First analysis of the 3[nu][sub 9] [minus] [nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5], and 3[nu][sub 9] [minus] 2[nu][sub 9] bands of HNO[sub 3]: Torsional splitting in the [nu][sub 9] vibrational mode
Using Fourier transform spectra recorded at 25 and 12 [mu]m, it has been possible to perform the first analysis of the 3[nu][sub 9] [minus] 2[nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5] and 3[nu][sub 9] [minus] [nu][sub 9] hot bands of HNO[sub 3] located at 392.4 cm[sup [minus]1], 409.8 cm[sup [min...
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| Veröffentlicht in: | Journal of molecular spectroscopy 1994-07, Vol.166:1 |
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| container_title | Journal of molecular spectroscopy |
| container_volume | 166:1 |
| creator | Perrin, A. Flaud, J.M. Camy-Peyret, C. |
| description | Using Fourier transform spectra recorded at 25 and 12 [mu]m, it has been possible to perform the first analysis of the 3[nu][sub 9] [minus] 2[nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5] and 3[nu][sub 9] [minus] [nu][sub 9] hot bands of HNO[sub 3] located at 392.4 cm[sup [minus]1], 409.8 cm[sup [minus]1], and 830.4 cm[sup [minus]1], respectively. An accurate description of the torsional splitting in the [nu][sub 9] = 3 vibrational state was achieved, leading to the determination of the two torsional band centers E[sub [nu][sub g]=3.1] = 1,288.8451 cm[sup [minus]1] and E[sub [nu][sub g]=3.2] = 1,288.9036 cm[sup [minus]1] and to the first determination of the [nu][sub 9] torsional potential of HNO[sub 3]. Finally, the 4[nu][sub 9] [minus] 3[nu][sub 9], [nu][sub 5] + [nu][sub 9] [minus] 2[nu][sub 9], and [nu][sub 5] + [nu][sub 9] [minus] [nu][sub 9] hot bands were identified for the first time at 375.3 [minus] 376.1 cm[sup [minus]1], 447.2 cm[sup [minus]1] and 885.424 cm[sup [minus]1] respectively. |
| doi_str_mv | 10.1006/jmsp.1994.1187 |
| format | Article |
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An accurate description of the torsional splitting in the [nu][sub 9] = 3 vibrational state was achieved, leading to the determination of the two torsional band centers E[sub [nu][sub g]=3.1] = 1,288.8451 cm[sup [minus]1] and E[sub [nu][sub g]=3.2] = 1,288.9036 cm[sup [minus]1] and to the first determination of the [nu][sub 9] torsional potential of HNO[sub 3]. Finally, the 4[nu][sub 9] [minus] 3[nu][sub 9], [nu][sub 5] + [nu][sub 9] [minus] 2[nu][sub 9], and [nu][sub 5] + [nu][sub 9] [minus] [nu][sub 9] hot bands were identified for the first time at 375.3 [minus] 376.1 cm[sup [minus]1], 447.2 cm[sup [minus]1] and 885.424 cm[sup [minus]1] respectively.</description><identifier>ISSN: 0022-2852</identifier><identifier>EISSN: 1096-083X</identifier><identifier>DOI: 10.1006/jmsp.1994.1187</identifier><language>eng</language><publisher>United States</publisher><subject>540110 ; 540120 - Environment, Atmospheric- Chemicals Monitoring & Transport- (1990-) ; CHLOROFLUOROCARBONS ; DATA ; EARTH ATMOSPHERE ; ENERGY LEVELS ; ENVIRONMENTAL SCIENCES ; EXCITED STATES ; EXPERIMENTAL DATA ; FOURIER TRANSFORM SPECTROMETERS ; HYDROGEN COMPOUNDS ; INFORMATION ; INORGANIC ACIDS ; MEASURING INSTRUMENTS ; NITRIC ACID ; NUMERICAL DATA ; ORGANIC CHLORINE COMPOUNDS ; ORGANIC COMPOUNDS ; ORGANIC FLUORINE COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; ROTATIONAL STATES ; SPECTRA ; SPECTROMETERS ; VIBRATIONAL STATES</subject><ispartof>Journal of molecular spectroscopy, 1994-07, Vol.166:1</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/7036769$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Perrin, A.</creatorcontrib><creatorcontrib>Flaud, J.M.</creatorcontrib><creatorcontrib>Camy-Peyret, C.</creatorcontrib><title>First analysis of the 3[nu][sub 9] [minus] [nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5], and 3[nu][sub 9] [minus] 2[nu][sub 9] bands of HNO[sub 3]: Torsional splitting in the [nu][sub 9] vibrational mode</title><title>Journal of molecular spectroscopy</title><description>Using Fourier transform spectra recorded at 25 and 12 [mu]m, it has been possible to perform the first analysis of the 3[nu][sub 9] [minus] 2[nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5] and 3[nu][sub 9] [minus] [nu][sub 9] hot bands of HNO[sub 3] located at 392.4 cm[sup [minus]1], 409.8 cm[sup [minus]1], and 830.4 cm[sup [minus]1], respectively. An accurate description of the torsional splitting in the [nu][sub 9] = 3 vibrational state was achieved, leading to the determination of the two torsional band centers E[sub [nu][sub g]=3.1] = 1,288.8451 cm[sup [minus]1] and E[sub [nu][sub g]=3.2] = 1,288.9036 cm[sup [minus]1] and to the first determination of the [nu][sub 9] torsional potential of HNO[sub 3]. Finally, the 4[nu][sub 9] [minus] 3[nu][sub 9], [nu][sub 5] + [nu][sub 9] [minus] 2[nu][sub 9], and [nu][sub 5] + [nu][sub 9] [minus] [nu][sub 9] hot bands were identified for the first time at 375.3 [minus] 376.1 cm[sup [minus]1], 447.2 cm[sup [minus]1] and 885.424 cm[sup [minus]1] respectively.</description><subject>540110</subject><subject>540120 - Environment, Atmospheric- Chemicals Monitoring & Transport- (1990-)</subject><subject>CHLOROFLUOROCARBONS</subject><subject>DATA</subject><subject>EARTH ATMOSPHERE</subject><subject>ENERGY LEVELS</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>EXCITED STATES</subject><subject>EXPERIMENTAL DATA</subject><subject>FOURIER TRANSFORM SPECTROMETERS</subject><subject>HYDROGEN COMPOUNDS</subject><subject>INFORMATION</subject><subject>INORGANIC ACIDS</subject><subject>MEASURING INSTRUMENTS</subject><subject>NITRIC ACID</subject><subject>NUMERICAL DATA</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC FLUORINE COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>ROTATIONAL STATES</subject><subject>SPECTRA</subject><subject>SPECTROMETERS</subject><subject>VIBRATIONAL STATES</subject><issn>0022-2852</issn><issn>1096-083X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNqNzk9Lw0AQBfBFFIzVq-fFs4mzu-bPehVLT3rpoRBC2aRbOyXZLZmN4Hf0QxmiYA-Cnh48fsM8xq4FJAIgu9t3dEiE1veJEEV-wiIBOouhUKtTFgFIGcsilefsgmgPIESaq4h9zLGnwI0z7Tshcb_lYWe5Kt1QlTTUXFe87NANNOZPd_uHSEdh3OZ3JY_LemTT28Xzy9Sp6oEvfU_ox02cDi2GgO6Vo5uWHd--Yd2b8AU7v7GX7GxrWrJX3zljN_On5eMi9hRwTQ0G2-wa75xtwjoHleWZVv9Cn3KDb78</recordid><startdate>19940701</startdate><enddate>19940701</enddate><creator>Perrin, A.</creator><creator>Flaud, J.M.</creator><creator>Camy-Peyret, C.</creator><scope>OTOTI</scope></search><sort><creationdate>19940701</creationdate><title>First analysis of the 3[nu][sub 9] [minus] [nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5], and 3[nu][sub 9] [minus] 2[nu][sub 9] bands of HNO[sub 3]: Torsional splitting in the [nu][sub 9] vibrational mode</title><author>Perrin, A. ; Flaud, J.M. ; Camy-Peyret, C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_70367693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>540110</topic><topic>540120 - Environment, Atmospheric- Chemicals Monitoring & Transport- (1990-)</topic><topic>CHLOROFLUOROCARBONS</topic><topic>DATA</topic><topic>EARTH ATMOSPHERE</topic><topic>ENERGY LEVELS</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>EXCITED STATES</topic><topic>EXPERIMENTAL DATA</topic><topic>FOURIER TRANSFORM SPECTROMETERS</topic><topic>HYDROGEN COMPOUNDS</topic><topic>INFORMATION</topic><topic>INORGANIC ACIDS</topic><topic>MEASURING INSTRUMENTS</topic><topic>NITRIC ACID</topic><topic>NUMERICAL DATA</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC FLUORINE COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>ROTATIONAL STATES</topic><topic>SPECTRA</topic><topic>SPECTROMETERS</topic><topic>VIBRATIONAL STATES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Perrin, A.</creatorcontrib><creatorcontrib>Flaud, J.M.</creatorcontrib><creatorcontrib>Camy-Peyret, C.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of molecular spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Perrin, A.</au><au>Flaud, J.M.</au><au>Camy-Peyret, C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>First analysis of the 3[nu][sub 9] [minus] [nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5], and 3[nu][sub 9] [minus] 2[nu][sub 9] bands of HNO[sub 3]: Torsional splitting in the [nu][sub 9] vibrational mode</atitle><jtitle>Journal of molecular spectroscopy</jtitle><date>1994-07-01</date><risdate>1994</risdate><volume>166:1</volume><issn>0022-2852</issn><eissn>1096-083X</eissn><abstract>Using Fourier transform spectra recorded at 25 and 12 [mu]m, it has been possible to perform the first analysis of the 3[nu][sub 9] [minus] 2[nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5] and 3[nu][sub 9] [minus] [nu][sub 9] hot bands of HNO[sub 3] located at 392.4 cm[sup [minus]1], 409.8 cm[sup [minus]1], and 830.4 cm[sup [minus]1], respectively. An accurate description of the torsional splitting in the [nu][sub 9] = 3 vibrational state was achieved, leading to the determination of the two torsional band centers E[sub [nu][sub g]=3.1] = 1,288.8451 cm[sup [minus]1] and E[sub [nu][sub g]=3.2] = 1,288.9036 cm[sup [minus]1] and to the first determination of the [nu][sub 9] torsional potential of HNO[sub 3]. Finally, the 4[nu][sub 9] [minus] 3[nu][sub 9], [nu][sub 5] + [nu][sub 9] [minus] 2[nu][sub 9], and [nu][sub 5] + [nu][sub 9] [minus] [nu][sub 9] hot bands were identified for the first time at 375.3 [minus] 376.1 cm[sup [minus]1], 447.2 cm[sup [minus]1] and 885.424 cm[sup [minus]1] respectively.</abstract><cop>United States</cop><doi>10.1006/jmsp.1994.1187</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2852 |
| ispartof | Journal of molecular spectroscopy, 1994-07, Vol.166:1 |
| issn | 0022-2852 1096-083X |
| language | eng |
| recordid | cdi_osti_scitechconnect_7036769 |
| source | Elsevier ScienceDirect Journals |
| subjects | 540110 540120 - Environment, Atmospheric- Chemicals Monitoring & Transport- (1990-) CHLOROFLUOROCARBONS DATA EARTH ATMOSPHERE ENERGY LEVELS ENVIRONMENTAL SCIENCES EXCITED STATES EXPERIMENTAL DATA FOURIER TRANSFORM SPECTROMETERS HYDROGEN COMPOUNDS INFORMATION INORGANIC ACIDS MEASURING INSTRUMENTS NITRIC ACID NUMERICAL DATA ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC FLUORINE COMPOUNDS ORGANIC HALOGEN COMPOUNDS ROTATIONAL STATES SPECTRA SPECTROMETERS VIBRATIONAL STATES |
| title | First analysis of the 3[nu][sub 9] [minus] [nu][sub 9], 3[nu][sub 9] [minus] [nu][sub 5], and 3[nu][sub 9] [minus] 2[nu][sub 9] bands of HNO[sub 3]: Torsional splitting in the [nu][sub 9] vibrational mode |
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