Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi sub 2 Fe sub 4 minus x Ga sub x O sub 9
The solid solution Bi{sub 2}Fe{sub 4{minus}x}Ga{sub x}O{sub 9} (0 {le} x {le} 4) was synthesized and investigated by X-ray diffraction, Moessbauer spectroscopy, and susceptibility measurements. The system was found essentially to follow Vegard's law. The crystal structure of the x = 2 member, B...
Gespeichert in:
| Veröffentlicht in: | Journal of solid state chemistry 1992-07, Vol.99:1 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | Journal of solid state chemistry |
| container_volume | 99:1 |
| creator | Giaquinta, D.M. Papaefthymiou, G.C. Davis, W.M. Loye, H.C. zur |
| description | The solid solution Bi{sub 2}Fe{sub 4{minus}x}Ga{sub x}O{sub 9} (0 {le} x {le} 4) was synthesized and investigated by X-ray diffraction, Moessbauer spectroscopy, and susceptibility measurements. The system was found essentially to follow Vegard's law. The crystal structure of the x = 2 member, Bi{sub 2}Fe{sub 2}Ga{sub 2}O{sub 9}, was solved. The structure is orthorhombic with space group Pbam (No. 55), a = 7.946(1) {angstrom}, b = 8.355(1){angstrom}, and c = 5.929(1) {angstrom}. Iron and gallium were nonstatistically distributed over two octahedral and two tetrahedral sites. The iron displayed a 60% preference for the octahedral positions. Magnetic susceptibility and Moessbauer measurements showed antiferromagnetic behavior. The ordering temperature, T{sub N}, exhibited a strong dependence on x, decreasing rapidly with gallium doping from T{sub N} = 245 {plus minus} 5 K for x = 0 to T{sub N} {lt} 4.2 K for x = 3. Spin-glass-like behavior was observed in the gallium-substituted compounds, and a previously undetected spin rearrangement at 220 K for the x = 0 compound is reported. |
| doi_str_mv | 10.1016/0022-4596(92)90296-8 |
| format | Article |
| fullrecord | <record><control><sourceid>osti</sourceid><recordid>TN_cdi_osti_scitechconnect_6957540</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>6957540</sourcerecordid><originalsourceid>FETCH-osti_scitechconnect_69575403</originalsourceid><addsrcrecordid>eNqNir1OwzAUhS0EEuHnDRiumEBqwDZJWq-gFjYGGNgq17klRold-V5L6YPwvkCEmFnOd3TOJ8SFkjdKquZWSq3LqjbNldHXRmrTlIsDUShp6nKum7dDUfwpx-KE6ENKpepFVYjPl33gDsnTDIhTdpwTzsCGFgb7HpC9g12KO0zskSBu4duG3u4xYQsbT0PmDjjZQJ59DDAg2x7i6FsEir1vfzJP170HyhvQsMKpVDD4kAlGeLTTMMLzRHMmjra2Jzz_5am4XC1fH57KSOzX5Dyj61wMAR2vG1PP60re_Uv6AoMnXeM</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi sub 2 Fe sub 4 minus x Ga sub x O sub 9</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Giaquinta, D.M. ; Papaefthymiou, G.C. ; Davis, W.M. ; Loye, H.C. zur</creator><creatorcontrib>Giaquinta, D.M. ; Papaefthymiou, G.C. ; Davis, W.M. ; Loye, H.C. zur</creatorcontrib><description>The solid solution Bi{sub 2}Fe{sub 4{minus}x}Ga{sub x}O{sub 9} (0 {le} x {le} 4) was synthesized and investigated by X-ray diffraction, Moessbauer spectroscopy, and susceptibility measurements. The system was found essentially to follow Vegard's law. The crystal structure of the x = 2 member, Bi{sub 2}Fe{sub 2}Ga{sub 2}O{sub 9}, was solved. The structure is orthorhombic with space group Pbam (No. 55), a = 7.946(1) {angstrom}, b = 8.355(1){angstrom}, and c = 5.929(1) {angstrom}. Iron and gallium were nonstatistically distributed over two octahedral and two tetrahedral sites. The iron displayed a 60% preference for the octahedral positions. Magnetic susceptibility and Moessbauer measurements showed antiferromagnetic behavior. The ordering temperature, T{sub N}, exhibited a strong dependence on x, decreasing rapidly with gallium doping from T{sub N} = 245 {plus minus} 5 K for x = 0 to T{sub N} {lt} 4.2 K for x = 3. Spin-glass-like behavior was observed in the gallium-substituted compounds, and a previously undetected spin rearrangement at 220 K for the x = 0 compound is reported.</description><identifier>ISSN: 0022-4596</identifier><identifier>EISSN: 1095-726X</identifier><identifier>DOI: 10.1016/0022-4596(92)90296-8</identifier><language>eng</language><publisher>United States</publisher><subject>360204 - Ceramics, Cermets, & Refractories- Physical Properties ; 400201 - Chemical & Physicochemical Properties ; ANTIFERROMAGNETIC MATERIALS ; BISMUTH COMPOUNDS ; BISMUTH OXIDES ; CHALCOGENIDES ; CHEMICAL PREPARATION ; COHERENT SCATTERING ; CRYSTAL LATTICES ; CRYSTAL STRUCTURE ; DATA ; DIFFRACTION ; DISPERSIONS ; EXPERIMENTAL DATA ; GALLIUM COMPOUNDS ; GALLIUM OXIDES ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IRON COMPOUNDS ; IRON OXIDES ; LATTICE PARAMETERS ; MAGNETIC MATERIALS ; MAGNETIC PROPERTIES ; MAGNETIC SUSCEPTIBILITY ; MATERIALS ; MATERIALS SCIENCE ; MIXTURES ; MOESSBAUER EFFECT ; NUMERICAL DATA ; ORTHORHOMBIC LATTICES ; OXIDES ; OXYGEN COMPOUNDS ; PHYSICAL PROPERTIES ; SCATTERING ; SOLID SOLUTIONS ; SOLUTIONS ; SYNTHESIS ; TRANSITION ELEMENT COMPOUNDS ; X-RAY DIFFRACTION</subject><ispartof>Journal of solid state chemistry, 1992-07, Vol.99:1</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/6957540$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Giaquinta, D.M.</creatorcontrib><creatorcontrib>Papaefthymiou, G.C.</creatorcontrib><creatorcontrib>Davis, W.M.</creatorcontrib><creatorcontrib>Loye, H.C. zur</creatorcontrib><title>Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi sub 2 Fe sub 4 minus x Ga sub x O sub 9</title><title>Journal of solid state chemistry</title><description>The solid solution Bi{sub 2}Fe{sub 4{minus}x}Ga{sub x}O{sub 9} (0 {le} x {le} 4) was synthesized and investigated by X-ray diffraction, Moessbauer spectroscopy, and susceptibility measurements. The system was found essentially to follow Vegard's law. The crystal structure of the x = 2 member, Bi{sub 2}Fe{sub 2}Ga{sub 2}O{sub 9}, was solved. The structure is orthorhombic with space group Pbam (No. 55), a = 7.946(1) {angstrom}, b = 8.355(1){angstrom}, and c = 5.929(1) {angstrom}. Iron and gallium were nonstatistically distributed over two octahedral and two tetrahedral sites. The iron displayed a 60% preference for the octahedral positions. Magnetic susceptibility and Moessbauer measurements showed antiferromagnetic behavior. The ordering temperature, T{sub N}, exhibited a strong dependence on x, decreasing rapidly with gallium doping from T{sub N} = 245 {plus minus} 5 K for x = 0 to T{sub N} {lt} 4.2 K for x = 3. Spin-glass-like behavior was observed in the gallium-substituted compounds, and a previously undetected spin rearrangement at 220 K for the x = 0 compound is reported.</description><subject>360204 - Ceramics, Cermets, & Refractories- Physical Properties</subject><subject>400201 - Chemical & Physicochemical Properties</subject><subject>ANTIFERROMAGNETIC MATERIALS</subject><subject>BISMUTH COMPOUNDS</subject><subject>BISMUTH OXIDES</subject><subject>CHALCOGENIDES</subject><subject>CHEMICAL PREPARATION</subject><subject>COHERENT SCATTERING</subject><subject>CRYSTAL LATTICES</subject><subject>CRYSTAL STRUCTURE</subject><subject>DATA</subject><subject>DIFFRACTION</subject><subject>DISPERSIONS</subject><subject>EXPERIMENTAL DATA</subject><subject>GALLIUM COMPOUNDS</subject><subject>GALLIUM OXIDES</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IRON COMPOUNDS</subject><subject>IRON OXIDES</subject><subject>LATTICE PARAMETERS</subject><subject>MAGNETIC MATERIALS</subject><subject>MAGNETIC PROPERTIES</subject><subject>MAGNETIC SUSCEPTIBILITY</subject><subject>MATERIALS</subject><subject>MATERIALS SCIENCE</subject><subject>MIXTURES</subject><subject>MOESSBAUER EFFECT</subject><subject>NUMERICAL DATA</subject><subject>ORTHORHOMBIC LATTICES</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>PHYSICAL PROPERTIES</subject><subject>SCATTERING</subject><subject>SOLID SOLUTIONS</subject><subject>SOLUTIONS</subject><subject>SYNTHESIS</subject><subject>TRANSITION ELEMENT COMPOUNDS</subject><subject>X-RAY DIFFRACTION</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNqNir1OwzAUhS0EEuHnDRiumEBqwDZJWq-gFjYGGNgq17klRold-V5L6YPwvkCEmFnOd3TOJ8SFkjdKquZWSq3LqjbNldHXRmrTlIsDUShp6nKum7dDUfwpx-KE6ENKpepFVYjPl33gDsnTDIhTdpwTzsCGFgb7HpC9g12KO0zskSBu4duG3u4xYQsbT0PmDjjZQJ59DDAg2x7i6FsEir1vfzJP170HyhvQsMKpVDD4kAlGeLTTMMLzRHMmjra2Jzz_5am4XC1fH57KSOzX5Dyj61wMAR2vG1PP60re_Uv6AoMnXeM</recordid><startdate>19920701</startdate><enddate>19920701</enddate><creator>Giaquinta, D.M.</creator><creator>Papaefthymiou, G.C.</creator><creator>Davis, W.M.</creator><creator>Loye, H.C. zur</creator><scope>OTOTI</scope></search><sort><creationdate>19920701</creationdate><title>Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi sub 2 Fe sub 4 minus x Ga sub x O sub 9</title><author>Giaquinta, D.M. ; Papaefthymiou, G.C. ; Davis, W.M. ; Loye, H.C. zur</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_69575403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>360204 - Ceramics, Cermets, & Refractories- Physical Properties</topic><topic>400201 - Chemical & Physicochemical Properties</topic><topic>ANTIFERROMAGNETIC MATERIALS</topic><topic>BISMUTH COMPOUNDS</topic><topic>BISMUTH OXIDES</topic><topic>CHALCOGENIDES</topic><topic>CHEMICAL PREPARATION</topic><topic>COHERENT SCATTERING</topic><topic>CRYSTAL LATTICES</topic><topic>CRYSTAL STRUCTURE</topic><topic>DATA</topic><topic>DIFFRACTION</topic><topic>DISPERSIONS</topic><topic>EXPERIMENTAL DATA</topic><topic>GALLIUM COMPOUNDS</topic><topic>GALLIUM OXIDES</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IRON COMPOUNDS</topic><topic>IRON OXIDES</topic><topic>LATTICE PARAMETERS</topic><topic>MAGNETIC MATERIALS</topic><topic>MAGNETIC PROPERTIES</topic><topic>MAGNETIC SUSCEPTIBILITY</topic><topic>MATERIALS</topic><topic>MATERIALS SCIENCE</topic><topic>MIXTURES</topic><topic>MOESSBAUER EFFECT</topic><topic>NUMERICAL DATA</topic><topic>ORTHORHOMBIC LATTICES</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>PHYSICAL PROPERTIES</topic><topic>SCATTERING</topic><topic>SOLID SOLUTIONS</topic><topic>SOLUTIONS</topic><topic>SYNTHESIS</topic><topic>TRANSITION ELEMENT COMPOUNDS</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Giaquinta, D.M.</creatorcontrib><creatorcontrib>Papaefthymiou, G.C.</creatorcontrib><creatorcontrib>Davis, W.M.</creatorcontrib><creatorcontrib>Loye, H.C. zur</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Giaquinta, D.M.</au><au>Papaefthymiou, G.C.</au><au>Davis, W.M.</au><au>Loye, H.C. zur</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi sub 2 Fe sub 4 minus x Ga sub x O sub 9</atitle><jtitle>Journal of solid state chemistry</jtitle><date>1992-07-01</date><risdate>1992</risdate><volume>99:1</volume><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>The solid solution Bi{sub 2}Fe{sub 4{minus}x}Ga{sub x}O{sub 9} (0 {le} x {le} 4) was synthesized and investigated by X-ray diffraction, Moessbauer spectroscopy, and susceptibility measurements. The system was found essentially to follow Vegard's law. The crystal structure of the x = 2 member, Bi{sub 2}Fe{sub 2}Ga{sub 2}O{sub 9}, was solved. The structure is orthorhombic with space group Pbam (No. 55), a = 7.946(1) {angstrom}, b = 8.355(1){angstrom}, and c = 5.929(1) {angstrom}. Iron and gallium were nonstatistically distributed over two octahedral and two tetrahedral sites. The iron displayed a 60% preference for the octahedral positions. Magnetic susceptibility and Moessbauer measurements showed antiferromagnetic behavior. The ordering temperature, T{sub N}, exhibited a strong dependence on x, decreasing rapidly with gallium doping from T{sub N} = 245 {plus minus} 5 K for x = 0 to T{sub N} {lt} 4.2 K for x = 3. Spin-glass-like behavior was observed in the gallium-substituted compounds, and a previously undetected spin rearrangement at 220 K for the x = 0 compound is reported.</abstract><cop>United States</cop><doi>10.1016/0022-4596(92)90296-8</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4596 |
| ispartof | Journal of solid state chemistry, 1992-07, Vol.99:1 |
| issn | 0022-4596 1095-726X |
| language | eng |
| recordid | cdi_osti_scitechconnect_6957540 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | 360204 - Ceramics, Cermets, & Refractories- Physical Properties 400201 - Chemical & Physicochemical Properties ANTIFERROMAGNETIC MATERIALS BISMUTH COMPOUNDS BISMUTH OXIDES CHALCOGENIDES CHEMICAL PREPARATION COHERENT SCATTERING CRYSTAL LATTICES CRYSTAL STRUCTURE DATA DIFFRACTION DISPERSIONS EXPERIMENTAL DATA GALLIUM COMPOUNDS GALLIUM OXIDES INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRON COMPOUNDS IRON OXIDES LATTICE PARAMETERS MAGNETIC MATERIALS MAGNETIC PROPERTIES MAGNETIC SUSCEPTIBILITY MATERIALS MATERIALS SCIENCE MIXTURES MOESSBAUER EFFECT NUMERICAL DATA ORTHORHOMBIC LATTICES OXIDES OXYGEN COMPOUNDS PHYSICAL PROPERTIES SCATTERING SOLID SOLUTIONS SOLUTIONS SYNTHESIS TRANSITION ELEMENT COMPOUNDS X-RAY DIFFRACTION |
| title | Synthesis, structure, and magnetic properties of the layered bismuth transition metal oxide solid solution Bi sub 2 Fe sub 4 minus x Ga sub x O sub 9 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T05%3A29%3A40IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-osti&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20structure,%20and%20magnetic%20properties%20of%20the%20layered%20bismuth%20transition%20metal%20oxide%20solid%20solution%20Bi%20sub%202%20Fe%20sub%204%20minus%20x%20Ga%20sub%20x%20O%20sub%209&rft.jtitle=Journal%20of%20solid%20state%20chemistry&rft.au=Giaquinta,%20D.M.&rft.date=1992-07-01&rft.volume=99:1&rft.issn=0022-4596&rft.eissn=1095-726X&rft_id=info:doi/10.1016/0022-4596(92)90296-8&rft_dat=%3Costi%3E6957540%3C/osti%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |