Consistent porphyrin force field. 1. Normal-mode analysis for nickel porphine and nickel tetraphenylporphine from resonance Raman and infrared spectra and isotope shifts

Resonance Raman spectra with variable-wavelength excitation are reported for Ni{sup II} porphine (NiP) and for the pyrrole-d{sub 8}, meso-d{sub 4}, and (pyrrole + meso)-d{sub 12} isotopomers, as well as for Ni{sup II} meso-tetraphenylporphine (NiTPP) and its pyrrole-{sup 15}N{sub 4}, pyrrole-d{sub 8...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1990, Vol.94 (1), p.31-47
Hauptverfasser:	Li, Xiao Yuan, Czernuszewicz, Roman S, Kincaid, James R, Su, Y. Oliver, Spiro, Thomas G
Format:	Artikel
Sprache:	eng
Schlagworte:	550200 > Biochemistry BASIC BIOLOGICAL SCIENCES CARBOXYLIC ACIDS DATA DATA ANALYSIS ELEMENTS ENERGY LEVELS EXPERIMENTAL DATA HETEROCYCLIC ACIDS HETEROCYCLIC COMPOUNDS INFORMATION INFRARED SPECTRA INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE EFFECTS MEASURING INSTRUMENTS MEASURING METHODS METALS NICKEL NUMERICAL DATA ORGANIC ACIDS ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS PORPHYRINS RAMAN SPECTRA SPECTRA TRANSITION ELEMENTS 400202 > Isotope Effects, Isotope Exchange, & Isotope Separation VALENCE
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