Phase Transformations in Monoclinic Zirconia Caused by Milling and Subsequent Annealing
Monoclinic ZrO2 has been milled for various times down to a crystallite size of 145 Å. Using the time‐differential perturbed‐angular‐correlation technique, it was possible to associate the resulting growing amount of disordered material with two different, very distributed and milling‐time‐dependent...
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| Veröffentlicht in: | Journal of the American Ceramic Society 1994-06, Vol.77 (6), p.1525-1530 |
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| container_title | Journal of the American Ceramic Society |
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| creator | Scian, Alberto N. Aglietti, Esteban F. Caracoche, María C. Rivas, Patricia C. Pasquevich, Alberto F. López García, Alberto R. |
| description | Monoclinic ZrO2 has been milled for various times down to a crystallite size of 145 Å. Using the time‐differential perturbed‐angular‐correlation technique, it was possible to associate the resulting growing amount of disordered material with two different, very distributed and milling‐time‐dependent hyperfine interactions: one (Y) of quadrupole frequency similar to that of tetragonal zirconia after long milling, the other (X) one of a quadrupole frequency similar to that of monoclinic zirconia at shorter milling times. Upon annealing, all samples showed the recovery of the crystalline monoclinic phase at the expense of the disordered structures. In samples milled for shorter times, the (Y) interaction emerges as an ordered crystallization product, upon annealing at temperatures which depend nearly linearly on the crystallite size. |
| doi_str_mv | 10.1111/j.1151-2916.1994.tb09752.x |
| format | Article |
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Using the time‐differential perturbed‐angular‐correlation technique, it was possible to associate the resulting growing amount of disordered material with two different, very distributed and milling‐time‐dependent hyperfine interactions: one (Y) of quadrupole frequency similar to that of tetragonal zirconia after long milling, the other (X) one of a quadrupole frequency similar to that of monoclinic zirconia at shorter milling times. Upon annealing, all samples showed the recovery of the crystalline monoclinic phase at the expense of the disordered structures. In samples milled for shorter times, the (Y) interaction emerges as an ordered crystallization product, upon annealing at temperatures which depend nearly linearly on the crystallite size.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1151-2916.1994.tb09752.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies ; ANNEALING ; Applied sciences ; Building materials. Ceramics. Glasses ; Ceramic industries ; CHALCOGENIDES ; Chemical industry and chemicals ; CRYSTAL-PHASE TRANSFORMATIONS ; DATA ; Exact sciences and technology ; EXPERIMENTAL DATA ; HEAT TREATMENTS ; INFORMATION ; MACHINING ; MATERIALS SCIENCE ; MILLING ; Miscellaneous ; NUMERICAL DATA ; OXIDES ; OXYGEN COMPOUNDS ; PHASE TRANSFORMATIONS ; Technical ceramics ; TRANSITION ELEMENT COMPOUNDS ; ZIRCONIUM COMPOUNDS ; ZIRCONIUM OXIDES</subject><ispartof>Journal of the American Ceramic Society, 1994-06, Vol.77 (6), p.1525-1530</ispartof><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4795-e5eac53908f5cd6346bae469bcb5fd3abb7d8ce700d534291c2a368f00033b183</citedby><cites>FETCH-LOGICAL-c4795-e5eac53908f5cd6346bae469bcb5fd3abb7d8ce700d534291c2a368f00033b183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fj.1151-2916.1994.tb09752.x$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fj.1151-2916.1994.tb09752.x$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4123157$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/7072158$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Scian, Alberto N.</creatorcontrib><creatorcontrib>Aglietti, Esteban F.</creatorcontrib><creatorcontrib>Caracoche, María C.</creatorcontrib><creatorcontrib>Rivas, Patricia C.</creatorcontrib><creatorcontrib>Pasquevich, Alberto F.</creatorcontrib><creatorcontrib>López García, Alberto R.</creatorcontrib><title>Phase Transformations in Monoclinic Zirconia Caused by Milling and Subsequent Annealing</title><title>Journal of the American Ceramic Society</title><description>Monoclinic ZrO2 has been milled for various times down to a crystallite size of 145 Å. Using the time‐differential perturbed‐angular‐correlation technique, it was possible to associate the resulting growing amount of disordered material with two different, very distributed and milling‐time‐dependent hyperfine interactions: one (Y) of quadrupole frequency similar to that of tetragonal zirconia after long milling, the other (X) one of a quadrupole frequency similar to that of monoclinic zirconia at shorter milling times. Upon annealing, all samples showed the recovery of the crystalline monoclinic phase at the expense of the disordered structures. In samples milled for shorter times, the (Y) interaction emerges as an ordered crystallization product, upon annealing at temperatures which depend nearly linearly on the crystallite size.</description><subject>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies</subject><subject>ANNEALING</subject><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>Ceramic industries</subject><subject>CHALCOGENIDES</subject><subject>Chemical industry and chemicals</subject><subject>CRYSTAL-PHASE TRANSFORMATIONS</subject><subject>DATA</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HEAT TREATMENTS</subject><subject>INFORMATION</subject><subject>MACHINING</subject><subject>MATERIALS SCIENCE</subject><subject>MILLING</subject><subject>Miscellaneous</subject><subject>NUMERICAL DATA</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHASE TRANSFORMATIONS</subject><subject>Technical ceramics</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>ZIRCONIUM COMPOUNDS</subject><subject>ZIRCONIUM OXIDES</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqVkM1uGyEUhVHVSnXTvgOKqu7G4WeAoataVuokctJIcRWpGwQM0-COIYWxYr99GY2VfdlcofNx7uEAcI7RHJdzsS2D4YpIzOdYyno-GCQFI_PDGzDD7CS9BTOEEKlEQ9B78CHnbbli2dQz8Hj_pLODm6RD7mLa6cHHkKEP8DaGaHsfvIW_fLIxeA2Xep9dC80R3vq-aL-hDi182Jvs_u5dGOAiBKdH4SN41-k-u0-neQZ-fr_cLK-q9Y_V9XKxrmwtJKscc9oyKlHTMdtyWnOjXc2lsYZ1LdXGiLaxTiDUMlqXv1iiKW-6kp9Sgxt6Bs4n35gHr7L1g7NPJWxwdlACCYLZCH2ZoOcUS848qJ3P1vW9Di7usyKcISK4LODXCbQp5pxcp56T3-l0VBipsXC1VWPhamxVjYWrU-HqUB5_Pm3R2eq-K5Van18dakwoZqJg3ybsxffu-B8L1M1ieYkZYcWimix8Htzh1UKnP4oLKph6vFspwVd3bEOu1Jr-A3KTpJ4</recordid><startdate>199406</startdate><enddate>199406</enddate><creator>Scian, Alberto N.</creator><creator>Aglietti, Esteban F.</creator><creator>Caracoche, María C.</creator><creator>Rivas, Patricia C.</creator><creator>Pasquevich, Alberto F.</creator><creator>López García, Alberto R.</creator><general>Blackwell Publishing Ltd</general><general>Blackwell</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>OTOTI</scope></search><sort><creationdate>199406</creationdate><title>Phase Transformations in Monoclinic Zirconia Caused by Milling and Subsequent Annealing</title><author>Scian, Alberto N. ; Aglietti, Esteban F. ; Caracoche, María C. ; Rivas, Patricia C. ; Pasquevich, Alberto F. ; López García, Alberto R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4795-e5eac53908f5cd6346bae469bcb5fd3abb7d8ce700d534291c2a368f00033b183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies</topic><topic>ANNEALING</topic><topic>Applied sciences</topic><topic>Building materials. Ceramics. Glasses</topic><topic>Ceramic industries</topic><topic>CHALCOGENIDES</topic><topic>Chemical industry and chemicals</topic><topic>CRYSTAL-PHASE TRANSFORMATIONS</topic><topic>DATA</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HEAT TREATMENTS</topic><topic>INFORMATION</topic><topic>MACHINING</topic><topic>MATERIALS SCIENCE</topic><topic>MILLING</topic><topic>Miscellaneous</topic><topic>NUMERICAL DATA</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHASE TRANSFORMATIONS</topic><topic>Technical ceramics</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>ZIRCONIUM COMPOUNDS</topic><topic>ZIRCONIUM OXIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Scian, Alberto N.</creatorcontrib><creatorcontrib>Aglietti, Esteban F.</creatorcontrib><creatorcontrib>Caracoche, María C.</creatorcontrib><creatorcontrib>Rivas, Patricia C.</creatorcontrib><creatorcontrib>Pasquevich, Alberto F.</creatorcontrib><creatorcontrib>López García, Alberto R.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>OSTI.GOV</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Scian, Alberto N.</au><au>Aglietti, Esteban F.</au><au>Caracoche, María C.</au><au>Rivas, Patricia C.</au><au>Pasquevich, Alberto F.</au><au>López García, Alberto R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Phase Transformations in Monoclinic Zirconia Caused by Milling and Subsequent Annealing</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>1994-06</date><risdate>1994</risdate><volume>77</volume><issue>6</issue><spage>1525</spage><epage>1530</epage><pages>1525-1530</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><coden>JACTAW</coden><abstract>Monoclinic ZrO2 has been milled for various times down to a crystallite size of 145 Å. Using the time‐differential perturbed‐angular‐correlation technique, it was possible to associate the resulting growing amount of disordered material with two different, very distributed and milling‐time‐dependent hyperfine interactions: one (Y) of quadrupole frequency similar to that of tetragonal zirconia after long milling, the other (X) one of a quadrupole frequency similar to that of monoclinic zirconia at shorter milling times. Upon annealing, all samples showed the recovery of the crystalline monoclinic phase at the expense of the disordered structures. In samples milled for shorter times, the (Y) interaction emerges as an ordered crystallization product, upon annealing at temperatures which depend nearly linearly on the crystallite size.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1994.tb09752.x</doi><tpages>6</tpages></addata></record> |
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| subjects | 360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies ANNEALING Applied sciences Building materials. Ceramics. Glasses Ceramic industries CHALCOGENIDES Chemical industry and chemicals CRYSTAL-PHASE TRANSFORMATIONS DATA Exact sciences and technology EXPERIMENTAL DATA HEAT TREATMENTS INFORMATION MACHINING MATERIALS SCIENCE MILLING Miscellaneous NUMERICAL DATA OXIDES OXYGEN COMPOUNDS PHASE TRANSFORMATIONS Technical ceramics TRANSITION ELEMENT COMPOUNDS ZIRCONIUM COMPOUNDS ZIRCONIUM OXIDES |
| title | Phase Transformations in Monoclinic Zirconia Caused by Milling and Subsequent Annealing |
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