Effect of Volatilization on the Conduction Behavior of Acceptor-Doped Chromium Oxide

The effect of volatilization on the conduction behavior of Li‐ or Mg‐doped Cr2O3 was studied. The Po2 dependence on conduction changed from 1/4 to 3/8 when volatilization occurred. The high‐temperature conduction mechanism of Cr2O3 may be dominated by the formation of Cr vacancies due to the volatil...

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Veröffentlicht in:Journal of the American Ceramic Society 1989-08, Vol.72 (8), p.1382-1385
Hauptverfasser: Huang, Rong-Fong, Anderson, Harlan U.
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container_title Journal of the American Ceramic Society
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creator Huang, Rong-Fong
Anderson, Harlan U.
description The effect of volatilization on the conduction behavior of Li‐ or Mg‐doped Cr2O3 was studied. The Po2 dependence on conduction changed from 1/4 to 3/8 when volatilization occurred. The high‐temperature conduction mechanism of Cr2O3 may be dominated by the formation of Cr vacancies due to the volatilization effect.
doi_str_mv 10.1111/j.1151-2916.1989.tb07657.x
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The Po2 dependence on conduction changed from 1/4 to 3/8 when volatilization occurred. The high‐temperature conduction mechanism of Cr2O3 may be dominated by the formation of Cr vacancies due to the volatilization effect.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1151-2916.1989.tb07657.x</identifier><identifier>CODEN: JACTAW</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>ALKALI METALS ; ALKALINE EARTH METALS ; CHALCOGENIDES ; CHEMICAL ANALYSIS ; chromia ; CHROMIUM COMPOUNDS ; CHROMIUM OXIDES ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Conductivity phenomena in semiconductors and insulators ; CRYSTAL DEFECTS ; CRYSTAL STRUCTURE ; DATA ; DOPED MATERIALS ; ELECTRIC CONDUCTIVITY ; electrical conductivity ; ELECTRICAL PROPERTIES ; Electronic transport in condensed matter ; ELEMENTS ; Exact sciences and technology ; EXPERIMENTAL DATA ; GRAVIMETRIC ANALYSIS ; INFORMATION ; LITHIUM ; Low-field transport and mobility; piezoresistance ; MAGNESIUM ; MATERIALS ; MATERIALS SCIENCE ; METALS ; NUMERICAL DATA ; OXIDES ; OXYGEN COMPOUNDS ; PHYSICAL PROPERTIES ; Physics ; QUANTITATIVE CHEMICAL ANALYSIS ; SAMPLE PREPARATION ; THERMAL ANALYSIS ; THERMAL GRAVIMETRIC ANALYSIS ; TRANSITION ELEMENT COMPOUNDS 360204 -- Ceramics, Cermets, &amp; Refractories-- Physical Properties ; VOLATILITY ; volatilization</subject><ispartof>Journal of the American Ceramic Society, 1989-08, Vol.72 (8), p.1382-1385</ispartof><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4712-3a5ec563b52fcabbe91f08d91fb94fcfa478f2f6ae8284d143c08b47156f14b33</citedby><cites>FETCH-LOGICAL-c4712-3a5ec563b52fcabbe91f08d91fb94fcfa478f2f6ae8284d143c08b47156f14b33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fj.1151-2916.1989.tb07657.x$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fj.1151-2916.1989.tb07657.x$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1416,27868,27923,27924,45573,45574</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=6915033$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6909610$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Huang, Rong-Fong</creatorcontrib><creatorcontrib>Anderson, Harlan U.</creatorcontrib><title>Effect of Volatilization on the Conduction Behavior of Acceptor-Doped Chromium Oxide</title><title>Journal of the American Ceramic Society</title><description>The effect of volatilization on the conduction behavior of Li‐ or Mg‐doped Cr2O3 was studied. 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The Po2 dependence on conduction changed from 1/4 to 3/8 when volatilization occurred. The high‐temperature conduction mechanism of Cr2O3 may be dominated by the formation of Cr vacancies due to the volatilization effect.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1989.tb07657.x</doi><tpages>4</tpages></addata></record>
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identifier ISSN: 0002-7820
ispartof Journal of the American Ceramic Society, 1989-08, Vol.72 (8), p.1382-1385
issn 0002-7820
1551-2916
language eng
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source Periodicals Index Online; Wiley Online Library All Journals
subjects ALKALI METALS
ALKALINE EARTH METALS
CHALCOGENIDES
CHEMICAL ANALYSIS
chromia
CHROMIUM COMPOUNDS
CHROMIUM OXIDES
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Conductivity phenomena in semiconductors and insulators
CRYSTAL DEFECTS
CRYSTAL STRUCTURE
DATA
DOPED MATERIALS
ELECTRIC CONDUCTIVITY
electrical conductivity
ELECTRICAL PROPERTIES
Electronic transport in condensed matter
ELEMENTS
Exact sciences and technology
EXPERIMENTAL DATA
GRAVIMETRIC ANALYSIS
INFORMATION
LITHIUM
Low-field transport and mobility
piezoresistance
MAGNESIUM
MATERIALS
MATERIALS SCIENCE
METALS
NUMERICAL DATA
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
Physics
QUANTITATIVE CHEMICAL ANALYSIS
SAMPLE PREPARATION
THERMAL ANALYSIS
THERMAL GRAVIMETRIC ANALYSIS
TRANSITION ELEMENT COMPOUNDS 360204 -- Ceramics, Cermets, & Refractories-- Physical Properties
VOLATILITY
volatilization
title Effect of Volatilization on the Conduction Behavior of Acceptor-Doped Chromium Oxide
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