A new class of room temperature luminescent organometallic complexes: luminescence and photophysical properties of permethylscandocene chloride in fluid solution
The search for organometallic complexes that emit in fluid solution at room temperature has been intensely pursued for the past 35 years because of the importance of an understanding of excited-state properties to the areas of solar energy conversion and photoassisted catalysis. Data are presented h...
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| Veröffentlicht in: | Journal of the American Chemical Society 1989-11, Vol.111 (24), p.8947-8948 |
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| container_end_page | 8948 |
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| container_issue | 24 |
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| container_title | Journal of the American Chemical Society |
| container_volume | 111 |
| creator | Pfennig, Brian W Thompson, Mark E Bocarsly, Andrew B |
| description | The search for organometallic complexes that emit in fluid solution at room temperature has been intensely pursued for the past 35 years because of the importance of an understanding of excited-state properties to the areas of solar energy conversion and photoassisted catalysis. Data are presented here on the photophysics of the d{sup 0} first row transition metal complex Cp*{sub 2}ScCl (Cp* = pentamethylcyclopentadienyl). To the best of their knowledge, this represents a new class of organometallic transition-metal complexes having no aromatic amine ligands that luminesce at room temperature in fluid solution. |
| doi_str_mv | 10.1021/ja00206a044 |
| format | Article |
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Data are presented here on the photophysics of the d{sup 0} first row transition metal complex Cp*{sub 2}ScCl (Cp* = pentamethylcyclopentadienyl). 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Am. Chem. Soc</addtitle><description>The search for organometallic complexes that emit in fluid solution at room temperature has been intensely pursued for the past 35 years because of the importance of an understanding of excited-state properties to the areas of solar energy conversion and photoassisted catalysis. Data are presented here on the photophysics of the d{sup 0} first row transition metal complex Cp*{sub 2}ScCl (Cp* = pentamethylcyclopentadienyl). To the best of their knowledge, this represents a new class of organometallic transition-metal complexes having no aromatic amine ligands that luminesce at room temperature in fluid solution.</description><subject>140500 - Solar Energy Conversion</subject><subject>360104 - Metals & Alloys- Physical Properties</subject><subject>400500 - Photochemistry</subject><subject>Atomic and molecular physics</subject><subject>CHEMISTRY</subject><subject>COMPLEXES</subject><subject>CONVERSION</subject><subject>DATA</subject><subject>DATA ANALYSIS</subject><subject>ENERGY CONVERSION</subject><subject>ENERGY LEVELS</subject><subject>Exact sciences and technology</subject><subject>EXCITED STATES</subject><subject>EXPERIMENTAL DATA</subject><subject>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MATERIALS SCIENCE</subject><subject>MEASURING INSTRUMENTS</subject><subject>MEASURING METHODS</subject><subject>Molecular properties and interactions with photons</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANOMETALLIC COMPOUNDS</subject><subject>PHOTOCHEMISTRY</subject><subject>Physics</subject><subject>SCANDIUM COMPLEXES</subject><subject>SOLAR ENERGY</subject><subject>SOLAR ENERGY CONVERSION</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><recordid>eNpt0cGOFCEQANCO0cRx9eQPEBPjwbQCTQPjbbPZdTdOoomjHglDFzYjDR2g487n-KeibXQPnoDUqwKqmuYpwa8IpuT1UWNMMdeYsXvNhvQUtz2h_H6zwTXQCsm7h82jnI_1yKgkm-bHOQrwHRmvc0bRohTjhApMMyRdlgTIL5MLkA2EgmL6qkOcoGjvnUEmTrOHW8hv7igDSIcBzWMscR5P2Rnt0ZxiLVgc_L6jbmuN8eSzqTTWJEBm9DG5AZALyPrFDShHvxQXw-PmgdU-w5M_61nz6epyf3Hd7t6_vbk437W662VptxjY0JEeb4XRktFDJ7gBams7DpyanukOhoMlkglOhKBWbsEKyaxkRnPOu7Pm2Vo35uJUNq6AGU0MAUxRgvRSClbRyxWZFHNOYNWc3KTTSRGsfo1A3RlB1c9XPev6VW-TDsblfylbIbuO9tW1q3O5wO3fuE7fFBed6NX-w0d1xd7t2JftXn2u_sXqtcnqGJcUamP--4KfyCOmGw</recordid><startdate>19891101</startdate><enddate>19891101</enddate><creator>Pfennig, Brian W</creator><creator>Thompson, Mark E</creator><creator>Bocarsly, Andrew B</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19891101</creationdate><title>A new class of room temperature luminescent organometallic complexes: luminescence and photophysical properties of permethylscandocene chloride in fluid solution</title><author>Pfennig, Brian W ; Thompson, Mark E ; Bocarsly, Andrew B</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a358t-90e4d315097ca842b376ce2f206b62c54a3edbf184761772f89ef784f84ca6663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>140500 - Solar Energy Conversion</topic><topic>360104 - Metals & Alloys- Physical Properties</topic><topic>400500 - Photochemistry</topic><topic>Atomic and molecular physics</topic><topic>CHEMISTRY</topic><topic>COMPLEXES</topic><topic>CONVERSION</topic><topic>DATA</topic><topic>DATA ANALYSIS</topic><topic>ENERGY CONVERSION</topic><topic>ENERGY LEVELS</topic><topic>Exact sciences and technology</topic><topic>EXCITED STATES</topic><topic>EXPERIMENTAL DATA</topic><topic>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MATERIALS SCIENCE</topic><topic>MEASURING INSTRUMENTS</topic><topic>MEASURING METHODS</topic><topic>Molecular properties and interactions with photons</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANOMETALLIC COMPOUNDS</topic><topic>PHOTOCHEMISTRY</topic><topic>Physics</topic><topic>SCANDIUM COMPLEXES</topic><topic>SOLAR ENERGY</topic><topic>SOLAR ENERGY CONVERSION</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pfennig, Brian W</creatorcontrib><creatorcontrib>Thompson, Mark E</creatorcontrib><creatorcontrib>Bocarsly, Andrew B</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pfennig, Brian W</au><au>Thompson, Mark E</au><au>Bocarsly, Andrew B</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new class of room temperature luminescent organometallic complexes: luminescence and photophysical properties of permethylscandocene chloride in fluid solution</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>1989-11-01</date><risdate>1989</risdate><volume>111</volume><issue>24</issue><spage>8947</spage><epage>8948</epage><pages>8947-8948</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>The search for organometallic complexes that emit in fluid solution at room temperature has been intensely pursued for the past 35 years because of the importance of an understanding of excited-state properties to the areas of solar energy conversion and photoassisted catalysis. Data are presented here on the photophysics of the d{sup 0} first row transition metal complex Cp*{sub 2}ScCl (Cp* = pentamethylcyclopentadienyl). To the best of their knowledge, this represents a new class of organometallic transition-metal complexes having no aromatic amine ligands that luminesce at room temperature in fluid solution.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ja00206a044</doi><tpages>2</tpages></addata></record> |
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| identifier | ISSN: 0002-7863 |
| ispartof | Journal of the American Chemical Society, 1989-11, Vol.111 (24), p.8947-8948 |
| issn | 0002-7863 1520-5126 |
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| source | ACS Publications |
| subjects | 140500 - Solar Energy Conversion 360104 - Metals & Alloys- Physical Properties 400500 - Photochemistry Atomic and molecular physics CHEMISTRY COMPLEXES CONVERSION DATA DATA ANALYSIS ENERGY CONVERSION ENERGY LEVELS Exact sciences and technology EXCITED STATES EXPERIMENTAL DATA Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE MEASURING INSTRUMENTS MEASURING METHODS Molecular properties and interactions with photons NUMERICAL DATA ORGANIC COMPOUNDS ORGANOMETALLIC COMPOUNDS PHOTOCHEMISTRY Physics SCANDIUM COMPLEXES SOLAR ENERGY SOLAR ENERGY CONVERSION TRANSITION ELEMENT COMPLEXES |
| title | A new class of room temperature luminescent organometallic complexes: luminescence and photophysical properties of permethylscandocene chloride in fluid solution |
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