Organo-f-element thermochemistry. Absolute metal-ligand bond disruption enthalpies in bis(pentamethylcyclopentadienyl)samarium hydrocarbyl, hydride, dialkylamide, alkoxide, halide, thiolate, and phosphide complexes. Implications for organolanthanide bonding and reactivity

Absolute samarium-ligand bond disruption enthalpies in the series Cp{prime}{sub 2}Sm-R/X (Cp{prime} = {eta}{sup 5}-(CH{sub 3}){sub 5}C{sub 5}) have been measured by iodinolytic and alcoholytic isoperibol titration calorimetry of Cp{prime}{sub 2}Sm/(Cp{prime}{sub 2}Sm-I){sub n}, (Cp{prime}{sub 2}Sm-O...

Ausführliche Beschreibung