Electrochemical treatment of mixed and hazardous wastes : oxidation of ethylene glycol and benzene by silver(II)
In the future, mediated electrochemical oxidation (MEO) may be used for the ambient temperature destruction of hazardous waste and for the conversion of mixed waste to low-level radioactive waste. The MEO of ethylene glycol and benzene, two model compounds, in an electrochemical reactor was studied....
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| Veröffentlicht in: | Journal of the Electrochemical Society 1992-03, Vol.139 (3), p.654-662 |
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| container_title | Journal of the Electrochemical Society |
| container_volume | 139 |
| creator | FARMER, J. C WANG, F. T HAWLEY-FEDDER, R. A LEWIS, P. R SUMMERS, L. J FOILES, L |
| description | In the future, mediated electrochemical oxidation (MEO) may be used for the ambient temperature destruction of hazardous waste and for the conversion of mixed waste to low-level radioactive waste. The MEO of ethylene glycol and benzene, two model compounds, in an electrochemical reactor was studied. The reactor had a rotating-cylinder anode that was operated well below the limiting current for Ag(II) generation. Rates of CO sub 2 generation were measured and used to calculate both destruction and current efficiencies for the process. Gas chromatography with mass spectrometry (GC/MS) was used to identify several reaction intermediates. A simple model was developed to predict the time dependence of CO sub 2 evolution. |
| doi_str_mv | 10.1149/1.2069280 |
| format | Article |
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C ; WANG, F. T ; HAWLEY-FEDDER, R. A ; LEWIS, P. R ; SUMMERS, L. J ; FOILES, L</creator><creatorcontrib>FARMER, J. C ; WANG, F. T ; HAWLEY-FEDDER, R. A ; LEWIS, P. R ; SUMMERS, L. J ; FOILES, L</creatorcontrib><description>In the future, mediated electrochemical oxidation (MEO) may be used for the ambient temperature destruction of hazardous waste and for the conversion of mixed waste to low-level radioactive waste. The MEO of ethylene glycol and benzene, two model compounds, in an electrochemical reactor was studied. The reactor had a rotating-cylinder anode that was operated well below the limiting current for Ag(II) generation. Rates of CO sub 2 generation were measured and used to calculate both destruction and current efficiencies for the process. Gas chromatography with mass spectrometry (GC/MS) was used to identify several reaction intermediates. 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| identifier | ISSN: 0013-4651 |
| ispartof | Journal of the Electrochemical Society, 1992-03, Vol.139 (3), p.654-662 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_osti_scitechconnect_7042391 |
| source | IOP Publishing Journals |
| subjects | 052001 - Nuclear Fuels- Waste Processing 400102 - Chemical & Spectral Procedures 400400 - Electrochemistry 664200 - Spectra of Atoms & Molecules & their Interactions with Photons- (1992-) ALCOHOLS AROMATICS ATOMIC AND MOLECULAR PHYSICS BENZENE CARBON COMPOUNDS CARBON DIOXIDE CARBON OXIDES CHALCOGENIDES CHEMICAL REACTIONS CHEMICAL REACTORS CHEMISTRY CHROMATOGRAPHY ELECTROCHEMISTRY ELEMENTS Exact sciences and technology GAS CHROMATOGRAPHY General and physical chemistry GLYCOLS HAZARDOUS MATERIALS HYDROCARBONS HYDROXY COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Kinetics and mechanism of reactions LOW-LEVEL RADIOACTIVE WASTES MANAGEMENT MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES MASS SPECTROSCOPY MATERIALS METALS ORGANIC COMPOUNDS ORGANIC POLYMERS OXIDATION OXIDES OXYGEN COMPOUNDS PLANNING POLYETHYLENE GLYCOLS POLYMERS PROCESSING RADIOACTIVE MATERIALS RADIOACTIVE WASTE MANAGEMENT RADIOACTIVE WASTE PROCESSING RADIOACTIVE WASTES SEPARATION PROCESSES SILVER SPECTROSCOPY TIME DEPENDENCE TRANSITION ELEMENTS WASTE MANAGEMENT WASTE PROCESSING WASTES |
| title | Electrochemical treatment of mixed and hazardous wastes : oxidation of ethylene glycol and benzene by silver(II) |
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