Terminal and new bridging coordination of methylguanidine, arginine, and canavanine to platinum(II). The first crystallographic study of bonding between a transition metal and a guanidine ligand

The compound (Pt(trpy)Cl)Cl reacts with the guanidine-containing compounds methylguanidine, arginine, and canavanine to form the yellow monometallic complexes (Pt(trpy)MeGua){sup 2+}, (Pt(trpy)ArgH){sup 2+}, and (Pt(trpy)CanH){sup 2+} and the red bimetallic complexes ((Pt(trpy)){sub 2}MeGua){sup 4+}...

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Veröffentlicht in:	Inorganic chemistry 1990-03, Vol.29 (5), p.918-926
Hauptverfasser:	Ratilla, Eva Marie A, Scott, Brian K, Moxness, Michael S, Kostic, Nenad M
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties AMINO ACIDS ARGININE CARBONIC ACID DERIVATIVES CARBOXYLIC ACIDS CHEMICAL BONDS COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA Exact sciences and technology EXPERIMENTAL DATA GUANIDINES INFORMATION Inorganic compounds INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Metal complexes NUMERICAL DATA ORGANIC ACIDS ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANOMETALLIC COMPOUNDS Physics PLATINUM COMPLEXES Structure of solids and liquids crystallography Structure of specific crystalline solids TRANSITION ELEMENT COMPLEXES
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