Combustion Synthesis of Silicon Carbide in Nitrogen Atmosphere
Fine SiC powders were synthesized by burning the mixed reactionts Si and C in a nitrogen atmosphere of 3 to 10 MPa. The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. T...
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Veröffentlicht in: | Journal of the American Ceramic Society 1989-09, Vol.72 (9), p.1735-1738 |
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container_title | Journal of the American Ceramic Society |
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creator | Yamada, Osamu Hirao, Kiyoshi Koizumi, Mitsue Miyamoto, Yoshinari |
description | Fine SiC powders were synthesized by burning the mixed reactionts Si and C in a nitrogen atmosphere of 3 to 10 MPa. The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure. |
doi_str_mv | 10.1111/j.1151-2916.1989.tb06315.x |
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The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1151-2916.1989.tb06315.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication ; 400800 - Combustion, Pyrolysis, & High-Temperature Chemistry ; Applied sciences ; Building materials. Ceramics. 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The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.</description><subject>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication</subject><subject>400800 - Combustion, Pyrolysis, & High-Temperature Chemistry</subject><subject>Applied sciences</subject><subject>Building materials. Ceramics. Glasses</subject><subject>CARBIDES</subject><subject>CARBON COMPOUNDS</subject><subject>Ceramic industries</subject><subject>Chemical industry and chemicals</subject><subject>CHEMICAL REACTION KINETICS</subject><subject>CHEMICAL REACTIONS</subject><subject>COMBUSTION</subject><subject>ELEMENTS</subject><subject>Exact sciences and technology</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>KINETICS</subject><subject>MATERIALS SCIENCE</subject><subject>NITROGEN</subject><subject>NONMETALS</subject><subject>OXIDATION</subject><subject>POWDERS</subject><subject>REACTION KINETICS</subject><subject>silicon carbide</subject><subject>SILICON CARBIDES</subject><subject>SILICON COMPOUNDS</subject><subject>SYNTHESIS</subject><subject>Technical ceramics</subject><subject>THERMOCHEMICAL PROCESSES</subject><subject>VERY HIGH TEMPERATURE</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1989</creationdate><recordtype>article</recordtype><sourceid>K30</sourceid><recordid>eNqVkEuP0zAUhS0E0pSB_xANiF2KHb9iFogqGgqjqiDNg6XlODZ1SeOO7Yr234-jVLNghzdXvv58zr0HgCsE5yifj9tcKCorgdgciVrMUwsZRnR-fAFmiJ6fXoIZhLAqeV3BC_A6xm2-ZpzMwOfG79pDTM4Pxe1pSBsTXSy8LW5d73RuNiq0rjOFG4q1S8H_NkOxSDsf9xsTzBvwyqo-mrfnegnuv17fNd_K1Y_l92axKjXFnJYWY44YqzvTKcsFryHRHSEtJtB2taKGtkYRywgnFWFVlSlmjWUQUUs40vgSXE26Po8qo3bJ6E0ebzA6SQ6hYDXL0IcJ2gf_eDAxyZ2L2vS9Gow_RFlRRASjIoPv_gG3_hCGvIBElajzxISP1KeJ0sHHGIyV--B2KpwkgnJMX27lmL4cI5Zj-vKcvjzmz-_PFipq1dugBu3iswLjSGA4enyZsL-uN6f_MJA3i-YacUyzRDlJuJjM8VlChT_ZJa8if62X8mb5sFr9XD9Ihp8A2MCnWw</recordid><startdate>198909</startdate><enddate>198909</enddate><creator>Yamada, Osamu</creator><creator>Hirao, Kiyoshi</creator><creator>Koizumi, Mitsue</creator><creator>Miyamoto, Yoshinari</creator><general>Blackwell Publishing Ltd</general><general>Blackwell</general><general>American Ceramic Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>HDMVH</scope><scope>K30</scope><scope>PAAUG</scope><scope>PAWHS</scope><scope>PAWZZ</scope><scope>PAXOH</scope><scope>PBHAV</scope><scope>PBQSW</scope><scope>PBYQZ</scope><scope>PCIWU</scope><scope>PCMID</scope><scope>PCZJX</scope><scope>PDGRG</scope><scope>PDWWI</scope><scope>PETMR</scope><scope>PFVGT</scope><scope>PGXDX</scope><scope>PIHIL</scope><scope>PISVA</scope><scope>PJCTQ</scope><scope>PJTMS</scope><scope>PLCHJ</scope><scope>PMHAD</scope><scope>PNQDJ</scope><scope>POUND</scope><scope>PPLAD</scope><scope>PQAPC</scope><scope>PQCAN</scope><scope>PQCMW</scope><scope>PQEME</scope><scope>PQHKH</scope><scope>PQMID</scope><scope>PQNCT</scope><scope>PQNET</scope><scope>PQSCT</scope><scope>PQSET</scope><scope>PSVJG</scope><scope>PVMQY</scope><scope>PZGFC</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>OTOTI</scope></search><sort><creationdate>198909</creationdate><title>Combustion Synthesis of Silicon Carbide in Nitrogen Atmosphere</title><author>Yamada, Osamu ; Hirao, Kiyoshi ; Koizumi, Mitsue ; Miyamoto, Yoshinari</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5375-f3371668dedaf797804cd44b340fd8a5e5bea4f647424622daf6fef6015f471c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication</topic><topic>400800 - Combustion, Pyrolysis, & High-Temperature Chemistry</topic><topic>Applied sciences</topic><topic>Building materials. 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The exothermic synthesis reaction propagated spontaneously after igniting the reactants at room temperature. The SiC powders obtained had a uniform size distribution of about 0.2 μm. The combustion velocity was 0.8 to 1.5 mm / s. The maximum temperature measured at the reaction was 2500 K, which was higher than the adiabatic combustion temperature of SiC, but slightly lower than the decomposition temperature of Si3N4 under nitrogen pressure.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1989.tb06315.x</doi><tpages>4</tpages></addata></record> |
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subjects | 360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication 400800 - Combustion, Pyrolysis, & High-Temperature Chemistry Applied sciences Building materials. Ceramics. Glasses CARBIDES CARBON COMPOUNDS Ceramic industries Chemical industry and chemicals CHEMICAL REACTION KINETICS CHEMICAL REACTIONS COMBUSTION ELEMENTS Exact sciences and technology INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS MATERIALS SCIENCE NITROGEN NONMETALS OXIDATION POWDERS REACTION KINETICS silicon carbide SILICON CARBIDES SILICON COMPOUNDS SYNTHESIS Technical ceramics THERMOCHEMICAL PROCESSES VERY HIGH TEMPERATURE |
title | Combustion Synthesis of Silicon Carbide in Nitrogen Atmosphere |
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