Electronic and stereochemical factors contributing to the lability of trans-aquomethyl(tetraazamacrocycle) cobalt(III) complexes. Kinetic and molecular mechanics studies

The origin and variability of the trans-labilizing influence of the Co-alkyl bond have been investigated by using the anation reactions of a series of trans-Co(N{sub 4})(OH{sub 2})CH{sub 3}{sup 2+} (N{sub 4} is a tetraazamacrocyclic ligand) complexes as probes. Anation reactions of some related tran...

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Veröffentlicht in:	Journal of the American Chemical Society 1989-09, Vol.111 (19), p.7411-7420
Hauptverfasser:	Endicott, John F, Kumar, Krishan, Schwarz, Carolyn L, Perkovic, Marc W, Lin, Wang Kan
Format:	Artikel
Sprache:	eng
Schlagworte:	400200 > Inorganic, Organic, & Physical Chemistry CALCULATION METHODS CHEMICAL REACTIONS Chemistry COBALT COMPLEXES COMPLEXES COORDINATION VALENCES DATA DATA ANALYSIS ELECTRONIC STRUCTURE Exact sciences and technology EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Kinetics and mechanisms LIGANDS MATERIALS SCIENCE MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA Organic chemistry Reactivity and mechanisms STEREOCHEMISTRY TRANSITION ELEMENT COMPLEXES VALENCE 360104 > Metals & Alloys-- Physical Properties
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