Temperature Dependence of Nonradiative Decay
The temperature dependences of nonradiative decay for the metal-to-ligand charge transfer excited states of [Re(bpy)(CO)[sub 3](4-Etpy)](PF[sub 6]) and [Os(bpy)[sub 2](CO)(py)](PF[sub 6])[sub 2] (bpy = 2,2[prime]-bipyridine; 4-Etpy = 4-ethylpyridine; py = pyridine) follow the behavior predicted by t...
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| Veröffentlicht in: | Journal of physical chemistry (1952) 1995-01, Vol.99 (1), p.51-54 |
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| container_title | Journal of physical chemistry (1952) |
| container_volume | 99 |
| creator | Claude, Juan Pablo Meyer, Thomas J |
| description | The temperature dependences of nonradiative decay for the metal-to-ligand charge transfer excited states of [Re(bpy)(CO)[sub 3](4-Etpy)](PF[sub 6]) and [Os(bpy)[sub 2](CO)(py)](PF[sub 6])[sub 2] (bpy = 2,2[prime]-bipyridine; 4-Etpy = 4-ethylpyridine; py = pyridine) follow the behavior predicted by the energy gap law. The variations with temperature can be calculated to within a factor of 2-3 by using parameters derived from a Frank-Condon analysis of emission spectral profiles. 17 refs., 4 figs., 1 tab. |
| doi_str_mv | 10.1021/j100001a010 |
| format | Article |
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Phys. Chem</addtitle><description>The temperature dependences of nonradiative decay for the metal-to-ligand charge transfer excited states of [Re(bpy)(CO)[sub 3](4-Etpy)](PF[sub 6]) and [Os(bpy)[sub 2](CO)(py)](PF[sub 6])[sub 2] (bpy = 2,2[prime]-bipyridine; 4-Etpy = 4-ethylpyridine; py = pyridine) follow the behavior predicted by the energy gap law. 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Phys. Chem</addtitle><date>1995-01-01</date><risdate>1995</risdate><volume>99</volume><issue>1</issue><spage>51</spage><epage>54</epage><pages>51-54</pages><issn>0022-3654</issn><eissn>1541-5740</eissn><abstract>The temperature dependences of nonradiative decay for the metal-to-ligand charge transfer excited states of [Re(bpy)(CO)[sub 3](4-Etpy)](PF[sub 6]) and [Os(bpy)[sub 2](CO)(py)](PF[sub 6])[sub 2] (bpy = 2,2[prime]-bipyridine; 4-Etpy = 4-ethylpyridine; py = pyridine) follow the behavior predicted by the energy gap law. The variations with temperature can be calculated to within a factor of 2-3 by using parameters derived from a Frank-Condon analysis of emission spectral profiles. 17 refs., 4 figs., 1 tab.</abstract><cop>United States</cop><pub>American Chemical Society</pub><doi>10.1021/j100001a010</doi><tpages>4</tpages></addata></record> |
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| ispartof | Journal of physical chemistry (1952), 1995-01, Vol.99 (1), p.51-54 |
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| source | American Chemical Society |
| subjects | 400102 -- Chemical & Spectral Procedures 400500 -- Photochemistry 990200 -- Mathematics & Computers ALCOHOLS CHARGE TRANSPORT COMPLEXES EMISSION SPECTRA ENERGY LEVELS ETHANOL EXCITED STATES FLUORIMETERS FRANCK-CONDON PRINCIPLE GENERAL AND MISCELLANEOUS//MATHEMATICS, COMPUTING, AND INFORMATION SCIENCE HYDROXY COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LASERS LIGANDS MATHEMATICAL MODELS MEASURING INSTRUMENTS METHANOL ORGANIC COMPOUNDS OSMIUM COMPLEXES RHENIUM COMPLEXES SPECTRA TEMPERATURE DEPENDENCE TRANSITION ELEMENT COMPLEXES 400201 -- Chemical & Physicochemical Properties |
| title | Temperature Dependence of Nonradiative Decay |
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