H/D isotope effects in water radiolysis. 3. Atomic hydrogen in acidic H sub 2 O/D sub 2 O mixtures. [Accelerated electrons]

The authors present measurements of the EPR spectra of H and D atoms immediately (30-50 ns) following pulse radiolysis of acidic H{sub 2}O/D{sub 2}O mixtures with 3-MeV electrons. The spectra exhibit a low-field emission/high-field absorption (E/A) polarization pattern of chemically induced dynamic...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1991-11, Vol.95:23
Hauptverfasser:	Ping Han, Bartels, D.M.
Format:	Artikel
Sprache:	eng
Schlagworte:	400202 - Isotope Effects, Isotope Exchange, & Isotope Separation 400600 - Radiation Chemistry BEAMS CHEMICAL RADIATION EFFECTS CHEMICAL REACTIONS DECOMPOSITION DISSOCIATION ELECTRON BEAMS ELECTRONS ELEMENTARY PARTICLES ENERGY LEVELS EXCITED STATES FERMIONS HEAVY WATER HYDRATION HYDROGEN COMPOUNDS INORGANIC ACIDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE EFFECTS LEPTON BEAMS LEPTONS OXYGEN COMPOUNDS PARTICLE BEAMS RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY RADIATION EFFECTS RADICALS RADIOLYSIS SOLVATED ELECTRONS SOLVATION WATER
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