Combustion Synthesis of Silicon Carbide in Nitrogen Atmosphere

Fine SiC powders were synthesized by burning the mixed reactionts Si and C in a nitrogen atmosphere of 3 to 10 MPa. The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. T...

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Veröffentlicht in:Journal of the American Ceramic Society 1989-09, Vol.72 (9), p.1735-1738
Hauptverfasser: Yamada, Osamu, Hirao, Kiyoshi, Koizumi, Mitsue, Miyamoto, Yoshinari
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container_end_page 1738
container_issue 9
container_start_page 1735
container_title Journal of the American Ceramic Society
container_volume 72
creator Yamada, Osamu
Hirao, Kiyoshi
Koizumi, Mitsue
Miyamoto, Yoshinari
description Fine SiC powders were synthesized by burning the mixed reactionts Si and C in a nitrogen atmosphere of 3 to 10 MPa. The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.
doi_str_mv 10.1111/j.1151-2916.1989.tb06315.x
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The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1151-2916.1989.tb06315.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>360201 - Ceramics, Cermets, &amp; Refractories- Preparation &amp; Fabrication ; 400800 - Combustion, Pyrolysis, &amp; High-Temperature Chemistry ; Applied sciences ; Building materials. Ceramics. 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The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.</description><subject>360201 - Ceramics, Cermets, &amp; Refractories- Preparation &amp; Fabrication</subject><subject>400800 - Combustion, Pyrolysis, &amp; High-Temperature Chemistry</subject><subject>Applied sciences</subject><subject>Building materials. Ceramics. 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The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1989.tb06315.x</doi><tpages>4</tpages></addata></record>
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subjects 360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication
400800 - Combustion, Pyrolysis, & High-Temperature Chemistry
Applied sciences
Building materials. Ceramics. Glasses
CARBIDES
CARBON COMPOUNDS
Ceramic industries
Chemical industry and chemicals
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
COMBUSTION
ELEMENTS
Exact sciences and technology
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
KINETICS
MATERIALS SCIENCE
NITROGEN
NONMETALS
OXIDATION
POWDERS
REACTION KINETICS
silicon carbide
SILICON CARBIDES
SILICON COMPOUNDS
SYNTHESIS
Technical ceramics
THERMOCHEMICAL PROCESSES
VERY HIGH TEMPERATURE
title Combustion Synthesis of Silicon Carbide in Nitrogen Atmosphere
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