Mixed-valence biferrocenes: pronounced anion dependence of valence detrapping and effects of an asymmetric crystal lattice

The effect of changing the anion from I{sub 3}{sup {minus}} to either PF{sub 6}{sup {minus}} or SbF{sub 6}{sup {minus}} upon the rate of intramolecular electron transfer in salts of the mixed-valence 1{prime},1{prime}{double prime}-dibenzylbiferrocenium cation is investigated. Single-crystal X-ray s...

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Veröffentlicht in:	Journal of the American Chemical Society 1990-06, Vol.112 (13), p.5031-5042
Hauptverfasser:	Webb, Robert J, Geib, Steven J, Staley, Donna L, Rheingold, Arnold L, Hendrickson, David N
Format:	Artikel
Sprache:	eng
Schlagworte:	COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA DATA ANALYSIS DIENES ELECTRON TRANSFER Exact sciences and technology EXPERIMENTAL DATA FERROCENE HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRON COMPLEXES MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA ORGANIC COMPOUNDS Physics POLYENES SALTS Structure of solids and liquids crystallography TRANSITION ELEMENT COMPLEXES 400400 > Electrochemistry
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