Crystallization of Fine, Chemically Prepared Lead Lanthanum Zirconate Titanate Powders at Low Temperature

Fine, homogeneous lead lanthanum zirconate titanate (PLZT) powder prepared by the hydrolysis of an aqueous nitrate solution with ammonia gas exhibits high reactivity when calcined. The minimum temperature for crystal formation in PLZT is 400°C. The kinetics of crystallization between 400° and 600°C...

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Veröffentlicht in:Journal of the American Ceramic Society 1990-01, Vol.73 (1), p.31-34
Hauptverfasser: Yoshikawa, Yoshio, Tsuzuki, Kaoru
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description Fine, homogeneous lead lanthanum zirconate titanate (PLZT) powder prepared by the hydrolysis of an aqueous nitrate solution with ammonia gas exhibits high reactivity when calcined. The minimum temperature for crystal formation in PLZT is 400°C. The kinetics of crystallization between 400° and 600°C are studied isothermally by XRD. The isothermal crystallization process is best fitted to a first‐order equation derived for a random, nucleation‐controlled system on a large number of small particles with an activation energy of 297 kJ/mol. Characterization of the powder by XRD line‐broadening and BET surface‐area examination in the range 400° to 500°C shows a microstructure consisting of ∼20‐nm subunits agglomerated into ∼60‐nm particles. Each subunit evidently generates a single nucleus, which grows within that subunit.
doi_str_mv 10.1111/j.1151-2916.1990.tb05085.x
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The minimum temperature for crystal formation in PLZT is 400°C. The kinetics of crystallization between 400° and 600°C are studied isothermally by XRD. The isothermal crystallization process is best fitted to a first‐order equation derived for a random, nucleation‐controlled system on a large number of small particles with an activation energy of 297 kJ/mol. Characterization of the powder by XRD line‐broadening and BET surface‐area examination in the range 400° to 500°C shows a microstructure consisting of ∼20‐nm subunits agglomerated into ∼60‐nm particles. Each subunit evidently generates a single nucleus, which grows within that subunit.</description><subject>360201 -- Ceramics, Cermets, &amp; Refractories-- Preparation &amp; Fabrication</subject><subject>400101 -- Activation, Nuclear Reaction, Radiometric &amp; Radiochemical Procedures</subject><subject>ACTIVATION ENERGY</subject><subject>Applied sciences</subject><subject>AQUEOUS SOLUTIONS</subject><subject>Building materials. 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The minimum temperature for crystal formation in PLZT is 400°C. The kinetics of crystallization between 400° and 600°C are studied isothermally by XRD. The isothermal crystallization process is best fitted to a first‐order equation derived for a random, nucleation‐controlled system on a large number of small particles with an activation energy of 297 kJ/mol. Characterization of the powder by XRD line‐broadening and BET surface‐area examination in the range 400° to 500°C shows a microstructure consisting of ∼20‐nm subunits agglomerated into ∼60‐nm particles. Each subunit evidently generates a single nucleus, which grows within that subunit.</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1151-2916.1990.tb05085.x</doi><tpages>4</tpages></addata></record>
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identifier ISSN: 0002-7820
ispartof Journal of the American Ceramic Society, 1990-01, Vol.73 (1), p.31-34
issn 0002-7820
1551-2916
language eng
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source Periodicals Index Online; Wiley Online Library All Journals
subjects 360201 -- Ceramics, Cermets, & Refractories-- Preparation & Fabrication
400101 -- Activation, Nuclear Reaction, Radiometric & Radiochemical Procedures
ACTIVATION ENERGY
Applied sciences
AQUEOUS SOLUTIONS
Building materials. Ceramics. Glasses
Ceramic industries
Chemical industry and chemicals
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COHERENT SCATTERING
CRYSTALLIZATION
DECOMPOSITION
DIFFRACTION
DISPERSIONS
ELEMENTS
ENERGY
Exact sciences and technology
HYDROLYSIS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LANTHANUM
LEAD
lead lanthanum zirconate titanate
LOW TEMPERATURE
LYSIS
MATERIALS SCIENCE
METALS
MIXTURES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
POWDERS
RARE EARTHS
SCATTERING
sintering
SOLUTIONS
SOLVOLYSIS
SYNTHESIS
Technical ceramics
TITANATES
TITANIUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS 360202 -- Ceramics, Cermets, & Refractories-- Structure & Phase Studies
X-RAY DIFFRACTION
ZIRCONIUM
title Crystallization of Fine, Chemically Prepared Lead Lanthanum Zirconate Titanate Powders at Low Temperature
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