Laser Desorption Mass Spectrometry of Fullerene Derivatives: Laser-Induced Fragmentation and Coalescence Reactions
Laser desorption mass spectrometry was carried out for several fullerene derivatives (C sub(60)O and a series of 6-6 ring-bridge closed adducts of C sub(60) with bis(ethoxycarbonyl)methylenes C sub(61)(COOEt) sub(2), C sub(62)(COOEt) sub(4), and C sub(63)(COOEt) sub(6)) to investigate laser-induced...
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| Veröffentlicht in: | Journal of physical chemistry (1952) 1994-09, Vol.98 (39), p.9683-9687 |
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| container_end_page | 9687 |
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| container_issue | 39 |
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| container_title | Journal of physical chemistry (1952) |
| container_volume | 98 |
| creator | Beck, Rainer D Weis, Patrick Hirsch, Andreas Lamparth, Iris |
| description | Laser desorption mass spectrometry was carried out for several fullerene derivatives (C sub(60)O and a series of 6-6 ring-bridge closed adducts of C sub(60) with bis(ethoxycarbonyl)methylenes C sub(61)(COOEt) sub(2), C sub(62)(COOEt) sub(4), and C sub(63)(COOEt) sub(6)) to investigate laser-induced growth reactions between the desorbed species. A clear correspondence between the size distribution of fragments of the parent species and the desorption-induced reaction products indicates an efficient mechanism by which reactive fragments, produced by the desorption laser, aggregate or coalesce. The reaction mechanism and nature of the products were probed through fluence dependence studies and the detection of delayed electron emission. |
| doi_str_mv | 10.1021/j100090a001 |
| format | Article |
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A clear correspondence between the size distribution of fragments of the parent species and the desorption-induced reaction products indicates an efficient mechanism by which reactive fragments, produced by the desorption laser, aggregate or coalesce. 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Phys. Chem</addtitle><description>Laser desorption mass spectrometry was carried out for several fullerene derivatives (C sub(60)O and a series of 6-6 ring-bridge closed adducts of C sub(60) with bis(ethoxycarbonyl)methylenes C sub(61)(COOEt) sub(2), C sub(62)(COOEt) sub(4), and C sub(63)(COOEt) sub(6)) to investigate laser-induced growth reactions between the desorbed species. A clear correspondence between the size distribution of fragments of the parent species and the desorption-induced reaction products indicates an efficient mechanism by which reactive fragments, produced by the desorption laser, aggregate or coalesce. The reaction mechanism and nature of the products were probed through fluence dependence studies and the detection of delayed electron emission.</description><subject>661300 -- Other Aspects of Physical Science-- (1992-)</subject><subject>ADDUCTS</subject><subject>CARBON</subject><subject>CHEMICAL REACTIONS</subject><subject>CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS</subject><subject>COALESCENCE</subject><subject>DERIVATIZATION</subject><subject>DESORPTION</subject><subject>ELECTRON EMISSION</subject><subject>ELEMENTS</subject><subject>EMISSION</subject><subject>FRAGMENTATION</subject><subject>FULLERENES</subject><subject>HEATING</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>LASER-RADIATION HEATING</subject><subject>MASS SPECTRA</subject><subject>MASS SPECTROSCOPY</subject><subject>NONMETALS</subject><subject>PLASMA HEATING</subject><subject>SORPTION</subject><subject>SPECTRA</subject><subject>SPECTROSCOPY 400201 -- Chemical & Physicochemical Properties</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNpt0MFu1DAQBmALgcRSOPECFgc4oJSxEztZbnTLllaLWLGFq-U4E8iStRePU9G3x20Q4sDJh_nm1_hn7LmAUwFSvNkLAFiCBRAP2EKoShSqruAhWwBIWZRaVY_ZE6J9ZqIsxYLFjSWM_BwpxGMagucfLRHfHdGlGA6Y4i0PPV9P44gRPWYZhxubhhukt_x-ubj03eSw4-tovx3QJ3ufY33HV8GOSA69Q_4Zrbsb0FP2qLcj4bM_7wn7sn5_vfpQbD5dXK7ebQpbqmUq6q6RjdKVrEGBdL1TsgLsVdO7tq2klVrZTra6BaWWSgOCqJvWtkor0GXdlSfsxZwbKA2G3JDQfXfB-_w1o5tSQSMyejmjYww_J6RkDkM-eBytxzCRkbqqVKWXGb6eoYuBKGJvjnE42HhrBJi78s0_5WddzHqghL_-Uht_GF2XtTLX253ZXp1frb7uzsw2-1ezt47MPkzR52b-m_wbkgOSSg</recordid><startdate>19940901</startdate><enddate>19940901</enddate><creator>Beck, Rainer D</creator><creator>Weis, Patrick</creator><creator>Hirsch, Andreas</creator><creator>Lamparth, Iris</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>19940901</creationdate><title>Laser Desorption Mass Spectrometry of Fullerene Derivatives: Laser-Induced Fragmentation and Coalescence Reactions</title><author>Beck, Rainer D ; Weis, Patrick ; Hirsch, Andreas ; Lamparth, Iris</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a359t-7d828564270502cfc5240ef58fcbb42a265ad2b6b0559560e0178bab5650637d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>661300 -- Other Aspects of Physical Science-- (1992-)</topic><topic>ADDUCTS</topic><topic>CARBON</topic><topic>CHEMICAL REACTIONS</topic><topic>CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS</topic><topic>COALESCENCE</topic><topic>DERIVATIZATION</topic><topic>DESORPTION</topic><topic>ELECTRON EMISSION</topic><topic>ELEMENTS</topic><topic>EMISSION</topic><topic>FRAGMENTATION</topic><topic>FULLERENES</topic><topic>HEATING</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>LASER-RADIATION HEATING</topic><topic>MASS SPECTRA</topic><topic>MASS SPECTROSCOPY</topic><topic>NONMETALS</topic><topic>PLASMA HEATING</topic><topic>SORPTION</topic><topic>SPECTRA</topic><topic>SPECTROSCOPY 400201 -- Chemical & Physicochemical Properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Beck, Rainer D</creatorcontrib><creatorcontrib>Weis, Patrick</creatorcontrib><creatorcontrib>Hirsch, Andreas</creatorcontrib><creatorcontrib>Lamparth, Iris</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>OSTI.GOV</collection><jtitle>Journal of physical chemistry (1952)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Beck, Rainer D</au><au>Weis, Patrick</au><au>Hirsch, Andreas</au><au>Lamparth, Iris</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Laser Desorption Mass Spectrometry of Fullerene Derivatives: Laser-Induced Fragmentation and Coalescence Reactions</atitle><jtitle>Journal of physical chemistry (1952)</jtitle><addtitle>J. Phys. Chem</addtitle><date>1994-09-01</date><risdate>1994</risdate><volume>98</volume><issue>39</issue><spage>9683</spage><epage>9687</epage><pages>9683-9687</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>Laser desorption mass spectrometry was carried out for several fullerene derivatives (C sub(60)O and a series of 6-6 ring-bridge closed adducts of C sub(60) with bis(ethoxycarbonyl)methylenes C sub(61)(COOEt) sub(2), C sub(62)(COOEt) sub(4), and C sub(63)(COOEt) sub(6)) to investigate laser-induced growth reactions between the desorbed species. A clear correspondence between the size distribution of fragments of the parent species and the desorption-induced reaction products indicates an efficient mechanism by which reactive fragments, produced by the desorption laser, aggregate or coalesce. The reaction mechanism and nature of the products were probed through fluence dependence studies and the detection of delayed electron emission.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/j100090a001</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 0022-3654 |
| ispartof | Journal of physical chemistry (1952), 1994-09, Vol.98 (39), p.9683-9687 |
| issn | 0022-3654 1541-5740 |
| language | eng |
| recordid | cdi_osti_scitechconnect_6835081 |
| source | ACS Publications |
| subjects | 661300 -- Other Aspects of Physical Science-- (1992-) ADDUCTS CARBON CHEMICAL REACTIONS CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS COALESCENCE DERIVATIZATION DESORPTION ELECTRON EMISSION ELEMENTS EMISSION FRAGMENTATION FULLERENES HEATING INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LASER-RADIATION HEATING MASS SPECTRA MASS SPECTROSCOPY NONMETALS PLASMA HEATING SORPTION SPECTRA SPECTROSCOPY 400201 -- Chemical & Physicochemical Properties |
| title | Laser Desorption Mass Spectrometry of Fullerene Derivatives: Laser-Induced Fragmentation and Coalescence Reactions |
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