Analytic Quantum Theory of Electron Transfer with a Reaction Mode Strongly Coupled to the Electron and Weakly Coupled to the Bath

We develop an effective analytic framework built around our own extension of standard small polaron theory. We assume a Hamiltonian in which the electron operators are strongly coupled to a single linear oscillator, the reaction mode, which is in turn weakly coupled to the heat bath. The Hamiltonian...

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Veröffentlicht in:Journal of physical chemistry (1952) 1994-07, Vol.98 (30), p.7395-7401
Hauptverfasser: Lindenberg, Katja, Cortes, Emilio, Pearlstein, Robert M
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Sprache:eng
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