On kinetic phase transitions in surface reactions

The steady-state properties for the bimolecular surface reaction A + 1 2 B 2 → AB are investigated. Kinetic phase transition points, bistability, and hysteresis characteristics are specified by using kinetic equations of the mean-field-approximation type. Comparisons with Monte Carlo simulation resu...

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Veröffentlicht in:Journal of catalysis 1990-03, Vol.122 (1), p.95-112
Hauptverfasser: Dumont, Martine, Dufour, P., Sente, B., Dagonnier, R.
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container_end_page 112
container_issue 1
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container_title Journal of catalysis
container_volume 122
creator Dumont, Martine
Dufour, P.
Sente, B.
Dagonnier, R.
description The steady-state properties for the bimolecular surface reaction A + 1 2 B 2 → AB are investigated. Kinetic phase transition points, bistability, and hysteresis characteristics are specified by using kinetic equations of the mean-field-approximation type. Comparisons with Monte Carlo simulation results are made.
doi_str_mv 10.1016/0021-9517(90)90264-K
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ispartof Journal of catalysis, 1990-03, Vol.122 (1), p.95-112
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1090-2694
language eng
recordid cdi_osti_scitechconnect_6379145
source Elsevier ScienceDirect Journals
subjects 330702 - Emission Control- Carbon Monoxide
400201 - Chemical & Physicochemical Properties
ADVANCED PROPULSION SYSTEMS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYSTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
Chemistry
EQUATIONS
Exact sciences and technology
General and physical chemistry
HYSTERESIS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
KINETIC EQUATIONS
KINETICS
MONTE CARLO METHOD
OXIDATION
OXIDES
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
REACTION KINETICS
SIMULATION
STEADY-STATE CONDITIONS
SURFACE PROPERTIES
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title On kinetic phase transitions in surface reactions
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