Lateral diffusion of an adsorbate at a chromatographic C(18)/water interface

The first measurement of the lateral diffusion coefficient of an adsorbate on a chromatographic surface is described. Pattern-photobleaching/fluorescence-recovery was used to measure the lateral diffusion coefficient of acridine orange at the interface of water and a C18 chromatographic surface.

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Veröffentlicht in:Analytical chemistry (Washington) 1994-05, Vol.66 (10), p.1708
Hauptverfasser: Zulli, Steven L, Kovaleski, John M, Zhu, X Ron, Harris, Joel M, Wirth, Mary J
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container_issue 10
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container_title Analytical chemistry (Washington)
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creator Zulli, Steven L
Kovaleski, John M
Zhu, X Ron
Harris, Joel M
Wirth, Mary J
description The first measurement of the lateral diffusion coefficient of an adsorbate on a chromatographic surface is described. Pattern-photobleaching/fluorescence-recovery was used to measure the lateral diffusion coefficient of acridine orange at the interface of water and a C18 chromatographic surface.
doi_str_mv 10.1021/ac00082a018
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subjects 400105 - Separation Procedures
400201 - Chemical & Physicochemical Properties
400500 - Photochemistry
ACRIDINE ORANGE
ACRIDINES
ADSORPTION
ALKANES
AMINES
AROMATICS
AZAARENES
AZINES
Chemistry
CHROMATOGRAPHY
CYCLOALKANES
DECALIN
DIFFUSION
DYES
FLUORESCENCE
HETEROCYCLIC COMPOUNDS
HEXADECANE
HOLOGRAPHY
HYDROCARBONS
HYDROGEN COMPOUNDS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
INTERFACES
LASERS
LUMINESCENCE
Molecules
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PYRIDINES
Scientific imaging
SEPARATION PROCESSES
SORPTION
WATER
title Lateral diffusion of an adsorbate at a chromatographic C(18)/water interface
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