Binding and activation of halocarbons by iron(II) and ruthenium(II)
A series of cyclopentadienylruthenium(II) and -iron(II) complexes contain intact iodoalkanes, p-iodotoluene, or chelating (P, X) (o-halophenyl)diphenylphosphine (X = Cl, Br) ligands. The halocarbons coordinate via {sigma}-donation of a halogen lone pair and retain their carbon-halogen bonds. The com...
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| Veröffentlicht in: | Organometallics 1990-03, Vol.9 (3), p.745-755 |
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| creator | Kulawiec, Robert J Faller, J. W Crabtree, Robert H |
| description | A series of cyclopentadienylruthenium(II) and -iron(II) complexes contain intact iodoalkanes, p-iodotoluene, or chelating (P, X) (o-halophenyl)diphenylphosphine (X = Cl, Br) ligands. The halocarbons coordinate via {sigma}-donation of a halogen lone pair and retain their carbon-halogen bonds. The complexes are synthesized from the halocarbon, metal halide, and silver(I) ion. Full characterization shows that they are Ru(II) complexes of intact halocarbons rather than Ru(IV) products of oxidative addition. The crystal and molecular structure of one such complex, (Cp(CO)(PPh{sub 3})Ru(IC{sub 6}H{sub 4}-p-CH{sub 3}))PF{sub 6}, is reported (P{bar 1}, a = 10.976 (3) {angstrom}, b = 11.329 (3) {angstrom}, c = 13.666 (4) {angstrom}, {beta} = 102.62 (3){degree}, Z = 2, R{sub 1} = 0.054, R{sub 2} = 0.065). |
| doi_str_mv | 10.1021/om00117a033 |
| format | Article |
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The crystal and molecular structure of one such complex, (Cp(CO)(PPh{sub 3})Ru(IC{sub 6}H{sub 4}-p-CH{sub 3}))PF{sub 6}, is reported (P{bar 1}, a = 10.976 (3) {angstrom}, b = 11.329 (3) {angstrom}, c = 13.666 (4) {angstrom}, {beta} = 102.62 (3){degree}, Z = 2, R{sub 1} = 0.054, R{sub 2} = 0.065).</description><identifier>ISSN: 0276-7333</identifier><identifier>EISSN: 1520-6041</identifier><identifier>DOI: 10.1021/om00117a033</identifier><identifier>CODEN: ORGND7</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; CHEMICAL ACTIVATION ; Chemistry ; COMPLEXES ; Condensed matter: structure, mechanical and thermal properties ; CRYSTAL STRUCTURE ; DATA ; DATA ANALYSIS ; Exact sciences and technology ; EXPERIMENTAL DATA ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; IRON COMPLEXES ; MEASURING INSTRUMENTS ; MEASURING METHODS ; NUMERICAL DATA ; Organic chemistry ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; RUTHENIUM COMPLEXES ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; TRANSITION ELEMENT COMPLEXES ; Transition metals derivatives</subject><ispartof>Organometallics, 1990-03, Vol.9 (3), p.745-755</ispartof><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a423t-cc1604c7f4c5f71f2f2ca8fe2106c41bb21d3cfba8c10237f3d7614e133183d13</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/om00117a033$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/om00117a033$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,780,784,885,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6893328$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/6380260$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Kulawiec, Robert J</creatorcontrib><creatorcontrib>Faller, J. W</creatorcontrib><creatorcontrib>Crabtree, Robert H</creatorcontrib><title>Binding and activation of halocarbons by iron(II) and ruthenium(II)</title><title>Organometallics</title><addtitle>Organometallics</addtitle><description>A series of cyclopentadienylruthenium(II) and -iron(II) complexes contain intact iodoalkanes, p-iodotoluene, or chelating (P, X) (o-halophenyl)diphenylphosphine (X = Cl, Br) ligands. The halocarbons coordinate via {sigma}-donation of a halogen lone pair and retain their carbon-halogen bonds. The complexes are synthesized from the halocarbon, metal halide, and silver(I) ion. Full characterization shows that they are Ru(II) complexes of intact halocarbons rather than Ru(IV) products of oxidative addition. The crystal and molecular structure of one such complex, (Cp(CO)(PPh{sub 3})Ru(IC{sub 6}H{sub 4}-p-CH{sub 3}))PF{sub 6}, is reported (P{bar 1}, a = 10.976 (3) {angstrom}, b = 11.329 (3) {angstrom}, c = 13.666 (4) {angstrom}, {beta} = 102.62 (3){degree}, Z = 2, R{sub 1} = 0.054, R{sub 2} = 0.065).</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>CHEMICAL ACTIVATION</subject><subject>Chemistry</subject><subject>COMPLEXES</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>CRYSTAL STRUCTURE</subject><subject>DATA</subject><subject>DATA ANALYSIS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>IRON COMPLEXES</subject><subject>MEASURING INSTRUMENTS</subject><subject>MEASURING METHODS</subject><subject>NUMERICAL DATA</subject><subject>Organic chemistry</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>RUTHENIUM COMPLEXES</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>TRANSITION ELEMENT COMPLEXES</subject><subject>Transition metals derivatives</subject><issn>0276-7333</issn><issn>1520-6041</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNpt0F1LwzAUBuAgCs6PK_9AEUFFqjk5XVMvdfgxnKj4dRnS08ZFt0SSTty_t7MiXngVSJ4T3vMytgX8ELiAIz_lHEBqjrjEetAXPM15Bsusx4XMU4mIq2wtxlfOeS5R9Njg1LrKupdEuyrR1NgP3VjvEm-SsZ540qH0LiblPLHBu73hcP9bhlkzrp2dTRc3G2zF6EmsN3_OdfZ4fvYwuExHNxfDwcko1ZnAJiWCNgxJk1HfSDDCCNKFqQXwnDIoSwEVkil1Qe0yKA1WMoesBkQosAJcZ9vdvz42VkWyTU1j8s7V1KgcCy5y3qKDDlHwMYbaqPdgpzrMFXC1KEn9KanVO51-15H0xATtyMbfkbw4RhRFy9KO2djUn7_POryptkbZVw-39-r6Tj7dj8SVem79buc1RfXqZ8G1vfwb4AvP74Aj</recordid><startdate>19900301</startdate><enddate>19900301</enddate><creator>Kulawiec, Robert J</creator><creator>Faller, J. W</creator><creator>Crabtree, Robert H</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19900301</creationdate><title>Binding and activation of halocarbons by iron(II) and ruthenium(II)</title><author>Kulawiec, Robert J ; Faller, J. W ; Crabtree, Robert H</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a423t-cc1604c7f4c5f71f2f2ca8fe2106c41bb21d3cfba8c10237f3d7614e133183d13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>CHEMICAL ACTIVATION</topic><topic>Chemistry</topic><topic>COMPLEXES</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>CRYSTAL STRUCTURE</topic><topic>DATA</topic><topic>DATA ANALYSIS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>IRON COMPLEXES</topic><topic>MEASURING INSTRUMENTS</topic><topic>MEASURING METHODS</topic><topic>NUMERICAL DATA</topic><topic>Organic chemistry</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>RUTHENIUM COMPLEXES</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>TRANSITION ELEMENT COMPLEXES</topic><topic>Transition metals derivatives</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kulawiec, Robert J</creatorcontrib><creatorcontrib>Faller, J. W</creatorcontrib><creatorcontrib>Crabtree, Robert H</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Organometallics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kulawiec, Robert J</au><au>Faller, J. W</au><au>Crabtree, Robert H</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Binding and activation of halocarbons by iron(II) and ruthenium(II)</atitle><jtitle>Organometallics</jtitle><addtitle>Organometallics</addtitle><date>1990-03-01</date><risdate>1990</risdate><volume>9</volume><issue>3</issue><spage>745</spage><epage>755</epage><pages>745-755</pages><issn>0276-7333</issn><eissn>1520-6041</eissn><coden>ORGND7</coden><abstract>A series of cyclopentadienylruthenium(II) and -iron(II) complexes contain intact iodoalkanes, p-iodotoluene, or chelating (P, X) (o-halophenyl)diphenylphosphine (X = Cl, Br) ligands. The halocarbons coordinate via {sigma}-donation of a halogen lone pair and retain their carbon-halogen bonds. The complexes are synthesized from the halocarbon, metal halide, and silver(I) ion. Full characterization shows that they are Ru(II) complexes of intact halocarbons rather than Ru(IV) products of oxidative addition. The crystal and molecular structure of one such complex, (Cp(CO)(PPh{sub 3})Ru(IC{sub 6}H{sub 4}-p-CH{sub 3}))PF{sub 6}, is reported (P{bar 1}, a = 10.976 (3) {angstrom}, b = 11.329 (3) {angstrom}, c = 13.666 (4) {angstrom}, {beta} = 102.62 (3){degree}, Z = 2, R{sub 1} = 0.054, R{sub 2} = 0.065).</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/om00117a033</doi><tpages>11</tpages></addata></record> |
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| subjects | 400201 - Chemical & Physicochemical Properties CHEMICAL ACTIVATION Chemistry COMPLEXES Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE DATA DATA ANALYSIS Exact sciences and technology EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY IRON COMPLEXES MEASURING INSTRUMENTS MEASURING METHODS NUMERICAL DATA Organic chemistry ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS Organometalloidal and organometallic compounds Physics Preparations and properties RUTHENIUM COMPLEXES Structure of solids and liquids crystallography Structure of specific crystalline solids TRANSITION ELEMENT COMPLEXES Transition metals derivatives |
| title | Binding and activation of halocarbons by iron(II) and ruthenium(II) |
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