Studies of lithium intercalation into carbons using nonaqueous electrochemical cells

This paper discusses how Li/graphite and Li/petroleum coke cells using a 1{ital M} LiAsF{sub 6} in a 50:50 mixture of propylene carbonate (PC) and ethylene carbonate (EC) electrolyte exhibit irreversible reactions only on the first discharge. These irreversible reactions are associated with electrol...

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Veröffentlicht in:	Journal of the Electrochemical Society 1990-07, Vol.137 (7), p.2009-2013
Hauptverfasser:	FONG, R, VON SACKEN, U, DAHN, J. R
Format:	Artikel
Sprache:	eng
Schlagworte:	02 PETROLEUM 020500 - Petroleum- Products & By-Products 30 DIRECT ENERGY CONVERSION 300503 - Fuel Cells- Materials, Components, & Auxiliaries 300505 - Fuel Cells- Electrochemistry, Mass Transfer & Thermodynamics 400201 - Chemical & Physicochemical Properties ALKALI METALS Applied sciences CARBON CHEMICAL REACTION KINETICS CHEMISTRY COKE DEPOSITION DIFFUSION Direct energy conversion and energy accumulation DIRECT ENERGY CONVERTERS Electrical engineering. Electrical power engineering Electrical power engineering ELECTROCHEMICAL CELLS Electrochemical conversion: primary and secondary batteries, fuel cells ELECTROCHEMISTRY ELECTRODES ELECTROLYTES ELEMENTS Exact sciences and technology FUEL CELLS HIGH-TEMPERATURE FUEL CELLS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY KINETICS LITHIUM METALS MOLTEN CARBONATE FUEL CELLS NONMETALS PASSIVATION PETROLEUM PRODUCTS REACTION KINETICS SOLID ELECTROLYTES SURFACE COATING
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