface functionalization routes have been developed by the mimicking of schemes used by organisms to produce complex ceramic composites such as teeth, bones, and shells. High-quality, dense polycrystalline films of oxides, hydroxides, and sulfides have now been prepared from "biomimetic" synthesis techniques. Ceramic films can be synthesized on plastics and other materials at temperatures below 100°C. As a low-temperature process in which water rather than organic solvents is used, this synthesis is environmentally benign. Nanocrystalline ceramics can be produced, sometimes with preferred crystallite orientation. The direct deposition of high-resolution patterned films has also been demonstrated. The process is well suited to the production of organic-inorganic composites.</description><identifier>ISSN: 0036-8075</identifier><identifier>EISSN: 1095-9203</identifier><identifier>DOI: 10.1126/science.264.5155.48</identifier><identifier>PMID: 17778133</identifier><identifier>CODEN: SCIEAS</identifier><language>eng</language><publisher>Washington, DC: American Society for the Advancement of Science</publisher><subject>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication ; Applied sciences ; Biomimetic materials ; BIOMIMETIC PROCESSES ; Biomimetics ; Building materials. Ceramics. 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C.</creatorcontrib><creatorcontrib>Rieke, P. C.</creatorcontrib><creatorcontrib>Tarasevich, B. J.</creatorcontrib><creatorcontrib>Campbell, A. A.</creatorcontrib><creatorcontrib>Fryxell, G. E.</creatorcontrib><creatorcontrib>Graff, G. L.</creatorcontrib><creatorcontrib>Song, L.</creatorcontrib><creatorcontrib>Liu, J.</creatorcontrib><creatorcontrib>Virden, J. W.</creatorcontrib><creatorcontrib>McVay, G. L.</creatorcontrib><title>Ceramic Thin-Film Formation on Functionalized Interfaces Through Biomimetic Processing</title><title>Science (American Association for the Advancement of Science)</title><addtitle>Science</addtitle><description>Processing routes have been developed for the production of thin ceramic films through precipitation from aqueous solutions. The techniques are based on crystal nucleation and growth onto functionalized interfaces. Surface functionalization routes have been developed by the mimicking of schemes used by organisms to produce complex ceramic composites such as teeth, bones, and shells. High-quality, dense polycrystalline films of oxides, hydroxides, and sulfides have now been prepared from "biomimetic" synthesis techniques. Ceramic films can be synthesized on plastics and other materials at temperatures below 100°C. As a low-temperature process in which water rather than organic solvents is used, this synthesis is environmentally benign. Nanocrystalline ceramics can be produced, sometimes with preferred crystallite orientation. The direct deposition of high-resolution patterned films has also been demonstrated. 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Glasses</subject><subject>Ceramic industries</subject><subject>Ceramic materials</subject><subject>CERAMICS</subject><subject>Chemical industry and chemicals</subject><subject>Coatings</subject><subject>Crystals</subject><subject>DEPOSITION</subject><subject>Dielectric films</subject><subject>ENVIRONMENTAL IMPACTS</subject><subject>Exact sciences and technology</subject><subject>Functional groups</subject><subject>Material films</subject><subject>MATERIALS SCIENCE</subject><subject>Miscellaneous</subject><subject>Nucleation</subject><subject>PRODUCTION</subject><subject>Solubility</subject><subject>Supersaturation</subject><subject>Technical ceramics</subject><subject>THIN FILMS</subject><subject>Tin oxides</subject><issn>0036-8075</issn><issn>1095-9203</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqN00Fr2zAUB3AzNtau2yfYGGEMtkOdSZZlycc2LFkgLIN1vQpVenJUbKmVZNj26aeQ0BHIIdhg2e_3dHj6uyjeYjTFuGq-RGXBKZhWTT2lmNJpzZ8V5xi1tGwrRJ4X5wiRpuSI0bPiVYz3COVaS14WZ5gxxjEh58XtDIIcrJrcbKwr57YfJnMfBpmsd5N8z0entmvZ27-gJ0uXIBipIOaG4MduM7m2frADpLzHj-BzJVrXvS5eGNlHeLN_XhS_5l9vZt_K1XqxnF2tSsUwT-Ud11qTGnCLdF3p_MYQUNMYpgBMRRFmkkhec9xWWjVUmZobYmpCW800JeSi-LDb18dkRZ5IArVR3jlQSTDcNLzBGX3aoYfgH0eISQw2Kuh76cCPUTBCcNsSUmV5uZOd7EFYZ3wKUnXg8pB678DY_PkKU4IqxuvMyyM8XxrySI_5zwc-kwS_UyfHGMXy5_eT6fr2ZHq9OJXyxeqAXh6jyvc9dCDyKc7WB5zsuAo-xgBGPAQ7yPBHYCS2cRX7uIocV7GNq6h57nq_P5nxbgD9v2efzww-7oGMSvYmSKdsfHI1QrzCKLN3O3Yfkw9P5YpzwvOv8A9Y5_j2</recordid><startdate>19940401</startdate><enddate>19940401</enddate><creator>Bunker, B. 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L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ceramic Thin-Film Formation on Functionalized Interfaces Through Biomimetic Processing</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>1994-04-01</date><risdate>1994</risdate><volume>264</volume><issue>5155</issue><spage>48</spage><epage>55</epage><pages>48-55</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><coden>SCIEAS</coden><abstract>Processing routes have been developed for the production of thin ceramic films through precipitation from aqueous solutions. The techniques are based on crystal nucleation and growth onto functionalized interfaces. Surface functionalization routes have been developed by the mimicking of schemes used by organisms to produce complex ceramic composites such as teeth, bones, and shells. 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| fulltext | fulltext |
| identifier | ISSN: 0036-8075 |
| ispartof | Science (American Association for the Advancement of Science), 1994-04, Vol.264 (5155), p.48-55 |
| issn | 0036-8075 1095-9203 |
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| recordid | cdi_osti_scitechconnect_7166861 |
| source | American Association for the Advancement of Science; Jstor Complete Legacy |
| subjects | 360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication Applied sciences Biomimetic materials BIOMIMETIC PROCESSES Biomimetics Building materials. Ceramics. Glasses Ceramic industries Ceramic materials CERAMICS Chemical industry and chemicals Coatings Crystals DEPOSITION Dielectric films ENVIRONMENTAL IMPACTS Exact sciences and technology Functional groups Material films MATERIALS SCIENCE Miscellaneous Nucleation PRODUCTION Solubility Supersaturation Technical ceramics THIN FILMS Tin oxides |
| title | Ceramic Thin-Film Formation on Functionalized Interfaces Through Biomimetic Processing |
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