Chemistry of trivalent cerium and uranium metallocenes: reactions with alcohols and thiols

The trivalent cerium metallocene (Me{sub 3}CC{sub 5}H{sub 4}){sub 3}Ce reacts with alcohols, HOR (R = CHMe{sub 2} or Ph), or thiols, HSR (R = CHMe{sub 2}, or Ph), to give the dimers (Me{sub 3}CC{sub 5}H{sub 4}){sub 4}Ce{sub 2} ({mu}-ER){sub 2} as shown by X-ray crystallography for the isopropoxide a...

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