IR spectrum of highly vibrationally excited OsO sub 4 in the region of strong nonlinear interaction of vibrational modes
The authors measured a linear infrared absorption spectrum (the {nu}{sub 3} band, {nu}{sub L} = 884-955 cm{sup {minus}1}) of OsO{sub 4} prepared at the high-lying vibrational states of E{sub vib} = 33,000 {plus minus} 250 cm{sup {minus}1} through radiationless transition. Contrary to the {nu}{sub 3}...
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| Veröffentlicht in: | Journal of physical chemistry (1952) 1990-02, Vol.94:4 |
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| container_title | Journal of physical chemistry (1952) |
| container_volume | 94:4 |
| creator | Boyarkin, O.V. Ionov, S.I. Stuchebrukhov, A.A. Bagratashvili, V.N. Djidjoev, M.S. |
| description | The authors measured a linear infrared absorption spectrum (the {nu}{sub 3} band, {nu}{sub L} = 884-955 cm{sup {minus}1}) of OsO{sub 4} prepared at the high-lying vibrational states of E{sub vib} = 33,000 {plus minus} 250 cm{sup {minus}1} through radiationless transition. Contrary to the {nu}{sub 3} transition from the ground state, the experimental spectrum manifests features of strong nonlinear interaction between the {nu}{sub 3} stretching and {nu}{sub 2}, {nu}{sub 4} bending modes. A suggested theoretical model explains general characteristics of the spectrum obtained. |
| doi_str_mv | 10.1021/j100367a018 |
| format | Article |
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Contrary to the {nu}{sub 3} transition from the ground state, the experimental spectrum manifests features of strong nonlinear interaction between the {nu}{sub 3} stretching and {nu}{sub 2}, {nu}{sub 4} bending modes. A suggested theoretical model explains general characteristics of the spectrum obtained.</description><identifier>ISSN: 0022-3654</identifier><identifier>EISSN: 1541-5740</identifier><identifier>DOI: 10.1021/j100367a018</identifier><language>eng</language><publisher>United States</publisher><subject>400201 -- Chemical & Physicochemical Properties ; ABSORPTION SPECTROSCOPY ; CALCULATION METHODS ; CHALCOGENIDES ; DATA ; DATA ANALYSIS ; ELECTROMAGNETIC RADIATION ; ENERGY LEVELS ; EXCITED STATES ; EXPERIMENTAL DATA ; INFORMATION ; INFRARED RADIATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MATERIALS SCIENCE ; MEASURING INSTRUMENTS ; MEASURING METHODS ; NUMERICAL DATA ; OSMIUM COMPOUNDS ; OSMIUM OXIDES ; OXIDES ; OXYGEN COMPOUNDS ; RADIATIONS ; REFRACTORY METAL COMPOUNDS ; SPECTROSCOPY ; TRANSITION ELEMENT COMPOUNDS 360204 -- Ceramics, Cermets, & Refractories-- Physical Properties</subject><ispartof>Journal of physical chemistry (1952), 1990-02, Vol.94:4</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.osti.gov/biblio/6715281$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Boyarkin, O.V.</creatorcontrib><creatorcontrib>Ionov, S.I.</creatorcontrib><creatorcontrib>Stuchebrukhov, A.A.</creatorcontrib><creatorcontrib>Bagratashvili, V.N.</creatorcontrib><creatorcontrib>Djidjoev, M.S.</creatorcontrib><title>IR spectrum of highly vibrationally excited OsO sub 4 in the region of strong nonlinear interaction of vibrational modes</title><title>Journal of physical chemistry (1952)</title><description>The authors measured a linear infrared absorption spectrum (the {nu}{sub 3} band, {nu}{sub L} = 884-955 cm{sup {minus}1}) of OsO{sub 4} prepared at the high-lying vibrational states of E{sub vib} = 33,000 {plus minus} 250 cm{sup {minus}1} through radiationless transition. Contrary to the {nu}{sub 3} transition from the ground state, the experimental spectrum manifests features of strong nonlinear interaction between the {nu}{sub 3} stretching and {nu}{sub 2}, {nu}{sub 4} bending modes. A suggested theoretical model explains general characteristics of the spectrum obtained.</description><subject>400201 -- Chemical & Physicochemical Properties</subject><subject>ABSORPTION SPECTROSCOPY</subject><subject>CALCULATION METHODS</subject><subject>CHALCOGENIDES</subject><subject>DATA</subject><subject>DATA ANALYSIS</subject><subject>ELECTROMAGNETIC RADIATION</subject><subject>ENERGY LEVELS</subject><subject>EXCITED STATES</subject><subject>EXPERIMENTAL DATA</subject><subject>INFORMATION</subject><subject>INFRARED RADIATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MATERIALS SCIENCE</subject><subject>MEASURING INSTRUMENTS</subject><subject>MEASURING METHODS</subject><subject>NUMERICAL DATA</subject><subject>OSMIUM COMPOUNDS</subject><subject>OSMIUM OXIDES</subject><subject>OXIDES</subject><subject>OXYGEN COMPOUNDS</subject><subject>RADIATIONS</subject><subject>REFRACTORY METAL COMPOUNDS</subject><subject>SPECTROSCOPY</subject><subject>TRANSITION ELEMENT COMPOUNDS 360204 -- Ceramics, Cermets, & Refractories-- Physical Properties</subject><issn>0022-3654</issn><issn>1541-5740</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNqNjs1qAkEQhIcQIRv1lBdoct-ke2d_vIeIngTJXcax3R1ZZ8L0GPTtXcGDx5yKor7qLqXeCD8IC_o8EKKuG4M0e1IZVSXlVVPis8oQiyLXdVW-qFeRAyKS1pSp83IN8ss2xdMRwh4613b9Bf7cNprkgjf94PhsXeIdrGQFctpCCc5D6hgitwNz60mKwbfgg--dZxMHInE0Nt3zh4NwDDuWiRrtTS88vetYvc-_f74WeZDkNnJ7aDsbvB-2beqGqmJG-l_QFTDsUzk</recordid><startdate>19900222</startdate><enddate>19900222</enddate><creator>Boyarkin, O.V.</creator><creator>Ionov, S.I.</creator><creator>Stuchebrukhov, A.A.</creator><creator>Bagratashvili, V.N.</creator><creator>Djidjoev, M.S.</creator><scope>OTOTI</scope></search><sort><creationdate>19900222</creationdate><title>IR spectrum of highly vibrationally excited OsO sub 4 in the region of strong nonlinear interaction of vibrational modes</title><author>Boyarkin, O.V. ; Ionov, S.I. ; Stuchebrukhov, A.A. ; Bagratashvili, V.N. ; Djidjoev, M.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_67152813</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>400201 -- Chemical & Physicochemical Properties</topic><topic>ABSORPTION SPECTROSCOPY</topic><topic>CALCULATION METHODS</topic><topic>CHALCOGENIDES</topic><topic>DATA</topic><topic>DATA ANALYSIS</topic><topic>ELECTROMAGNETIC RADIATION</topic><topic>ENERGY LEVELS</topic><topic>EXCITED STATES</topic><topic>EXPERIMENTAL DATA</topic><topic>INFORMATION</topic><topic>INFRARED RADIATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MATERIALS SCIENCE</topic><topic>MEASURING INSTRUMENTS</topic><topic>MEASURING METHODS</topic><topic>NUMERICAL DATA</topic><topic>OSMIUM COMPOUNDS</topic><topic>OSMIUM OXIDES</topic><topic>OXIDES</topic><topic>OXYGEN COMPOUNDS</topic><topic>RADIATIONS</topic><topic>REFRACTORY METAL COMPOUNDS</topic><topic>SPECTROSCOPY</topic><topic>TRANSITION ELEMENT COMPOUNDS 360204 -- Ceramics, Cermets, & Refractories-- Physical Properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boyarkin, O.V.</creatorcontrib><creatorcontrib>Ionov, S.I.</creatorcontrib><creatorcontrib>Stuchebrukhov, A.A.</creatorcontrib><creatorcontrib>Bagratashvili, V.N.</creatorcontrib><creatorcontrib>Djidjoev, M.S.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of physical chemistry (1952)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Boyarkin, O.V.</au><au>Ionov, S.I.</au><au>Stuchebrukhov, A.A.</au><au>Bagratashvili, V.N.</au><au>Djidjoev, M.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>IR spectrum of highly vibrationally excited OsO sub 4 in the region of strong nonlinear interaction of vibrational modes</atitle><jtitle>Journal of physical chemistry (1952)</jtitle><date>1990-02-22</date><risdate>1990</risdate><volume>94:4</volume><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>The authors measured a linear infrared absorption spectrum (the {nu}{sub 3} band, {nu}{sub L} = 884-955 cm{sup {minus}1}) of OsO{sub 4} prepared at the high-lying vibrational states of E{sub vib} = 33,000 {plus minus} 250 cm{sup {minus}1} through radiationless transition. Contrary to the {nu}{sub 3} transition from the ground state, the experimental spectrum manifests features of strong nonlinear interaction between the {nu}{sub 3} stretching and {nu}{sub 2}, {nu}{sub 4} bending modes. A suggested theoretical model explains general characteristics of the spectrum obtained.</abstract><cop>United States</cop><doi>10.1021/j100367a018</doi></addata></record> |
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| ispartof | Journal of physical chemistry (1952), 1990-02, Vol.94:4 |
| issn | 0022-3654 1541-5740 |
| language | eng |
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| source | ACS Publications |
| subjects | 400201 -- Chemical & Physicochemical Properties ABSORPTION SPECTROSCOPY CALCULATION METHODS CHALCOGENIDES DATA DATA ANALYSIS ELECTROMAGNETIC RADIATION ENERGY LEVELS EXCITED STATES EXPERIMENTAL DATA INFORMATION INFRARED RADIATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MATERIALS SCIENCE MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA OSMIUM COMPOUNDS OSMIUM OXIDES OXIDES OXYGEN COMPOUNDS RADIATIONS REFRACTORY METAL COMPOUNDS SPECTROSCOPY TRANSITION ELEMENT COMPOUNDS 360204 -- Ceramics, Cermets, & Refractories-- Physical Properties |
| title | IR spectrum of highly vibrationally excited OsO sub 4 in the region of strong nonlinear interaction of vibrational modes |
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