A kinetic model for olefin polymerization in high-pressure autoclave reactors

Free radical copolymerization in high‐pressure autoclave reactors is studied by developing a mathematical model. Kinetic mechanisms to describe the polymerization rate, molecular weight averages, branching frequencies, as well as copolymer composition are presented. Two phase kinetics due to polymer...

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Veröffentlicht in:	AIChE journal 1993-01, Vol.39 (1), p.111-126
Hauptverfasser:	Chan, Wai-Man, Gloor, Paul E., Hamielec, Archie E.
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALKENES Applied sciences AUTOCLAVES CHEMICAL REACTION KINETICS CHEMICAL REACTIONS CHEMICAL REACTORS COMPUTERIZED SIMULATION COPOLYMERS Exact sciences and technology HYDROCARBONS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS MATERIALS MATHEMATICAL MODELS MIXING MOLECULAR WEIGHT ORGANIC COMPOUNDS ORGANIC POLYMERS PARAMETRIC ANALYSIS PETROCHEMICALS PETROLEUM PRODUCTS Physicochemistry of polymers PLASTICS POLYETHYLENES POLYMERIZATION POLYMERS POLYOLEFINS Preparation, kinetics, thermodynamics, mechanism and catalysts RADICALS REACTION KINETICS SIMULATION SOLUBILITY SYNTHESIS SYNTHETIC MATERIALS THERMOPLASTICS
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