Quantum defects and the long-term behavior of radial Rydberg wave packets

We show that a theoretical description of radial Rydberg wave packets in alkali-metal atoms based solely on hydrogenic wave functions and energies is insufficient to explain data that could be obtained in pump-probe experiments with current technology. The modifications to long-term revival times in...

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Veröffentlicht in:Physical review. A, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 1994-12, Vol.50 (6), p.R4445-R4448
Hauptverfasser: Bluhm, R, Kosteleck, VA
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container_issue 6
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container_title Physical review. A, Atomic, molecular, and optical physics
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creator Bluhm, R
Kosteleck, VA
description We show that a theoretical description of radial Rydberg wave packets in alkali-metal atoms based solely on hydrogenic wave functions and energies is insufficient to explain data that could be obtained in pump-probe experiments with current technology. The modifications to long-term revival times induced by quantum defects cannot be obtained by direct scaling of the hydrogenic results. Moreover, the effects of laser detuning and quantum defects are different. An alternative approach providing analytical predictions is presented.
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issn 1050-2947
1094-1622
language eng
recordid cdi_osti_scitechconnect_6847597
source PROLA
subjects ALKALI METALS
ATOM COLLISIONS
ATOMIC AND MOLECULAR PHYSICS
COLLISIONS
EIGENSTATES
ELECTROMAGNETIC RADIATION
ELEMENTS
ENERGY LEVELS
EXCITED STATES
FUNCTIONS
HYDROGEN
IONIZATION
LASER RADIATION
METALS
NONMETALS
PHOTOIONIZATION
PHOTON COLLISIONS
PHOTON-ATOM COLLISIONS
RADIATIONS 664200 -- Spectra of Atoms & Molecules & their Interactions with Photons-- (1992-)
RYDBERG STATES
WAVE FUNCTIONS
WAVE PACKETS
title Quantum defects and the long-term behavior of radial Rydberg wave packets
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