Inhibition of C-H and C-O bond activation by surface oxygen: stabilization of surface phenoxide in the reaction of phenol on oxygen-precovered Mo(110)

Inhibition of C-H and C-O bond activation by surface oxygen: stabilization of surface phenoxide in the reaction of phenol on oxygen-precovered Mo(110)

The presence of surface oxygen on Mo(110) is shown to increase the kinetic stability of surface phenoxide formed after saturation phenol exposure with respect to decomposition. Temperature-programmed reaction and x-ray photoelectron spectroscopies have been used to study the reactions of phenol (C{s...

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Veröffentlicht in:Journal of the American Chemical Society 1989-06, Vol.111 (12), p.4233-4239
Hauptverfasser: SERAFIN, J. G, FRIEND, C. M
Format: Artikel
Sprache:eng
Schlagworte:
360104 - Metals & Alloys- Physical Properties
400000 - Chemistry
400201 - Chemical & Physicochemical Properties
AROMATICS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
Chemistry
DATA
DATA ANALYSIS
ELEMENTS
Exact sciences and technology
EXPERIMENTAL DATA
HYDROXY COMPOUNDS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
KINETICS
Kinetics and mechanisms
MATERIALS SCIENCE
MEASURING INSTRUMENTS
MEASURING METHODS
METALS
MOLYBDENUM
NONMETALS
NUMERICAL DATA
Organic chemistry
ORGANIC COMPOUNDS
OXYGEN
PHENOL
PHENOLS
REACTION KINETICS
Reactivity and mechanisms
SURFACE TREATMENTS
TRANSITION ELEMENTS
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