Ionically conductive thin polymer films prepared by plasma polymerization; Preparation and characterization of ultrathin films having fixed sulfonic acid groups with only one mobile species
Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treat...
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| Veröffentlicht in: | Journal of the Electrochemical Society 1990-01, Vol.137:1 |
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| container_title | Journal of the Electrochemical Society |
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| creator | Ogumi, Z. Uchimoto, Y. Takehara, Z. Foulkes, F.R. |
| description | Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 {mu}m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60{degrees}C of the order of 10{sup {minus} 6} S cm{sup {minus} 1} (10{sup 2} {Omega} cm{sup 2} resistance per unit area of as-prepared solid polymer electrolyte). This material shows promise for electrochemical applications such as all solid-state lithium batteries, sensors, and electrochemical display devices. |
| doi_str_mv | 10.1149/1.2086386 |
| format | Article |
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The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 {mu}m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60{degrees}C of the order of 10{sup {minus} 6} S cm{sup {minus} 1} (10{sup 2} {Omega} cm{sup 2} resistance per unit area of as-prepared solid polymer electrolyte). This material shows promise for electrochemical applications such as all solid-state lithium batteries, sensors, and electrochemical display devices.</description><identifier>ISSN: 0013-4651</identifier><identifier>EISSN: 1945-7111</identifier><identifier>DOI: 10.1149/1.2086386</identifier><language>eng</language><publisher>United States</publisher><subject>360602 -- Other Materials-- Structure & Phase Studies ; 400400 -- Electrochemistry ; 656003 -- Condensed Matter Physics-- Interactions between Beams & Condensed Matter-- (1987-) ; ALKALI METAL COMPOUNDS ; ALKALI METALS ; CHARGED PARTICLES ; CHEMICAL PREPARATION ; CHEMICAL REACTION KINETICS ; CHEMISTRY ; CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ; ELECTRIC BATTERIES ; ELECTRIC CONDUCTIVITY ; ELECTRIC DISCHARGES ; ELECTRICAL PROPERTIES ; ELECTROCHEMICAL CELLS ; ELECTROCHEMISTRY ; ELECTROLYTES ; ELEMENTS ; ENERGY STORAGE ; ESTERS ; GLOW DISCHARGES ; HALIDES ; HALOGEN COMPOUNDS ; INORGANIC PHOSPHORS ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IODIDES ; IODINE COMPOUNDS ; IONIC CONDUCTIVITY ; IONS ; KINETICS ; LITHIUM ; LITHIUM COMPOUNDS ; LITHIUM HALIDES ; LITHIUM IODIDES ; LITHIUM IONS ; MATERIALS SCIENCE ; METALS ; ORGANIC COMPOUNDS ; ORGANIC SILICON COMPOUNDS ; ORGANIC SULFUR COMPOUNDS ; PHOSPHORS ; PHYSICAL PROPERTIES ; PLASMA ; POLYMERS ; REACTION KINETICS ; SILOXANES ; SOLID ELECTROLYTES ; SOLID-STATE PLASMA ; SULFONIC ACID ESTERS ; SYNTHESIS 250903 -- Energy Storage-- Batteries-- Materials, Components, & Auxiliaries ; THIN FILMS</subject><ispartof>Journal of the Electrochemical Society, 1990-01, Vol.137:1</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/6817792$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Ogumi, Z.</creatorcontrib><creatorcontrib>Uchimoto, Y.</creatorcontrib><creatorcontrib>Takehara, Z.</creatorcontrib><creatorcontrib>Foulkes, F.R.</creatorcontrib><title>Ionically conductive thin polymer films prepared by plasma polymerization; Preparation and characterization of ultrathin films having fixed sulfonic acid groups with only one mobile species</title><title>Journal of the Electrochemical Society</title><description>Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 {mu}m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60{degrees}C of the order of 10{sup {minus} 6} S cm{sup {minus} 1} (10{sup 2} {Omega} cm{sup 2} resistance per unit area of as-prepared solid polymer electrolyte). 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Preparation and characterization of ultrathin films having fixed sulfonic acid groups with only one mobile species</title><author>Ogumi, Z. ; Uchimoto, Y. ; Takehara, Z. ; Foulkes, F.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_68177923</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>360602 -- Other Materials-- Structure & Phase Studies</topic><topic>400400 -- Electrochemistry</topic><topic>656003 -- Condensed Matter Physics-- Interactions between Beams & Condensed Matter-- (1987-)</topic><topic>ALKALI METAL COMPOUNDS</topic><topic>ALKALI METALS</topic><topic>CHARGED PARTICLES</topic><topic>CHEMICAL PREPARATION</topic><topic>CHEMICAL REACTION KINETICS</topic><topic>CHEMISTRY</topic><topic>CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY</topic><topic>ELECTRIC BATTERIES</topic><topic>ELECTRIC CONDUCTIVITY</topic><topic>ELECTRIC DISCHARGES</topic><topic>ELECTRICAL PROPERTIES</topic><topic>ELECTROCHEMICAL CELLS</topic><topic>ELECTROCHEMISTRY</topic><topic>ELECTROLYTES</topic><topic>ELEMENTS</topic><topic>ENERGY STORAGE</topic><topic>ESTERS</topic><topic>GLOW DISCHARGES</topic><topic>HALIDES</topic><topic>HALOGEN COMPOUNDS</topic><topic>INORGANIC PHOSPHORS</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IODIDES</topic><topic>IODINE COMPOUNDS</topic><topic>IONIC CONDUCTIVITY</topic><topic>IONS</topic><topic>KINETICS</topic><topic>LITHIUM</topic><topic>LITHIUM COMPOUNDS</topic><topic>LITHIUM HALIDES</topic><topic>LITHIUM IODIDES</topic><topic>LITHIUM IONS</topic><topic>MATERIALS SCIENCE</topic><topic>METALS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC SILICON COMPOUNDS</topic><topic>ORGANIC SULFUR COMPOUNDS</topic><topic>PHOSPHORS</topic><topic>PHYSICAL PROPERTIES</topic><topic>PLASMA</topic><topic>POLYMERS</topic><topic>REACTION KINETICS</topic><topic>SILOXANES</topic><topic>SOLID ELECTROLYTES</topic><topic>SOLID-STATE PLASMA</topic><topic>SULFONIC ACID ESTERS</topic><topic>SYNTHESIS 250903 -- Energy Storage-- Batteries-- Materials, Components, & Auxiliaries</topic><topic>THIN FILMS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ogumi, Z.</creatorcontrib><creatorcontrib>Uchimoto, Y.</creatorcontrib><creatorcontrib>Takehara, Z.</creatorcontrib><creatorcontrib>Foulkes, F.R.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of the Electrochemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ogumi, Z.</au><au>Uchimoto, Y.</au><au>Takehara, Z.</au><au>Foulkes, F.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionically conductive thin polymer films prepared by plasma polymerization; Preparation and characterization of ultrathin films having fixed sulfonic acid groups with only one mobile species</atitle><jtitle>Journal of the Electrochemical Society</jtitle><date>1990-01-01</date><risdate>1990</risdate><volume>137:1</volume><issn>0013-4651</issn><eissn>1945-7111</eissn><abstract>Ultrathin solid polymer electrolyte membranes containing sulfonic ester groups were prepared by polymerization of methyl benzenesulfonate and octamethylcyclotetrasiloxane in a glow discharge plasma. The sulfonic ester groups of the plasma polymer were transformed to lithium sulfonate groups by treatment with lithium iodide. Hybridization of this plasma polymer containing the lithium sulfonate groups with poly(ethylene oxide) (average Mw 300) resulted in the formation of a single lithium ion conductive film. The hybrid polymer electrolyte films were about 1 {mu}m thick, pinhole-free, adherent to various substrates, and showed ionic conductivities at 60{degrees}C of the order of 10{sup {minus} 6} S cm{sup {minus} 1} (10{sup 2} {Omega} cm{sup 2} resistance per unit area of as-prepared solid polymer electrolyte). This material shows promise for electrochemical applications such as all solid-state lithium batteries, sensors, and electrochemical display devices.</abstract><cop>United States</cop><doi>10.1149/1.2086386</doi></addata></record> |
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| source | IOP Publishing Journals |
| subjects | 360602 -- Other Materials-- Structure & Phase Studies 400400 -- Electrochemistry 656003 -- Condensed Matter Physics-- Interactions between Beams & Condensed Matter-- (1987-) ALKALI METAL COMPOUNDS ALKALI METALS CHARGED PARTICLES CHEMICAL PREPARATION CHEMICAL REACTION KINETICS CHEMISTRY CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ELECTRIC BATTERIES ELECTRIC CONDUCTIVITY ELECTRIC DISCHARGES ELECTRICAL PROPERTIES ELECTROCHEMICAL CELLS ELECTROCHEMISTRY ELECTROLYTES ELEMENTS ENERGY STORAGE ESTERS GLOW DISCHARGES HALIDES HALOGEN COMPOUNDS INORGANIC PHOSPHORS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IODIDES IODINE COMPOUNDS IONIC CONDUCTIVITY IONS KINETICS LITHIUM LITHIUM COMPOUNDS LITHIUM HALIDES LITHIUM IODIDES LITHIUM IONS MATERIALS SCIENCE METALS ORGANIC COMPOUNDS ORGANIC SILICON COMPOUNDS ORGANIC SULFUR COMPOUNDS PHOSPHORS PHYSICAL PROPERTIES PLASMA POLYMERS REACTION KINETICS SILOXANES SOLID ELECTROLYTES SOLID-STATE PLASMA SULFONIC ACID ESTERS SYNTHESIS 250903 -- Energy Storage-- Batteries-- Materials, Components, & Auxiliaries THIN FILMS |
| title | Ionically conductive thin polymer films prepared by plasma polymerization; Preparation and characterization of ultrathin films having fixed sulfonic acid groups with only one mobile species |
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