Hydration of monomeric metaphosphate anion in the gas phase

Thermochemical data for the clustering of water molecules onto the monomeric metaphosphate anion PO{sub 3}{sup {minus}} in the gas phase are derived from a study by high-pressure mass spectrometry. Experimental details are described, and the enthalpy and entropy changes for the successive addition o...

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Veröffentlicht in:	Journal of the American Chemical Society 1989-12, Vol.111 (25), p.9015-9018
Hauptverfasser:	Keesee, R. G, Castleman, A. W
Format:	Artikel
Sprache:	eng
Schlagworte:	400000 - Chemistry 400201 - Chemical & Physicochemical Properties 400202 - Isotope Effects, Isotope Exchange, & Isotope Separation Chemistry DATA DATA ANALYSIS Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry HYDRATION INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE EFFECTS MASS SPECTROSCOPY MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA OXYGEN COMPOUNDS PHOSPHATES PHOSPHORUS COMPOUNDS Solutions SOLVATION SPECTROSCOPY THERMOCHEMICAL PROCESSES
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container_title	Journal of the American Chemical Society
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creator	Keesee, R. G Castleman, A. W
description	Thermochemical data for the clustering of water molecules onto the monomeric metaphosphate anion PO{sub 3}{sup {minus}} in the gas phase are derived from a study by high-pressure mass spectrometry. Experimental details are described, and the enthalpy and entropy changes for the successive addition of the first four water (D{sub 2}O) molecules are reported. The results indicate that PO{sub 3}{sup {minus}} undergoes simple adduct formation up to the second hydration step, but the third hydration step involves an isomerization of the ion-water cluster into the dihydrate of the dihydrogen orthophosphate anion.
doi_str_mv	10.1021/ja00207a004
format	Article
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W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a272t-bf8a301da366381759a7852a576b9a262fc018a65ccd7c46b9ead5e44585af383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1989</creationdate><topic>400000 - Chemistry</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>400202 - Isotope Effects, Isotope Exchange, & Isotope Separation</topic><topic>Chemistry</topic><topic>DATA</topic><topic>DATA ANALYSIS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>General and physical chemistry</topic><topic>HYDRATION</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>ISOTOPE EFFECTS</topic><topic>MASS SPECTROSCOPY</topic><topic>MEASURING INSTRUMENTS</topic><topic>MEASURING METHODS</topic><topic>NUMERICAL DATA</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHOSPHATES</topic><topic>PHOSPHORUS COMPOUNDS</topic><topic>Solutions</topic><topic>SOLVATION</topic><topic>SPECTROSCOPY</topic><topic>THERMOCHEMICAL PROCESSES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Keesee, R. 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Soc</addtitle><date>1989-12-01</date><risdate>1989</risdate><volume>111</volume><issue>25</issue><spage>9015</spage><epage>9018</epage><pages>9015-9018</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><coden>JACSAT</coden><abstract>Thermochemical data for the clustering of water molecules onto the monomeric metaphosphate anion PO{sub 3}{sup {minus}} in the gas phase are derived from a study by high-pressure mass spectrometry. Experimental details are described, and the enthalpy and entropy changes for the successive addition of the first four water (D{sub 2}O) molecules are reported. The results indicate that PO{sub 3}{sup {minus}} undergoes simple adduct formation up to the second hydration step, but the third hydration step involves an isomerization of the ion-water cluster into the dihydrate of the dihydrogen orthophosphate anion.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/ja00207a004</doi><tpages>4</tpages></addata></record>
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subjects	400000 - Chemistry 400201 - Chemical & Physicochemical Properties 400202 - Isotope Effects, Isotope Exchange, & Isotope Separation Chemistry DATA DATA ANALYSIS Exact sciences and technology EXPERIMENTAL DATA General and physical chemistry HYDRATION INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE EFFECTS MASS SPECTROSCOPY MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA OXYGEN COMPOUNDS PHOSPHATES PHOSPHORUS COMPOUNDS Solutions SOLVATION SPECTROSCOPY THERMOCHEMICAL PROCESSES
title	Hydration of monomeric metaphosphate anion in the gas phase
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