Control and characterization of ordering in GaInP

Ga0.51In0.49P layers have been grown by organometallic vapor phase epitaxy on GaAs substrates with [110]-oriented grooves on the surface that have an important effect on the formation of Cu-Pt ordered structures during growth. In this work, the groove shape is demonstrated to be critically important...

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Veröffentlicht in:Applied physics letters 1993-06, Vol.62 (26), p.3496-3498
Hauptverfasser: Su, L. C., Pu, S. T., Stringfellow, G. B., Christen, J., Selber, H., Bimberg, D.
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container_end_page 3498
container_issue 26
container_start_page 3496
container_title Applied physics letters
container_volume 62
creator Su, L. C.
Pu, S. T.
Stringfellow, G. B.
Christen, J.
Selber, H.
Bimberg, D.
description Ga0.51In0.49P layers have been grown by organometallic vapor phase epitaxy on GaAs substrates with [110]-oriented grooves on the surface that have an important effect on the formation of Cu-Pt ordered structures during growth. In this work, the groove shape is demonstrated to be critically important. For the optimum groove shape, single domains of the (1̄11) and (11̄1) variants of the Cu-Pt ordered structure are formed on the two sides of the groove. Shallow grooves produce large domains on each side of the groove containing small domains of the other variant. For deep grooves, only a single variant is formed on each side of the groove, but the domains are small. For substrates with deep grooves on a GaAs substrate misoriented by 9°, every groove contains large regions of highly ordered and completely disordered material separated by a few micrometers. This allows a direct determination of the effect of ordering on the band gap of the material using cathodoluminescence spectroscopy, allowing the first direct demonstration that ordering reduces the energy band gap of a III/V alloy.
doi_str_mv 10.1063/1.109006
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ispartof Applied physics letters, 1993-06, Vol.62 (26), p.3496-3498
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language eng
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source AIP Digital Archive
subjects ALLOY SYSTEMS
CHEMICAL COMPOSITION
CRYSTAL STRUCTURE
DOMAIN STRUCTURE
ELECTROLUMINESCENCE
ELECTRONIC STRUCTURE
EPITAXY
GALLIUM COMPOUNDS
GALLIUM PHOSPHIDES
INDIUM COMPOUNDS
INDIUM PHOSPHIDES
LUMINESCENCE
MATERIALS SCIENCE
MORPHOLOGY
ORDER-DISORDER TRANSFORMATIONS
PHASE TRANSFORMATIONS
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PNICTIDES 360606 -- Other Materials-- Physical Properties-- (1992-)
TERNARY ALLOY SYSTEMS
VAPOR PHASE EPITAXY
title Control and characterization of ordering in GaInP
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