A Mechanism of Lithium Storage in Disordered Carbons

High-resolution electron microscopy and lithium-7 nuclear magnetic resonance measurements were carried out for a disordered carbon material, prepared by heat treatment of polyphenylene, in which lithium was stored electrochemically. The nuclear magnetic resonance spectrum suggests the existence of L...

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Veröffentlicht in:Science (American Association for the Advancement of Science) 1994-04, Vol.264 (5158), p.556-558
Hauptverfasser: Sato, Kenji, Noguchi, Minoru, Demachi, Atsushi, Oki, Naohiko, Endo, Morinobu
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container_issue 5158
container_start_page 556
container_title Science (American Association for the Advancement of Science)
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creator Sato, Kenji
Noguchi, Minoru
Demachi, Atsushi
Oki, Naohiko
Endo, Morinobu
description High-resolution electron microscopy and lithium-7 nuclear magnetic resonance measurements were carried out for a disordered carbon material, prepared by heat treatment of polyphenylene, in which lithium was stored electrochemically. The nuclear magnetic resonance spectrum suggests the existence of Li$_2$ covalent molecules in the carbon material. This extra covalent site of lithium storage promises extraordinarily high energy density for secondary batteries.
doi_str_mv 10.1126/science.264.5158.556
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subjects 250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries
ALKALI METALS
AROMATICS
Carbon
Chemical equilibrium
Chemistry
Doping
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
Electrochemistry
Electrodes
Electrodes: preparations and properties
ELEMENTS
ENERGY DENSITY
ENERGY STORAGE
Exact sciences and technology
General and physical chemistry
Graphite
HEAT TREATMENTS
HYDROCARBONS
Ions
LITHIUM
Lithium (Metal)
Materials
METALS
Molecules
NMR
Nuclear magnetic resonance
ORGANIC COMPOUNDS
Other electrodes
POLYPHENYLS
Scientific imaging
Spectroscopy
Stoichiometry
STORAGE
Transmission electron microscopes
title A Mechanism of Lithium Storage in Disordered Carbons
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