Electrocatalysis of anodic oxygen-transfer reactions : titanium substrates for pure and doped lead dioxide films
In this paper, voltammetric and kinetic results are described for the electrocatalytic oxidations of various compounds at doped PbO{sub 2}-film electrodes on Ti substrates. Compounds tested include dimethyl sulfoxide and several thiophene derivatives. Results are emphasized for PbO{sub 2} films dope...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1991-11, Vol.138 (11), p.3328-3337 |
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| container_title | Journal of the Electrochemical Society |
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| creator | JIANREN FENG JOHNSON, D. C |
| description | In this paper, voltammetric and kinetic results are described for the electrocatalytic oxidations of various compounds at doped PbO{sub 2}-film electrodes on Ti substrates. Compounds tested include dimethyl sulfoxide and several thiophene derivatives. Results are emphasized for PbO{sub 2} films doped with Fe{sup III} (Fe-PbO{sub 2}), and with Ag{sup I} and Bi{sup V} (Ag--Bi-PbO{sub 2}), that were electrolytically deposited on Ti substrates with the presence of an interlayer of PbO{sub 2} deposited from acidic solutions of Pb{sup 2+} and NaF. These laminar film electrodes are quite stable and offer significantly improved catalytic activity for various anodic oxygen-transfer reactions in comparison to pure PbO{sub 2}-film electrodes. |
| doi_str_mv | 10.1149/1.2085410 |
| format | Article |
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C</creatorcontrib><title>Electrocatalysis of anodic oxygen-transfer reactions : titanium substrates for pure and doped lead dioxide films</title><title>Journal of the Electrochemical Society</title><description>In this paper, voltammetric and kinetic results are described for the electrocatalytic oxidations of various compounds at doped PbO{sub 2}-film electrodes on Ti substrates. Compounds tested include dimethyl sulfoxide and several thiophene derivatives. Results are emphasized for PbO{sub 2} films doped with Fe{sup III} (Fe-PbO{sub 2}), and with Ag{sup I} and Bi{sup V} (Ag--Bi-PbO{sub 2}), that were electrolytically deposited on Ti substrates with the presence of an interlayer of PbO{sub 2} deposited from acidic solutions of Pb{sup 2+} and NaF. These laminar film electrodes are quite stable and offer significantly improved catalytic activity for various anodic oxygen-transfer reactions in comparison to pure PbO{sub 2}-film electrodes.</description><subject>30 DIRECT ENERGY CONVERSION</subject><subject>300503 - Fuel Cells- Materials, Components, & Auxiliaries</subject><subject>300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics</subject><subject>400400 - Electrochemistry</subject><subject>ALLOYS</subject><subject>ANODES</subject><subject>BISMUTH ADDITIONS</subject><subject>BISMUTH ALLOYS</subject><subject>CATALYSTS</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL REACTION KINETICS</subject><subject>CHEMICAL REACTIONS</subject><subject>Chemistry</subject><subject>DMSO</subject><subject>DOPED MATERIALS</subject><subject>ELECTROCATALYSTS</subject><subject>Electrochemistry</subject><subject>ELECTRODES</subject><subject>ELEMENTS</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>HETEROCYCLIC COMPOUNDS</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IRON ADDITIONS</subject><subject>IRON ALLOYS</subject><subject>KINETICS</subject><subject>Kinetics and mechanism of reactions</subject><subject>LEAD COMPOUNDS</subject><subject>LEAD OXIDES</subject><subject>MATERIALS</subject><subject>MATERIALS TESTING</subject><subject>METALS</subject><subject>NONMETALS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC SULFUR COMPOUNDS</subject><subject>OXIDES</subject><subject>OXYGEN</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHASE STABILITY</subject><subject>REACTION KINETICS</subject><subject>REDOX REACTIONS</subject><subject>SILVER ADDITIONS</subject><subject>SILVER ALLOYS</subject><subject>STABILITY</subject><subject>SUBSTRATES</subject><subject>SULFOXIDES</subject><subject>TESTING</subject><subject>THIN FILMS</subject><subject>THIOPHENE</subject><subject>TITANIUM</subject><subject>TRANSITION ELEMENTS</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNo9kEtLAzEUhYMoWKsL_0EQNy6m5uYxD3dS6gMKbnQ9ZDKJRqaTITeF9t-b0uLqngvfOXAOIbfAFgCyeYQFZ7WSwM7IDBqpigoAzsmMMRCFLBVckivE3_xCLasZmVaDNSkGo5Me9uiRBkf1GHpvaNjtv-1YpKhHdDbSaLVJPoxIn2jySY9-u6G47TATySJ1IdJpG23297QPk-3pYHWWPux8b6nzwwavyYXTA9qb052Tr5fV5_KtWH-8vi-f14URskmFEkyVrOwYs6UwTDJZM84bnttVjCtleW247jpupCq7Crq-r2tpXQWVgNIwMSd3x9yAybdofLLmx4RxzHXbKvfPmRl6OEImBsRoXTtFv9Fx3wJrD3u20J72zOz9kZ00Gj24vIrx-G9QALxRQvwBaktz3Q</recordid><startdate>19911101</startdate><enddate>19911101</enddate><creator>JIANREN FENG</creator><creator>JOHNSON, D. C</creator><general>Electrochemical Society</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19911101</creationdate><title>Electrocatalysis of anodic oxygen-transfer reactions : titanium substrates for pure and doped lead dioxide films</title><author>JIANREN FENG ; JOHNSON, D. C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-5305606b00e63c040480229220870255e28c2abb2c456b71bdd884ef717316c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>30 DIRECT ENERGY CONVERSION</topic><topic>300503 - Fuel Cells- Materials, Components, & Auxiliaries</topic><topic>300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics</topic><topic>400400 - Electrochemistry</topic><topic>ALLOYS</topic><topic>ANODES</topic><topic>BISMUTH ADDITIONS</topic><topic>BISMUTH ALLOYS</topic><topic>CATALYSTS</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL REACTION KINETICS</topic><topic>CHEMICAL REACTIONS</topic><topic>Chemistry</topic><topic>DMSO</topic><topic>DOPED MATERIALS</topic><topic>ELECTROCATALYSTS</topic><topic>Electrochemistry</topic><topic>ELECTRODES</topic><topic>ELEMENTS</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>HETEROCYCLIC COMPOUNDS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IRON ADDITIONS</topic><topic>IRON ALLOYS</topic><topic>KINETICS</topic><topic>Kinetics and mechanism of reactions</topic><topic>LEAD COMPOUNDS</topic><topic>LEAD OXIDES</topic><topic>MATERIALS</topic><topic>MATERIALS TESTING</topic><topic>METALS</topic><topic>NONMETALS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC SULFUR COMPOUNDS</topic><topic>OXIDES</topic><topic>OXYGEN</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHASE STABILITY</topic><topic>REACTION KINETICS</topic><topic>REDOX REACTIONS</topic><topic>SILVER ADDITIONS</topic><topic>SILVER ALLOYS</topic><topic>STABILITY</topic><topic>SUBSTRATES</topic><topic>SULFOXIDES</topic><topic>TESTING</topic><topic>THIN FILMS</topic><topic>THIOPHENE</topic><topic>TITANIUM</topic><topic>TRANSITION ELEMENTS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>JIANREN FENG</creatorcontrib><creatorcontrib>JOHNSON, D. C</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>JIANREN FENG</au><au>JOHNSON, D. C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrocatalysis of anodic oxygen-transfer reactions : titanium substrates for pure and doped lead dioxide films</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>1991-11-01</date><risdate>1991</risdate><volume>138</volume><issue>11</issue><spage>3328</spage><epage>3337</epage><pages>3328-3337</pages><issn>0013-4651</issn><eissn>1945-7111</eissn><coden>JESOAN</coden><abstract>In this paper, voltammetric and kinetic results are described for the electrocatalytic oxidations of various compounds at doped PbO{sub 2}-film electrodes on Ti substrates. Compounds tested include dimethyl sulfoxide and several thiophene derivatives. Results are emphasized for PbO{sub 2} films doped with Fe{sup III} (Fe-PbO{sub 2}), and with Ag{sup I} and Bi{sup V} (Ag--Bi-PbO{sub 2}), that were electrolytically deposited on Ti substrates with the presence of an interlayer of PbO{sub 2} deposited from acidic solutions of Pb{sup 2+} and NaF. These laminar film electrodes are quite stable and offer significantly improved catalytic activity for various anodic oxygen-transfer reactions in comparison to pure PbO{sub 2}-film electrodes.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2085410</doi><tpages>10</tpages></addata></record> |
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| ispartof | Journal of the Electrochemical Society, 1991-11, Vol.138 (11), p.3328-3337 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_osti_scitechconnect_7001040 |
| source | IOP Publishing Journals |
| subjects | 30 DIRECT ENERGY CONVERSION 300503 - Fuel Cells- Materials, Components, & Auxiliaries 300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics 400400 - Electrochemistry ALLOYS ANODES BISMUTH ADDITIONS BISMUTH ALLOYS CATALYSTS CHALCOGENIDES CHEMICAL REACTION KINETICS CHEMICAL REACTIONS Chemistry DMSO DOPED MATERIALS ELECTROCATALYSTS Electrochemistry ELECTRODES ELEMENTS Exact sciences and technology General and physical chemistry HETEROCYCLIC COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRON ADDITIONS IRON ALLOYS KINETICS Kinetics and mechanism of reactions LEAD COMPOUNDS LEAD OXIDES MATERIALS MATERIALS TESTING METALS NONMETALS ORGANIC COMPOUNDS ORGANIC SULFUR COMPOUNDS OXIDES OXYGEN OXYGEN COMPOUNDS PHASE STABILITY REACTION KINETICS REDOX REACTIONS SILVER ADDITIONS SILVER ALLOYS STABILITY SUBSTRATES SULFOXIDES TESTING THIN FILMS THIOPHENE TITANIUM TRANSITION ELEMENTS |
| title | Electrocatalysis of anodic oxygen-transfer reactions : titanium substrates for pure and doped lead dioxide films |
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