A synchrotron single crystal X-ray structure determination of (NH sub 4 ) sub 3 Mo sub 4 P sub 3 O sub 16 : A microporous molybdenum phosphate with Mo sub 4 O sub 4 sup 6+ cubes

Reaction of MoO{sub 3}, Mo, (NH{sub 4}){sub 2}HPO{sub 4}, H{sub 3}PO{sub 4}, and H{sub 2}O in a mole ratio of 1.4:1:3.6:6:120 at 360C for 16 hr gives a nearly quantitative yield of black cubes of (NH{sub 4}){sub 3}Mo{sub 4}P{sub 3}O{sub 16} (1). The structure of (1) was solved from data collected on...

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