Determination of the bonding and orientation of ethylene on Pd(111) by near-edge X-ray absorption fine structure and photoelectron spectroscopy

The bonding and orientation of ethylene on Pd(111) at low temperature have been characterized by NEXAFS and photoelectron spectroscopy. UPS shows that ethylene is {pi}-bonded to palladium, while NEXAFS demonstrate unequivocally that the molecule adopts a flat-lying geometry on the metal surface, wit...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1990-05, Vol.94 (10), p.4236-4239
Hauptverfasser:	LU PING WANG, TYSOE, W. T, ORMEROD, R. M, LAMBERT, R. C, HOFFMANN, H, ZAERA, F
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALKENES Applied sciences BONDING CHEMICAL REACTIONS CHEMISORPTION Chemistry DATA DATA ANALYSIS ELECTRON SPECTROSCOPY ELEMENTS ETHYLENE Exact sciences and technology EXPERIMENTAL DATA FABRICATION General and physical chemistry HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY JOINING MEASURING INSTRUMENTS MEASURING METHODS METALS Metals. Metallurgy NUMERICAL DATA ORGANIC COMPOUNDS ORIENTATION PALLADIUM PHOTOELECTRON SPECTROSCOPY PLATINUM METALS SEPARATION PROCESSES Solid-gas interface SORPTION SPECTROSCOPY Surface physical chemistry TRANSITION ELEMENTS
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