Samarium-promoted cyclopropanation of allylic alcohols

The use of samarium/mercury amalgam in conjunction with diiodomethane or chloroiodomethane to generate samarium carbenoids for the efficient cyclopropanation of allylic alcohols is discussed. These hydroxyl-directed cyclopropanations occur under mild conditions and allow a wide range of substitution...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Journal of organic chemistry 1989-07, Vol.54 (15), p.3525-3532
Hauptverfasser:	Molander, Gary A, Harring, Lori S
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALCOHOLS ALKANES Chemistry CYCLOALKANES DATA DATA ANALYSIS ELEMENTS Exact sciences and technology EXPERIMENTAL DATA HYDROCARBONS HYDROXY COMPOUNDS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MEASURING INSTRUMENTS MEASURING METHODS MERCURY METALS NUMERICAL DATA Organic chemistry ORGANIC COMPOUNDS RARE EARTHS SAMARIUM SYNTHESIS
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Schreiben Sie den ersten Kommentar!