Solid-state structure and fluxional solution behavior of the ambident organometallic nucleophiles (. eta. sup 3 -C sub 7 H sub 7 )M(CO) sub 3 sup minus (M = Ru, Os)

The cycloheptatrienyl carbonyl anions (C{sub 7}H{sub 7})M(CO){sub 3}{sup {minus}} (M = Ru, 1b; M = Os, 1c) have been isolated and structurally characterized as their Ph{sub 4}As{sup +} salts. Both 1b and 1c crystallize in the centrosymmetric space group P{bar 1} with two molecules per unit cell. For...

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Veröffentlicht in:	Organometallics 1990-01, Vol.9:1
Hauptverfasser:	Astley, S.T., Takats, J., Huffman, J.C., Streib, W.E.
Format:	Artikel
Sprache:	eng
Schlagworte:	COMPLEXES CRYSTAL STRUCTURE DATA DATA ANALYSIS EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MEASURING INSTRUMENTS MEASURING METHODS NMR SPECTRA NUMERICAL DATA ORGANIC COMPOUNDS ORGANOMETALLIC COMPOUNDS OSMIUM COMPLEXES RUTHENIUM COMPLEXES SPECTRA TRANSITION ELEMENT COMPLEXES 400200 > Inorganic, Organic, & Physical Chemistry
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