A Mechanism of Lithium Storage in Disordered Carbons
High-resolution electron microscopy and lithium-7 nuclear magnetic resonance measurements were carried out for a disordered carbon material, prepared by heat treatment of polyphenylene, in which lithium was stored electrochemically. The nuclear magnetic resonance spectrum suggests the existence of L...
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Veröffentlicht in: | Science (American Association for the Advancement of Science) 1994-04, Vol.264 (5158), p.556-558 |
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creator | Sato, Kenji Noguchi, Minoru Demachi, Atsushi Oki, Naohiko Endo, Morinobu |
description | High-resolution electron microscopy and lithium-7 nuclear magnetic resonance measurements were carried out for a disordered carbon material, prepared by heat treatment of polyphenylene, in which lithium was stored electrochemically. The nuclear magnetic resonance spectrum suggests the existence of Li$_2$ covalent molecules in the carbon material. This extra covalent site of lithium storage promises extraordinarily high energy density for secondary batteries. |
doi_str_mv | 10.1126/science.264.5158.556 |
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The nuclear magnetic resonance spectrum suggests the existence of Li$_2$ covalent molecules in the carbon material. 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The nuclear magnetic resonance spectrum suggests the existence of Li$_2$ covalent molecules in the carbon material. This extra covalent site of lithium storage promises extraordinarily high energy density for secondary batteries.</abstract><cop>Washington, DC</cop><pub>American Society for the Advancement of Science</pub><pmid>17732740</pmid><doi>10.1126/science.264.5158.556</doi><tpages>3</tpages></addata></record> |
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source | American Association for the Advancement of Science; Jstor Complete Legacy |
subjects | 250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries ALKALI METALS AROMATICS Carbon Chemical equilibrium Chemistry Doping ELECTRIC BATTERIES ELECTROCHEMICAL CELLS Electrochemistry Electrodes Electrodes: preparations and properties ELEMENTS ENERGY DENSITY ENERGY STORAGE Exact sciences and technology General and physical chemistry Graphite HEAT TREATMENTS HYDROCARBONS Ions LITHIUM Lithium (Metal) Materials METALS Molecules NMR Nuclear magnetic resonance ORGANIC COMPOUNDS Other electrodes POLYPHENYLS Scientific imaging Spectroscopy Stoichiometry STORAGE Transmission electron microscopes |
title | A Mechanism of Lithium Storage in Disordered Carbons |
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