A study of the system Yb + S, mainly by electron diffraction/microscopy
An electron diffraction study of various ytterbium sulfide preparations reveals the presence of several phases: “Yb 3S 4” in two orthorhombic forms, Ccmm at high temperatures and Pnma, the latter sometimes incommensurately modulated, sometimes not; B1-related types, both cubic and rhombohedral, agai...
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| Veröffentlicht in: | Journal of solid state chemistry 1990-12, Vol.89 (2), p.237-259 |
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| container_title | Journal of solid state chemistry |
| container_volume | 89 |
| creator | Otero-Díaz, L.C. Landa-Cánovas, A.R. Hyde, B.G. |
| description | An electron diffraction study of various ytterbium sulfide preparations reveals the presence of several phases: “Yb
3S
4” in two orthorhombic forms,
Ccmm at high temperatures and
Pnma, the latter sometimes incommensurately modulated, sometimes not; B1-related types, both cubic and rhombohedral, again the latter sometimes incommensurately modulated. The results are generally consistent with those previously reported. They reveal the absence of long-range order in some of the B1-related phases, and the consequent difficulty in identifying and delineating the phase relations between the cubic and rhombohedral Yb
1−δS types. |
| doi_str_mv | 10.1016/0022-4596(90)90266-Z |
| format | Article |
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3S
4” in two orthorhombic forms,
Ccmm at high temperatures and
Pnma, the latter sometimes incommensurately modulated, sometimes not; B1-related types, both cubic and rhombohedral, again the latter sometimes incommensurately modulated. The results are generally consistent with those previously reported. They reveal the absence of long-range order in some of the B1-related phases, and the consequent difficulty in identifying and delineating the phase relations between the cubic and rhombohedral Yb
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3S
4” in two orthorhombic forms,
Ccmm at high temperatures and
Pnma, the latter sometimes incommensurately modulated, sometimes not; B1-related types, both cubic and rhombohedral, again the latter sometimes incommensurately modulated. The results are generally consistent with those previously reported. They reveal the absence of long-range order in some of the B1-related phases, and the consequent difficulty in identifying and delineating the phase relations between the cubic and rhombohedral Yb
1−δS types.</description><subject>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies</subject><subject>CHALCOGENIDES</subject><subject>COHERENT SCATTERING</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>CRYSTAL STRUCTURE</subject><subject>Crystalline state (including molecular motions in solids)</subject><subject>Crystallographic aspects of phase transformations; pressure effects</subject><subject>DATA</subject><subject>DIFFRACTION</subject><subject>ELECTRON DIFFRACTION</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>INFORMATION</subject><subject>LATTICE PARAMETERS</subject><subject>MATERIALS SCIENCE</subject><subject>MEASURING METHODS</subject><subject>NUMERICAL DATA</subject><subject>PHASE STUDIES</subject><subject>Physics</subject><subject>RARE EARTH COMPOUNDS</subject><subject>SCATTERING</subject><subject>Structure of solids and liquids; crystallography</subject><subject>SULFIDES</subject><subject>SULFUR COMPOUNDS</subject><subject>YTTERBIUM COMPOUNDS</subject><subject>YTTERBIUM SULFIDES</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKv_wEMQD4qunexHurkIpWgVCh5U0F5CdpLQyH6UTRT237vrikdPc3nemXceQk4Z3DBgfAYQx1GaCX4h4FJAzHm02SMTBiKL5jF_2yeTP-SQHHn_AcBYlqcTslpQHz51RxtLw9ZQ3_lgKvpe0Cv6fE0r5eqyo0VHTWkwtE1NtbO2VRhcU88qh23jsdl1x-TAqtKbk985Ja_3dy_Lh2j9tHpcLtYRJhxCZC2gVrlJCp0bblPMMWXCqJyDsExpLJgpuIkZzgsrlBCWx7pIc8tVjELbZErOxr2ND056dMHgFpu67ttJnvAE8qSH0hEa2vnWWLlrXaXaTjKQgzE56JCDDilA_hiTmz52PsZ2yqMq-y9rdP4vm6WQZJD22O2Imf7PL2faoYap0WjXDi104_6_8w1rWIAG</recordid><startdate>19901201</startdate><enddate>19901201</enddate><creator>Otero-Díaz, L.C.</creator><creator>Landa-Cánovas, A.R.</creator><creator>Hyde, B.G.</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>OTOTI</scope></search><sort><creationdate>19901201</creationdate><title>A study of the system Yb + S, mainly by electron diffraction/microscopy</title><author>Otero-Díaz, L.C. ; Landa-Cánovas, A.R. ; Hyde, B.G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-ff0cda8e3bd8e6f4c8c419ea8609f1adcb1eb6e21c7bf9a99f62db48f6a2c9df3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies</topic><topic>CHALCOGENIDES</topic><topic>COHERENT SCATTERING</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>CRYSTAL STRUCTURE</topic><topic>Crystalline state (including molecular motions in solids)</topic><topic>Crystallographic aspects of phase transformations; pressure effects</topic><topic>DATA</topic><topic>DIFFRACTION</topic><topic>ELECTRON DIFFRACTION</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>INFORMATION</topic><topic>LATTICE PARAMETERS</topic><topic>MATERIALS SCIENCE</topic><topic>MEASURING METHODS</topic><topic>NUMERICAL DATA</topic><topic>PHASE STUDIES</topic><topic>Physics</topic><topic>RARE EARTH COMPOUNDS</topic><topic>SCATTERING</topic><topic>Structure of solids and liquids; crystallography</topic><topic>SULFIDES</topic><topic>SULFUR COMPOUNDS</topic><topic>YTTERBIUM COMPOUNDS</topic><topic>YTTERBIUM SULFIDES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Otero-Díaz, L.C.</creatorcontrib><creatorcontrib>Landa-Cánovas, A.R.</creatorcontrib><creatorcontrib>Hyde, B.G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Otero-Díaz, L.C.</au><au>Landa-Cánovas, A.R.</au><au>Hyde, B.G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A study of the system Yb + S, mainly by electron diffraction/microscopy</atitle><jtitle>Journal of solid state chemistry</jtitle><date>1990-12-01</date><risdate>1990</risdate><volume>89</volume><issue>2</issue><spage>237</spage><epage>259</epage><pages>237-259</pages><issn>0022-4596</issn><eissn>1095-726X</eissn><coden>JSSCBI</coden><abstract>An electron diffraction study of various ytterbium sulfide preparations reveals the presence of several phases: “Yb
3S
4” in two orthorhombic forms,
Ccmm at high temperatures and
Pnma, the latter sometimes incommensurately modulated, sometimes not; B1-related types, both cubic and rhombohedral, again the latter sometimes incommensurately modulated. The results are generally consistent with those previously reported. They reveal the absence of long-range order in some of the B1-related phases, and the consequent difficulty in identifying and delineating the phase relations between the cubic and rhombohedral Yb
1−δS types.</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><doi>10.1016/0022-4596(90)90266-Z</doi><tpages>23</tpages></addata></record> |
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| identifier | ISSN: 0022-4596 |
| ispartof | Journal of solid state chemistry, 1990-12, Vol.89 (2), p.237-259 |
| issn | 0022-4596 1095-726X |
| language | eng |
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| subjects | 360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies CHALCOGENIDES COHERENT SCATTERING Condensed matter: structure, mechanical and thermal properties CRYSTAL STRUCTURE Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects DATA DIFFRACTION ELECTRON DIFFRACTION Exact sciences and technology EXPERIMENTAL DATA INFORMATION LATTICE PARAMETERS MATERIALS SCIENCE MEASURING METHODS NUMERICAL DATA PHASE STUDIES Physics RARE EARTH COMPOUNDS SCATTERING Structure of solids and liquids crystallography SULFIDES SULFUR COMPOUNDS YTTERBIUM COMPOUNDS YTTERBIUM SULFIDES |
| title | A study of the system Yb + S, mainly by electron diffraction/microscopy |
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