Synthesis and structures of neutral and cationic rac-(ethylenebis(tetrahydroindenyl))zirconium(IV) benzyl complexes
Reaction of rac-(ethylenebis(tetrahydroindenyl))ZrCl{sub 2} (1) with 2 equiv of K(CH{sub 2}Ph) produces the dibenzyl complex (ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph){sub 2} (2). Reaction of 2 with ((C{sub 5}H{sub 4}Me){sub 2}Fe)(BPh{sub 4}) yields the cationic complex ((ethylenebis(tetrahydro...
Gespeichert in:
| Veröffentlicht in: | Organometallics 1990-05, Vol.9 (5), p.1539-1545 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1545 |
|---|---|
| container_issue | 5 |
| container_start_page | 1539 |
| container_title | Organometallics |
| container_volume | 9 |
| creator | Jordan, Richard F LaPointe, Robert E Baenziger, Norman Hinch, Garry D |
| description | Reaction of rac-(ethylenebis(tetrahydroindenyl))ZrCl{sub 2} (1) with 2 equiv of K(CH{sub 2}Ph) produces the dibenzyl complex (ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph){sub 2} (2). Reaction of 2 with ((C{sub 5}H{sub 4}Me){sub 2}Fe)(BPh{sub 4}) yields the cationic complex ((ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph)(THF))(BPh{sub 4}) (3). In CH{sub 3}CN solvent, 3 undergoes ligand substitution to yield ((ethylenebis(tetrahydroindenyl))Zr({eta}{sup 2}-CH{sub 2}Ph)(CH{sub 3}CN))(BPh{sub 4}) (4). The structures of 2 and 4 have been determined by X-ray diffraction. Complex 2 crystallizes in space group Pbcn with a = 10.008 (3) {angstrom}, b = 14.895 (4) {angstrom}, c = 17.532 (6) {angstrom}, V = 2,613.5 (2.4) {angstrom}{sup 3}, and Z = 4. Complex 4 crystallizes in space group P1 with a = 12.300 (2) {angstrom}, b = 12.493 (2) {angstrom}, c = 16.633 (3) {angstrom}, {alpha} = 84.61 (1){degree}, {beta} = 71.18 (1){degree}, {gamma} = 69.42 (1){degree}, V = 2,264.1 (9) {angstrom}{sup 3}, and Z = 2. |
| doi_str_mv | 10.1021/om00119a028 |
| format | Article |
| fullrecord | <record><control><sourceid>acs_osti_</sourceid><recordid>TN_cdi_osti_scitechconnect_6519006</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>c985941917</sourcerecordid><originalsourceid>FETCH-LOGICAL-a423t-8aee7e8b6a8a93d3095e03cf7648659054e49812affd7d275bc77031a3f226cd3</originalsourceid><addsrcrecordid>eNpt0N9rFDEQwPEgCp7VJ_-BRQTvKKv5sZvsPtaivcKBhVZfw1x2lkvdyx6ZLHT71xtdKT74lIf5TBi-jL0V_KPgUnwaj5wL0QKXzTO2ErXkpeaVeM5WXBpdGqXUS_aK6J5zro2SK0a3c0gHJE8FhK6gFCeXpohUjH0RcEoRhj8TB8mPwbsigivXmA7zgAH3ntYJMzrMXRx96DDMw2bz6KPLeDqur39sij2Gx3ko3Hg8DfiA9Jq96GEgfPP3PWPfv365u9yWu29X15cXuxIqqVLZAKLBZq-hgVZ1irc1cuV6o6tG1y2vK6zaRkjo-8500tR7ZwxXAlQvpXadOmPvln9HSt6S8wndId8V0CWra9HmCBmdL8jFkShib0_RHyHOVnD7O6r9J2rW7xd9AnIw9BGC8_S0ohtTtarOrFyYp4QPT2OIP23Obmp7d3NrP29Fs9uqG6uy_7B4cGTvxymG3OW_B_wCT9KT0A</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and structures of neutral and cationic rac-(ethylenebis(tetrahydroindenyl))zirconium(IV) benzyl complexes</title><source>American Chemical Society Journals</source><creator>Jordan, Richard F ; LaPointe, Robert E ; Baenziger, Norman ; Hinch, Garry D</creator><creatorcontrib>Jordan, Richard F ; LaPointe, Robert E ; Baenziger, Norman ; Hinch, Garry D</creatorcontrib><description>Reaction of rac-(ethylenebis(tetrahydroindenyl))ZrCl{sub 2} (1) with 2 equiv of K(CH{sub 2}Ph) produces the dibenzyl complex (ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph){sub 2} (2). Reaction of 2 with ((C{sub 5}H{sub 4}Me){sub 2}Fe)(BPh{sub 4}) yields the cationic complex ((ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph)(THF))(BPh{sub 4}) (3). In CH{sub 3}CN solvent, 3 undergoes ligand substitution to yield ((ethylenebis(tetrahydroindenyl))Zr({eta}{sup 2}-CH{sub 2}Ph)(CH{sub 3}CN))(BPh{sub 4}) (4). The structures of 2 and 4 have been determined by X-ray diffraction. Complex 2 crystallizes in space group Pbcn with a = 10.008 (3) {angstrom}, b = 14.895 (4) {angstrom}, c = 17.532 (6) {angstrom}, V = 2,613.5 (2.4) {angstrom}{sup 3}, and Z = 4. Complex 4 crystallizes in space group P1 with a = 12.300 (2) {angstrom}, b = 12.493 (2) {angstrom}, c = 16.633 (3) {angstrom}, {alpha} = 84.61 (1){degree}, {beta} = 71.18 (1){degree}, {gamma} = 69.42 (1){degree}, V = 2,264.1 (9) {angstrom}{sup 3}, and Z = 2.</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om00119a028</identifier><identifier>CODEN: ORGND7</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; CATALYSTS ; Chemistry ; COMPLEXES ; Condensed matter: structure, mechanical and thermal properties ; CRYSTAL STRUCTURE ; DATA ; DATA ANALYSIS ; Exact sciences and technology ; EXPERIMENTAL DATA ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MEASURING INSTRUMENTS ; MEASURING METHODS ; NUMERICAL DATA ; Organic chemistry ; Organic compounds ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; SYNTHESIS ; TRANSITION ELEMENT COMPLEXES ; Transition metals derivatives ; ZIRCONIUM COMPLEXES</subject><ispartof>Organometallics, 1990-05, Vol.9 (5), p.1539-1545</ispartof><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a423t-8aee7e8b6a8a93d3095e03cf7648659054e49812affd7d275bc77031a3f226cd3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om00119a028$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om00119a028$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6874935$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6519006$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Jordan, Richard F</creatorcontrib><creatorcontrib>LaPointe, Robert E</creatorcontrib><creatorcontrib>Baenziger, Norman</creatorcontrib><creatorcontrib>Hinch, Garry D</creatorcontrib><title>Synthesis and structures of neutral and cationic rac-(ethylenebis(tetrahydroindenyl))zirconium(IV) benzyl complexes</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>Reaction of rac-(ethylenebis(tetrahydroindenyl))ZrCl{sub 2} (1) with 2 equiv of K(CH{sub 2}Ph) produces the dibenzyl complex (ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph){sub 2} (2). Reaction of 2 with ((C{sub 5}H{sub 4}Me){sub 2}Fe)(BPh{sub 4}) yields the cationic complex ((ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph)(THF))(BPh{sub 4}) (3). In CH{sub 3}CN solvent, 3 undergoes ligand substitution to yield ((ethylenebis(tetrahydroindenyl))Zr({eta}{sup 2}-CH{sub 2}Ph)(CH{sub 3}CN))(BPh{sub 4}) (4). The structures of 2 and 4 have been determined by X-ray diffraction. Complex 2 crystallizes in space group Pbcn with a = 10.008 (3) {angstrom}, b = 14.895 (4) {angstrom}, c = 17.532 (6) {angstrom}, V = 2,613.5 (2.4) {angstrom}{sup 3}, and Z = 4. Complex 4 crystallizes in space group P1 with a = 12.300 (2) {angstrom}, b = 12.493 (2) {angstrom}, c = 16.633 (3) {angstrom}, {alpha} = 84.61 (1){degree}, {beta} = 71.18 (1){degree}, {gamma} = 69.42 (1){degree}, V = 2,264.1 (9) {angstrom}{sup 3}, and Z = 2.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>CATALYSTS</subject><subject>Chemistry</subject><subject>COMPLEXES</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>CRYSTAL STRUCTURE</subject><subject>DATA</subject><subject>DATA ANALYSIS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MEASURING INSTRUMENTS</subject><subject>MEASURING METHODS</subject><subject>NUMERICAL DATA</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>SYNTHESIS</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><subject>Transition metals derivatives</subject><subject>ZIRCONIUM COMPLEXES</subject><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNpt0N9rFDEQwPEgCp7VJ_-BRQTvKKv5sZvsPtaivcKBhVZfw1x2lkvdyx6ZLHT71xtdKT74lIf5TBi-jL0V_KPgUnwaj5wL0QKXzTO2ErXkpeaVeM5WXBpdGqXUS_aK6J5zro2SK0a3c0gHJE8FhK6gFCeXpohUjH0RcEoRhj8TB8mPwbsigivXmA7zgAH3ntYJMzrMXRx96DDMw2bz6KPLeDqur39sij2Gx3ko3Hg8DfiA9Jq96GEgfPP3PWPfv365u9yWu29X15cXuxIqqVLZAKLBZq-hgVZ1irc1cuV6o6tG1y2vK6zaRkjo-8500tR7ZwxXAlQvpXadOmPvln9HSt6S8wndId8V0CWra9HmCBmdL8jFkShib0_RHyHOVnD7O6r9J2rW7xd9AnIw9BGC8_S0ohtTtarOrFyYp4QPT2OIP23Obmp7d3NrP29Fs9uqG6uy_7B4cGTvxymG3OW_B_wCT9KT0A</recordid><startdate>19900501</startdate><enddate>19900501</enddate><creator>Jordan, Richard F</creator><creator>LaPointe, Robert E</creator><creator>Baenziger, Norman</creator><creator>Hinch, Garry D</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19900501</creationdate><title>Synthesis and structures of neutral and cationic rac-(ethylenebis(tetrahydroindenyl))zirconium(IV) benzyl complexes</title><author>Jordan, Richard F ; LaPointe, Robert E ; Baenziger, Norman ; Hinch, Garry D</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a423t-8aee7e8b6a8a93d3095e03cf7648659054e49812affd7d275bc77031a3f226cd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>CATALYSTS</topic><topic>Chemistry</topic><topic>COMPLEXES</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>CRYSTAL STRUCTURE</topic><topic>DATA</topic><topic>DATA ANALYSIS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MEASURING INSTRUMENTS</topic><topic>MEASURING METHODS</topic><topic>NUMERICAL DATA</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>SYNTHESIS</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><topic>Transition metals derivatives</topic><topic>ZIRCONIUM COMPLEXES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jordan, Richard F</creatorcontrib><creatorcontrib>LaPointe, Robert E</creatorcontrib><creatorcontrib>Baenziger, Norman</creatorcontrib><creatorcontrib>Hinch, Garry D</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jordan, Richard F</au><au>LaPointe, Robert E</au><au>Baenziger, Norman</au><au>Hinch, Garry D</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and structures of neutral and cationic rac-(ethylenebis(tetrahydroindenyl))zirconium(IV) benzyl complexes</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1990-05-01</date><risdate>1990</risdate><volume>9</volume><issue>5</issue><spage>1539</spage><epage>1545</epage><pages>1539-1545</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><coden>ORGND7</coden><abstract>Reaction of rac-(ethylenebis(tetrahydroindenyl))ZrCl{sub 2} (1) with 2 equiv of K(CH{sub 2}Ph) produces the dibenzyl complex (ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph){sub 2} (2). Reaction of 2 with ((C{sub 5}H{sub 4}Me){sub 2}Fe)(BPh{sub 4}) yields the cationic complex ((ethylenebis(tetrahydroindenyl))Zr(CH{sub 2}Ph)(THF))(BPh{sub 4}) (3). In CH{sub 3}CN solvent, 3 undergoes ligand substitution to yield ((ethylenebis(tetrahydroindenyl))Zr({eta}{sup 2}-CH{sub 2}Ph)(CH{sub 3}CN))(BPh{sub 4}) (4). The structures of 2 and 4 have been determined by X-ray diffraction. Complex 2 crystallizes in space group Pbcn with a = 10.008 (3) {angstrom}, b = 14.895 (4) {angstrom}, c = 17.532 (6) {angstrom}, V = 2,613.5 (2.4) {angstrom}{sup 3}, and Z = 4. Complex 4 crystallizes in space group P1 with a = 12.300 (2) {angstrom}, b = 12.493 (2) {angstrom}, c = 16.633 (3) {angstrom}, {alpha} = 84.61 (1){degree}, {beta} = 71.18 (1){degree}, {gamma} = 69.42 (1){degree}, V = 2,264.1 (9) {angstrom}{sup 3}, and Z = 2.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/om00119a028</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0276-7333 |
| ispartof | Organometallics, 1990-05, Vol.9 (5), p.1539-1545 |
| issn | 0276-7333 1520-6041 |
| language | eng |
| recordid | cdi_osti_scitechconnect_6519006 |
| source | American Chemical Society Journals |
| subjects | 400201 - Chemical & Physicochemical Properties CATALYSTS Chemistry COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA DATA ANALYSIS Exact sciences and technology EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS TRANSITION ELEMENT COMPLEXES Transition metals derivatives ZIRCONIUM COMPLEXES |
| title | Synthesis and structures of neutral and cationic rac-(ethylenebis(tetrahydroindenyl))zirconium(IV) benzyl complexes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T09%3A38%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-acs_osti_&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20structures%20of%20neutral%20and%20cationic%20rac-(ethylenebis(tetrahydroindenyl))zirconium(IV)%20benzyl%20complexes&rft.jtitle=Organometallics&rft.au=Jordan,%20Richard%20F&rft.date=1990-05-01&rft.volume=9&rft.issue=5&rft.spage=1539&rft.epage=1545&rft.pages=1539-1545&rft.issn=0276-7333&rft.eissn=1520-6041&rft.coden=ORGND7&rft_id=info:doi/10.1021/om00119a028&rft_dat=%3Cacs_osti_%3Ec985941917%3C/acs_osti_%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |