Surface temperature dependence of the steric effect in the scattering of oriented tert-butyl chloride and fluoroform molecules by graphite(0001)

The scattering of focused beams of hexapole-oriented {ital t}-BuCl and CHF{sub 3} molecules from a graphite (0001) surface has been studied over the surface temperature range 165 {lt} {ital T}{sub {ital s}}{lt}730 K. The detected number densities of the surface-scattered beams are compared for paral...

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Veröffentlicht in:	The Journal of chemical physics 1990-11, Vol.93 (10), p.7406-7415
Hauptverfasser:	IONOV, S. I, LAVILLA, M. E, MACKAY, R. S, BERNSTEIN, R. B
Format:	Artikel
Sprache:	eng
Schlagworte:	656003 - Condensed Matter Physics- Interactions between Beams & Condensed Matter- (1987-) ANGULAR DISTRIBUTION Atomic and molecular collision processes and interactions Atomic and molecular physics BEAMS CARBON COLLISIONS CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY DISTRIBUTION ELEMENTAL MINERALS ELEMENTS Exact sciences and technology FLUORINATED ALIPHATIC HYDROCARBONS FLUOROFORM GRAPHITE HALOGENATED ALIPHATIC HYDROCARBONS MINERALS MOLECULAR BEAMS MOLECULE COLLISIONS NONMETALS ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC FLUORINE COMPOUNDS ORGANIC HALOGEN COMPOUNDS ORIENTATION Other topics in atomic and molecular collision processes and interactions Physics TEMPERATURE DEPENDENCE
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